CA1073039A - Electrochemical zinc-oxygen cell with ion exchange membrane - Google Patents
Electrochemical zinc-oxygen cell with ion exchange membraneInfo
- Publication number
- CA1073039A CA1073039A CA282,104A CA282104A CA1073039A CA 1073039 A CA1073039 A CA 1073039A CA 282104 A CA282104 A CA 282104A CA 1073039 A CA1073039 A CA 1073039A
- Authority
- CA
- Canada
- Prior art keywords
- electrode
- zinc
- membrane
- oxygen
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 239000003014 ion exchange membrane Substances 0.000 title 1
- 239000012528 membrane Substances 0.000 claims abstract description 30
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000001301 oxygen Substances 0.000 claims abstract description 25
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 25
- 238000005342 ion exchange Methods 0.000 claims abstract description 22
- 239000003792 electrolyte Substances 0.000 claims abstract description 20
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 15
- 239000011701 zinc Substances 0.000 claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 8
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims abstract description 4
- 238000009792 diffusion process Methods 0.000 claims abstract description 3
- 239000011230 binding agent Substances 0.000 claims description 16
- -1 poly(tetrafluoroethylene) Polymers 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 7
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims 1
- 239000011262 electrochemically active material Substances 0.000 abstract description 2
- 231100000572 poisoning Toxicity 0.000 abstract description 2
- 230000000607 poisoning effect Effects 0.000 abstract description 2
- 229920000136 polysorbate Polymers 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 11
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000011149 active material Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000006735 deficit Effects 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000905957 Channa melasoma Species 0.000 description 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 241000212342 Sium Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229960001296 zinc oxide Drugs 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
- H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Hybrid Cells (AREA)
- Inert Electrodes (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL7607471A NL7607471A (nl) | 1976-07-07 | 1976-07-07 | Elektrochemische zink-zuurstof-cel. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1073039A true CA1073039A (en) | 1980-03-04 |
Family
ID=19826535
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA282,104A Expired CA1073039A (en) | 1976-07-07 | 1977-07-06 | Electrochemical zinc-oxygen cell with ion exchange membrane |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4137371A (enExample) |
| JP (1) | JPS536842A (enExample) |
| AU (1) | AU2679977A (enExample) |
| BE (1) | BE856298A (enExample) |
| BR (1) | BR7704455A (enExample) |
| CA (1) | CA1073039A (enExample) |
| DE (1) | DE2730068A1 (enExample) |
| FR (1) | FR2358028A1 (enExample) |
| GB (1) | GB1582085A (enExample) |
| IT (1) | IT1079755B (enExample) |
| NL (1) | NL7607471A (enExample) |
| SE (1) | SE7707759L (enExample) |
| ZA (1) | ZA774021B (enExample) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4333993A (en) * | 1980-09-22 | 1982-06-08 | Gould Inc. | Air cathode for air depolarized cells |
| US4341847A (en) * | 1980-10-14 | 1982-07-27 | Institute Of Gas Technology | Electrochemical zinc-oxygen cell |
| US4585710A (en) * | 1985-04-22 | 1986-04-29 | Duracell Inc. | Zinc/air cell cathode |
| US5092976A (en) * | 1987-03-02 | 1992-03-03 | Westinghouse Electric Corp. | Hydrogel loaded active layer in pressure tolerant gas diffusion electrodes |
| EP0371965A1 (en) * | 1987-03-02 | 1990-06-13 | Westinghouse Electric Corporation | Ionomer membranes in pressure tolerant gas diffusion electrodes |
| US5126031A (en) * | 1987-03-02 | 1992-06-30 | Gordon Arnold Z | Coprecipitated hydrogels in pressure tolerant gas diffusion electrodes |
| US4997725A (en) * | 1989-09-27 | 1991-03-05 | Gas Research Institute | Electrocatalytic oxidative dimerization of methane |
| US5064733A (en) * | 1989-09-27 | 1991-11-12 | Gas Research Institute | Electrochemical conversion of CO2 and CH4 to C2 hydrocarbons in a single cell |
| JPH0593550A (ja) * | 1991-04-11 | 1993-04-16 | Ebara Corp | 冷凍システム |
| US5487955A (en) | 1994-03-15 | 1996-01-30 | Electric Fuel (E.F.L.) Ltd. | Cooled zinc-oxygen battery |
| US5733676A (en) * | 1995-05-05 | 1998-03-31 | Rayovac Corporation | Metal-air cathode can and electrochemical cell made therewith |
| US5591541A (en) * | 1995-05-05 | 1997-01-07 | Rayovac Corporation | High steel content thin walled anode can |
| FR2745959B1 (fr) * | 1996-03-08 | 1998-07-10 | Sorapec Lab | Perfectionnements apportes a l'accumulateur ni-zn au moyen d'anolyte, de catholyte et de membrane remediant a la formation de dendrites |
| US6248463B1 (en) | 1997-05-05 | 2001-06-19 | Rayovac Corporation | Metal-air cathode can and electrochemical cell made therewith |
| FR2768264B1 (fr) * | 1997-09-11 | 1999-12-03 | Sorapec Lab | Generateur air-zinc rechargeable electriquement |
| US6461761B1 (en) | 1998-03-06 | 2002-10-08 | Rayovac Corporation | Air depolarized electrochemical cells |
| US6261709B1 (en) | 1998-03-06 | 2001-07-17 | Rayovac Corporation | Air depolarized electrochemical cell having mass-control chamber in anode |
| US6368738B1 (en) | 1998-03-06 | 2002-04-09 | Rayovac Corporation | Air depolarized electrochemical cell |
| US6127061A (en) * | 1999-01-26 | 2000-10-03 | High-Density Energy, Inc. | Catalytic air cathode for air-metal batteries |
| FR2835656A1 (fr) * | 2002-05-13 | 2003-08-08 | Commissariat Energie Atomique | Pile du type metal-oxygene comprenant un electrolyte apte a limiter, du cote cathodique, le passage de cations |
| US20100323249A1 (en) * | 2008-02-18 | 2010-12-23 | National Institute Of Advanced Industrial Science And Technology | Air electrode |
| US9118089B2 (en) | 2011-06-17 | 2015-08-25 | Fluidic, Inc. | Metal-air cell with ion exchange material |
| JP6154999B2 (ja) * | 2012-07-27 | 2017-06-28 | シャープ株式会社 | 電池用電極体、電池および金属空気電池 |
| CN113451541B (zh) * | 2021-05-28 | 2023-02-03 | 上海空间电源研究所 | 一种高电压锂离子正电极极片、电池及其制作方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2938064A (en) * | 1958-03-12 | 1960-05-24 | Union Carbide Corp | Air-depolarized cell |
| US3117034A (en) * | 1960-06-22 | 1964-01-07 | Ionics | Gas electrode |
| FR1492204A (fr) * | 1966-07-04 | 1967-08-18 | Wonder Piles | Perfectionnements aux générateurs électrochimiques |
| FR91138E (fr) * | 1966-10-17 | 1968-04-19 | Wonder Piles | Perfectionnements aux générateurs électrochimiques |
| FR1579475A (enExample) * | 1967-11-07 | 1969-08-29 | ||
| FR1601214A (en) * | 1968-12-31 | 1970-08-10 | Coating gaseous diffusion electrodes with - a separator | |
| DE1933305C3 (de) * | 1969-07-01 | 1978-04-06 | Siemens Ag, 1000 Berlin Und 8000 Muenchen | Verfahren zur Herstellung eines Bauteils für Brennstoffelemente |
| DE2129415A1 (de) * | 1970-07-24 | 1972-03-23 | Galvanische Elemente K Veb | Galvanisches Luftsauerstoffelement,vorzugsweise mit alkalischem Elektrolyten und Verfahren zur Herstellung eines solchen Elementes |
| FR2144935A5 (en) * | 1971-07-02 | 1973-02-16 | Wonder | Zinc electrode accumulator separator - of microporous polymer contg finely divided metal or carbon of high active surface |
| GB1398843A (en) * | 1971-07-10 | 1975-06-25 | Lucas Industries Ltd | Gas electrode |
| US3881959A (en) * | 1972-09-14 | 1975-05-06 | Fuji Electrochemical Co Ltd | Air cell |
| FR2283555A1 (fr) * | 1974-08-27 | 1976-03-26 | Accumulateurs Fixes | Pile electrique |
| FR2319205A2 (fr) * | 1975-07-24 | 1977-02-18 | Wonder | Perfectionnements aux separateurs pour accumulateurs, notamment a electrodes de zinc |
-
1976
- 1976-07-07 NL NL7607471A patent/NL7607471A/xx not_active Application Discontinuation
-
1977
- 1977-06-30 BE BE178935A patent/BE856298A/xx not_active IP Right Cessation
- 1977-07-02 DE DE19772730068 patent/DE2730068A1/de not_active Withdrawn
- 1977-07-04 ZA ZA00774021A patent/ZA774021B/xx unknown
- 1977-07-04 SE SE7707759A patent/SE7707759L/xx not_active Application Discontinuation
- 1977-07-05 US US05/812,892 patent/US4137371A/en not_active Expired - Lifetime
- 1977-07-06 FR FR7720820A patent/FR2358028A1/fr active Granted
- 1977-07-06 IT IT50161/77A patent/IT1079755B/it active
- 1977-07-06 CA CA282,104A patent/CA1073039A/en not_active Expired
- 1977-07-06 AU AU26799/77A patent/AU2679977A/en active Pending
- 1977-07-07 JP JP8149877A patent/JPS536842A/ja active Pending
- 1977-07-07 BR BR7704455A patent/BR7704455A/pt unknown
- 1977-07-07 GB GB28575/77A patent/GB1582085A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BR7704455A (pt) | 1978-04-04 |
| DE2730068A1 (de) | 1978-01-19 |
| FR2358028B1 (enExample) | 1984-03-16 |
| NL7607471A (nl) | 1978-01-10 |
| AU2679977A (en) | 1979-01-11 |
| ZA774021B (en) | 1978-05-30 |
| JPS536842A (en) | 1978-01-21 |
| BE856298A (nl) | 1977-12-30 |
| US4137371A (en) | 1979-01-30 |
| IT1079755B (it) | 1985-05-13 |
| FR2358028A1 (fr) | 1978-02-03 |
| GB1582085A (en) | 1980-12-31 |
| SE7707759L (sv) | 1978-01-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |