CA1062649A - Electrodeposition of tin-containing alloys and bath therefor - Google Patents
Electrodeposition of tin-containing alloys and bath thereforInfo
- Publication number
- CA1062649A CA1062649A CA248,731A CA248731A CA1062649A CA 1062649 A CA1062649 A CA 1062649A CA 248731 A CA248731 A CA 248731A CA 1062649 A CA1062649 A CA 1062649A
- Authority
- CA
- Canada
- Prior art keywords
- grams per
- per liter
- electroplating
- nickel
- ions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 title description 4
- 238000004070 electrodeposition Methods 0.000 title description 2
- 229910045601 alloy Inorganic materials 0.000 title 1
- 239000000956 alloy Substances 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 55
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 27
- 238000000576 coating method Methods 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 239000011248 coating agent Substances 0.000 claims abstract description 15
- FATUQANACHZLRT-KMRXSBRUSA-L calcium glucoheptonate Chemical compound [Ca+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)C([O-])=O FATUQANACHZLRT-KMRXSBRUSA-L 0.000 claims abstract description 13
- 239000008139 complexing agent Substances 0.000 claims abstract description 11
- 239000000758 substrate Substances 0.000 claims abstract description 11
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 claims abstract description 10
- 229940050410 gluconate Drugs 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 9
- -1 iron ions Chemical class 0.000 claims abstract description 9
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000007864 aqueous solution Substances 0.000 claims abstract description 8
- 229910052742 iron Inorganic materials 0.000 claims abstract description 8
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 7
- 239000010941 cobalt Substances 0.000 claims abstract description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001432 tin ion Inorganic materials 0.000 claims abstract description 7
- 239000000243 solution Substances 0.000 claims description 29
- 238000009713 electroplating Methods 0.000 claims description 11
- 230000001464 adherent effect Effects 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 15
- 229910052804 chromium Inorganic materials 0.000 abstract description 15
- 239000011651 chromium Substances 0.000 abstract description 15
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 229910000375 tin(II) sulfate Inorganic materials 0.000 description 7
- 238000007747 plating Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 239000002659 electrodeposit Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- RCIVOBGSMSSVTR-UHFFFAOYSA-L stannous sulfate Chemical compound [SnH2+2].[O-]S([O-])(=O)=O RCIVOBGSMSSVTR-UHFFFAOYSA-L 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- MEYVLGVRTYSQHI-UHFFFAOYSA-L cobalt(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Co+2].[O-]S([O-])(=O)=O MEYVLGVRTYSQHI-UHFFFAOYSA-L 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000000176 sodium gluconate Substances 0.000 description 2
- 235000012207 sodium gluconate Nutrition 0.000 description 2
- 229940005574 sodium gluconate Drugs 0.000 description 2
- FMYOMWCQJXWGEN-WNFIKIDCSA-M sodium;(2s,3r,4s,5r,6r)-2,3,4,5,6,7-hexahydroxyheptanoate Chemical compound [Na+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)C([O-])=O FMYOMWCQJXWGEN-WNFIKIDCSA-M 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229940095064 tartrate Drugs 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 229910019054 CoSO4-7H2O Inorganic materials 0.000 description 1
- 229910019099 CoSO4—7H2O Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/60—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of tin
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/562—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of iron or nickel or cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US58554875A | 1975-06-10 | 1975-06-10 | |
| US05/661,480 US4035249A (en) | 1975-06-10 | 1976-03-01 | Electrode position of tin-containing alloys and bath therefor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1062649A true CA1062649A (en) | 1979-09-18 |
Family
ID=27079429
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA248,731A Expired CA1062649A (en) | 1975-06-10 | 1976-03-23 | Electrodeposition of tin-containing alloys and bath therefor |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4035249A (en:Method) |
| JP (1) | JPS6025515B2 (en:Method) |
| AU (1) | AU499680B2 (en:Method) |
| BR (1) | BR7603673A (en:Method) |
| CA (1) | CA1062649A (en:Method) |
| DE (1) | DE2618638C3 (en:Method) |
| ES (1) | ES448766A1 (en:Method) |
| FR (1) | FR2314272A1 (en:Method) |
| IT (1) | IT1061232B (en:Method) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5838519B2 (ja) * | 1978-11-24 | 1983-08-23 | キザイ株式会社 | 黒色光沢錫↓−ニツケル合金電解メツキ液 |
| US4299671A (en) * | 1980-06-13 | 1981-11-10 | Hooker Chemicals & Plastics Corp. | Bath composition and method for electrodepositing cobalt-zinc alloys simulating a chromium plating |
| CA1193222A (en) | 1981-02-25 | 1985-09-10 | Wim M.J.C. Verberne | Electroplating cobalt alloy with zinc or tin from amine bath |
| AU548950B2 (en) * | 1982-02-03 | 1986-01-09 | Sumitomo Metal Industries Ltd. | Steel sheet with multilayer electroplating |
| JP2769614B2 (ja) * | 1986-06-04 | 1998-06-25 | ディップソール 株式会社 | 亜鉛−ニツケル合金用めつき浴 |
| JP4901120B2 (ja) * | 2005-03-29 | 2012-03-21 | 兵庫県 | 亜鉛を含むめっき皮膜 |
| CN109440149B (zh) * | 2018-11-23 | 2021-06-08 | 云南师范大学 | 一种电镀高铁-低锡合金的电镀液组成和工艺 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3881919A (en) * | 1974-01-07 | 1975-05-06 | Whyco Chromium Co | Ternary alloys |
-
1976
- 1976-03-01 US US05/661,480 patent/US4035249A/en not_active Expired - Lifetime
- 1976-03-23 CA CA248,731A patent/CA1062649A/en not_active Expired
- 1976-04-23 AU AU13299/76A patent/AU499680B2/en not_active Expired
- 1976-04-28 DE DE2618638A patent/DE2618638C3/de not_active Expired
- 1976-04-29 FR FR7612821A patent/FR2314272A1/fr active Granted
- 1976-05-03 IT IT49294/76A patent/IT1061232B/it active
- 1976-06-09 BR BR3673/76A patent/BR7603673A/pt unknown
- 1976-06-09 JP JP51066680A patent/JPS6025515B2/ja not_active Expired
- 1976-06-10 ES ES448766A patent/ES448766A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2618638B2 (de) | 1979-07-05 |
| JPS51149836A (en) | 1976-12-23 |
| JPS6025515B2 (ja) | 1985-06-18 |
| AU499680B2 (en) | 1979-04-26 |
| FR2314272A1 (fr) | 1977-01-07 |
| AU1329976A (en) | 1977-10-27 |
| BR7603673A (pt) | 1977-01-25 |
| US4035249A (en) | 1977-07-12 |
| DE2618638C3 (de) | 1980-03-06 |
| DE2618638A1 (de) | 1976-12-30 |
| ES448766A1 (es) | 1978-01-01 |
| IT1061232B (it) | 1983-02-28 |
| FR2314272B1 (en:Method) | 1980-08-22 |
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