CA1056231A - Procede d'argenture d'articles a base de polyamides - Google Patents
Procede d'argenture d'articles a base de polyamidesInfo
- Publication number
- CA1056231A CA1056231A CA205,877A CA205877A CA1056231A CA 1056231 A CA1056231 A CA 1056231A CA 205877 A CA205877 A CA 205877A CA 1056231 A CA1056231 A CA 1056231A
- Authority
- CA
- Canada
- Prior art keywords
- articles
- polyphenol
- weight
- polyamide
- treated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 21
- 229920002647 polyamide Polymers 0.000 title claims abstract description 12
- 239000004952 Polyamide Substances 0.000 title claims abstract description 10
- 150000008442 polyphenolic compounds Chemical class 0.000 claims abstract description 10
- 235000013824 polyphenols Nutrition 0.000 claims abstract description 10
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000007864 aqueous solution Substances 0.000 claims abstract description 7
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 6
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 5
- 230000008961 swelling Effects 0.000 claims abstract description 4
- 238000011282 treatment Methods 0.000 claims description 7
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 101100137177 Drosophila melanogaster polyph gene Proteins 0.000 claims description 2
- 239000004753 textile Substances 0.000 claims description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims 1
- 235000011114 ammonium hydroxide Nutrition 0.000 claims 1
- 238000007747 plating Methods 0.000 claims 1
- 239000000835 fiber Substances 0.000 abstract description 20
- 239000000243 solution Substances 0.000 abstract description 18
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 229910002651 NO3 Inorganic materials 0.000 abstract description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 230000005611 electricity Effects 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229920002302 Nylon 6,6 Polymers 0.000 description 3
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- JNKQKOKSOYJQIZ-UHFFFAOYSA-O azanium;silver;dinitrate Chemical compound [NH4+].[Ag+].[O-][N+]([O-])=O.[O-][N+]([O-])=O JNKQKOKSOYJQIZ-UHFFFAOYSA-O 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- HAAYBYDROVFKPU-UHFFFAOYSA-N silver;azane;nitrate Chemical compound N.N.[Ag+].[O-][N+]([O-])=O HAAYBYDROVFKPU-UHFFFAOYSA-N 0.000 description 2
- -1 wadding Substances 0.000 description 2
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 1
- 229920001342 Bakelite® Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- JPYHHZQJCSQRJY-UHFFFAOYSA-N Phloroglucinol Natural products CCC=CCC=CCC=CCC=CCCCCC(=O)C1=C(O)C=C(O)C=C1O JPYHHZQJCSQRJY-UHFFFAOYSA-N 0.000 description 1
- 244000007853 Sarothamnus scoparius Species 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000004637 bakelite Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 210000000078 claw Anatomy 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- XNRABACJWNCNEQ-UHFFFAOYSA-N silver;azane;nitrate Chemical compound N.[Ag+].[O-][N+]([O-])=O XNRABACJWNCNEQ-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/2006—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30
- C23C18/2046—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30 by chemical pretreatment
- C23C18/2053—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30 by chemical pretreatment only one step pretreatment
- C23C18/2066—Use of organic or inorganic compounds other than metals, e.g. activation, sensitisation with polymers
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/2006—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30
- C23C18/2026—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30 by radiant energy
- C23C18/2033—Heat
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31681—Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2418—Coating or impregnation increases electrical conductivity or anti-static quality
- Y10T442/2459—Nitrogen containing
Landscapes
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemically Coating (AREA)
- Artificial Filaments (AREA)
- Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7328614A FR2239539B1 (en, 2012) | 1973-08-01 | 1973-08-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1056231A true CA1056231A (fr) | 1979-06-12 |
Family
ID=9123608
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA205,877A Expired CA1056231A (fr) | 1973-08-01 | 1974-07-29 | Procede d'argenture d'articles a base de polyamides |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US4362779A (en, 2012) |
| JP (1) | JPS5045057A (en, 2012) |
| AR (1) | AR199856A1 (en, 2012) |
| BE (1) | BE818341A (en, 2012) |
| BR (1) | BR7406232D0 (en, 2012) |
| CA (1) | CA1056231A (en, 2012) |
| CH (2) | CH1050374A4 (en, 2012) |
| DE (1) | DE2437157C2 (en, 2012) |
| DK (1) | DK144531C (en, 2012) |
| ES (1) | ES428851A1 (en, 2012) |
| FI (1) | FI58163C (en, 2012) |
| FR (1) | FR2239539B1 (en, 2012) |
| GB (1) | GB1445772A (en, 2012) |
| IT (1) | IT1017826B (en, 2012) |
| LU (1) | LU70643A1 (en, 2012) |
| NL (1) | NL7410125A (en, 2012) |
| NO (1) | NO142359C (en, 2012) |
| SE (1) | SE7409903L (en, 2012) |
| SU (1) | SU544389A3 (en, 2012) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2040970B (en) * | 1978-12-19 | 1983-07-20 | Crown City Plating Co | Conditioning of caprolactam polymers for electroless plating |
| CH656401A5 (de) * | 1983-07-21 | 1986-06-30 | Suisse Horlogerie Rech Lab | Verfahren zur stromlosen abscheidung von metallen. |
| DE3337856A1 (de) * | 1983-10-18 | 1985-04-25 | Bayer Ag, 5090 Leverkusen | Verfahren zur aktivierung von substraten fuer die stromlose metallisierung |
| US4684762A (en) * | 1985-05-17 | 1987-08-04 | Raychem Corp. | Shielding fabric |
| AU580844B2 (en) * | 1984-11-13 | 1989-02-02 | Bentley-Harris Manufacturing Company, The | Shielding fabric and article |
| US4645574A (en) * | 1985-05-02 | 1987-02-24 | Material Concepts, Inc. | Continuous process for the sequential coating of polyamide filaments with copper and silver |
| US4710403A (en) * | 1986-05-05 | 1987-12-01 | Minnesota Mining And Manufacturing Company | Metallized polymers |
| FI95816C (fi) * | 1989-05-04 | 1996-03-25 | Ad Tech Holdings Ltd | Antimikrobinen esine ja menetelmä sen valmistamiseksi |
| US20030124256A1 (en) * | 2000-04-10 | 2003-07-03 | Omnishield, Inc. | Omnishield process and product |
| CN1156624C (zh) * | 2001-06-22 | 2004-07-07 | 朱红军 | 防集聚广谱抗菌纳米银针、纺织品及产业化生产工艺 |
| US8007904B2 (en) * | 2008-01-11 | 2011-08-30 | Fiber Innovation Technology, Inc. | Metal-coated fiber |
| CN109137481B (zh) * | 2018-07-24 | 2020-06-02 | 东华大学 | 一种基于材料溶胀收缩的功能改性的方法 |
| CN113445310B (zh) * | 2021-05-31 | 2022-05-24 | 苏州大学 | 一种镀银尼龙导电纤维及其制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1731261A (en) * | 1924-11-24 | 1929-10-15 | Radio Patents Corp | Method of metallizing the surfaces of insulating bands particularly for use in electric condensers |
| AT126123B (de) * | 1937-04-14 | 1932-01-11 | Max Ing Ow-Eschingen | Verfahren zur Herstellung von festhaftenden dichten Metallüberzügen auf fertigen Gegenständen ohne Formveränderung derselben während der Metallisierung. |
| US2351940A (en) * | 1940-03-13 | 1944-06-20 | Dupuis Jules | Method of making plated articles |
| US2986480A (en) * | 1960-05-18 | 1961-05-30 | Felix A Reiss | Method for depositing metals on nonconducting substrates |
| DE1283190B (de) | 1964-05-08 | 1969-09-11 | Intermetalon Ag | Verfahren zur Verbesserung der Haftfestigkeit von aufgedampften Metallen auf Textilien und Folien aus synthetischen Polyamiden |
| US3686019A (en) * | 1968-10-24 | 1972-08-22 | Asahi Kogyo Co Ltd | Process for the manufacture of fibrous mixtures having superior antistatic characteristics |
| US3686017A (en) * | 1970-10-05 | 1972-08-22 | Monsanto Co | Surface treatment of nylon shaped articles with aqueous reducing agents |
-
1973
- 1973-08-01 FR FR7328614A patent/FR2239539B1/fr not_active Expired
-
1974
- 1974-07-26 NL NL7410125A patent/NL7410125A/xx not_active Application Discontinuation
- 1974-07-29 CA CA205,877A patent/CA1056231A/fr not_active Expired
- 1974-07-29 BR BR623274A patent/BR7406232D0/pt unknown
- 1974-07-30 CH CH1050374D patent/CH1050374A4/xx unknown
- 1974-07-30 CH CH1050374A patent/CH586755B5/xx not_active IP Right Cessation
- 1974-07-30 JP JP8742574A patent/JPS5045057A/ja active Pending
- 1974-07-31 GB GB3384774A patent/GB1445772A/en not_active Expired
- 1974-07-31 SE SE7409903A patent/SE7409903L/ not_active Application Discontinuation
- 1974-07-31 LU LU70643A patent/LU70643A1/xx unknown
- 1974-07-31 NO NO742775A patent/NO142359C/no unknown
- 1974-07-31 DK DK409974A patent/DK144531C/da active
- 1974-07-31 BE BE147161A patent/BE818341A/xx unknown
- 1974-07-31 SU SU2051697A patent/SU544389A3/ru active
- 1974-07-31 AR AR25498674A patent/AR199856A1/es active
- 1974-08-01 DE DE2437157A patent/DE2437157C2/de not_active Expired
- 1974-08-01 FI FI2301/74A patent/FI58163C/fi active
- 1974-08-01 IT IT2587674A patent/IT1017826B/it active
- 1974-08-01 ES ES428851A patent/ES428851A1/es not_active Expired
-
1981
- 1981-05-08 US US06/262,210 patent/US4362779A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| BE818341A (fr) | 1975-01-31 |
| NO142359C (no) | 1980-08-06 |
| ES428851A1 (es) | 1976-08-16 |
| IT1017826B (it) | 1977-08-10 |
| CH1050374A4 (en, 2012) | 1976-10-29 |
| SU544389A3 (ru) | 1977-01-25 |
| DE2437157C2 (de) | 1983-05-05 |
| DK409974A (en, 2012) | 1975-04-01 |
| US4362779A (en) | 1982-12-07 |
| SE7409903L (en, 2012) | 1975-02-03 |
| NO742775L (en, 2012) | 1975-03-03 |
| FR2239539B1 (en, 2012) | 1976-04-30 |
| FI230174A7 (en, 2012) | 1975-02-02 |
| NO142359B (no) | 1980-04-28 |
| BR7406232D0 (pt) | 1975-05-27 |
| DK144531C (da) | 1982-09-06 |
| NL7410125A (nl) | 1975-02-04 |
| LU70643A1 (en, 2012) | 1974-12-10 |
| FI58163C (fi) | 1980-12-10 |
| AR199856A1 (es) | 1974-09-30 |
| CH586755B5 (en, 2012) | 1977-04-15 |
| FR2239539A1 (en, 2012) | 1975-02-28 |
| DE2437157A1 (de) | 1975-02-13 |
| GB1445772A (en) | 1976-08-11 |
| FI58163B (fi) | 1980-08-29 |
| JPS5045057A (en, 2012) | 1975-04-22 |
| DK144531B (da) | 1982-03-22 |
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