CA1037186A - Transparent storage-stable polysiloxanes which crosslink under atmospheric conditions - Google Patents
Transparent storage-stable polysiloxanes which crosslink under atmospheric conditionsInfo
- Publication number
- CA1037186A CA1037186A CA222,647A CA222647A CA1037186A CA 1037186 A CA1037186 A CA 1037186A CA 222647 A CA222647 A CA 222647A CA 1037186 A CA1037186 A CA 1037186A
- Authority
- CA
- Canada
- Prior art keywords
- weight
- mole
- methyl
- parts
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 polysiloxanes Polymers 0.000 title claims abstract description 58
- 229920001296 polysiloxane Polymers 0.000 title claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 60
- 239000000203 mixture Substances 0.000 claims abstract description 49
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 23
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 14
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 10
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 10
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 10
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 10
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 10
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 7
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 7
- 239000003054 catalyst Substances 0.000 claims abstract description 6
- 125000004423 acyloxy group Chemical group 0.000 claims abstract description 5
- 238000004438 BET method Methods 0.000 claims abstract description 4
- 125000003118 aryl group Chemical group 0.000 claims abstract description 4
- 125000001188 haloalkyl group Chemical group 0.000 claims abstract description 4
- 239000012763 reinforcing filler Substances 0.000 claims abstract description 4
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 3
- TVJPBVNWVPUZBM-UHFFFAOYSA-N [diacetyloxy(methyl)silyl] acetate Chemical compound CC(=O)O[Si](C)(OC(C)=O)OC(C)=O TVJPBVNWVPUZBM-UHFFFAOYSA-N 0.000 claims description 9
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 claims description 7
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 229910000077 silane Inorganic materials 0.000 claims description 4
- 239000004945 silicone rubber Substances 0.000 claims description 4
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 4
- VLFKGWCMFMCFRM-UHFFFAOYSA-N [diacetyloxy(phenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C1=CC=CC=C1 VLFKGWCMFMCFRM-UHFFFAOYSA-N 0.000 claims description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 3
- 230000007062 hydrolysis Effects 0.000 claims description 3
- 238000006460 hydrolysis reaction Methods 0.000 claims description 3
- HDNXAGOHLKHJOA-UHFFFAOYSA-N n-[bis(cyclohexylamino)-methylsilyl]cyclohexanamine Chemical compound C1CCCCC1N[Si](NC1CCCCC1)(C)NC1CCCCC1 HDNXAGOHLKHJOA-UHFFFAOYSA-N 0.000 claims description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- 125000005997 bromomethyl group Chemical group 0.000 claims description 2
- 125000002603 chloroethyl group Chemical group [H]C([*])([H])C([H])([H])Cl 0.000 claims description 2
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 claims description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000003944 tolyl group Chemical group 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Chemical group 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 description 20
- 239000005060 rubber Substances 0.000 description 19
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 15
- 239000012975 dibutyltin dilaurate Substances 0.000 description 14
- 229910002014 Aerosil® 130 Inorganic materials 0.000 description 13
- 239000000945 filler Substances 0.000 description 11
- 238000007872 degassing Methods 0.000 description 10
- 238000003860 storage Methods 0.000 description 10
- ZAEXPVSOLSDZRQ-UHFFFAOYSA-N [acetyloxy(dibutoxy)silyl] acetate Chemical compound CCCCO[Si](OC(C)=O)(OC(C)=O)OCCCC ZAEXPVSOLSDZRQ-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000011521 glass Substances 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- FZLSDZZNPXXBBB-KDURUIRLSA-N 5-chloro-N-[3-cyclopropyl-5-[[(3R,5S)-3,5-dimethylpiperazin-1-yl]methyl]phenyl]-4-(6-methyl-1H-indol-3-yl)pyrimidin-2-amine Chemical compound C[C@H]1CN(Cc2cc(Nc3ncc(Cl)c(n3)-c3c[nH]c4cc(C)ccc34)cc(c2)C2CC2)C[C@@H](C)N1 FZLSDZZNPXXBBB-KDURUIRLSA-N 0.000 description 1
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 1
- 229910002019 Aerosil® 380 Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- JCYZMTMYPZHVBF-UHFFFAOYSA-N Melarsoprol Chemical compound NC1=NC(N)=NC(NC=2C=CC(=CC=2)[As]2SC(CO)CS2)=N1 JCYZMTMYPZHVBF-UHFFFAOYSA-N 0.000 description 1
- 240000005428 Pistacia lentiscus Species 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- PCHPORCSPXIHLZ-UHFFFAOYSA-N diphenhydramine hydrochloride Chemical compound [Cl-].C=1C=CC=CC=1C(OCC[NH+](C)C)C1=CC=CC=C1 PCHPORCSPXIHLZ-UHFFFAOYSA-N 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/70—Siloxanes defined by use of the MDTQ nomenclature
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2413850A DE2413850C3 (de) | 1974-03-22 | 1974-03-22 | Bei Zutritt von Wasser oder Wasserdampf zu transparenten Elastomeren vernetzbare Polysüoxanforrrurtasse |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1037186A true CA1037186A (en) | 1978-08-22 |
Family
ID=5910859
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA222,647A Expired CA1037186A (en) | 1974-03-22 | 1975-03-20 | Transparent storage-stable polysiloxanes which crosslink under atmospheric conditions |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US4001168A (en, 2012) |
| JP (1) | JPS5825380B2 (en, 2012) |
| AT (1) | AT348761B (en, 2012) |
| BE (1) | BE826962A (en, 2012) |
| CA (1) | CA1037186A (en, 2012) |
| CH (1) | CH614226A5 (en, 2012) |
| DE (1) | DE2413850C3 (en, 2012) |
| ES (1) | ES435906A1 (en, 2012) |
| FI (1) | FI62124C (en, 2012) |
| FR (1) | FR2264846B1 (en, 2012) |
| GB (1) | GB1468467A (en, 2012) |
| IT (1) | IT1032379B (en, 2012) |
| NL (1) | NL176860C (en, 2012) |
| NO (1) | NO144391C (en, 2012) |
| SE (1) | SE408802B (en, 2012) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2929635A1 (de) * | 1979-07-21 | 1981-02-12 | Bayer Ag | Polysiloxanformmassen |
| DE3018548A1 (de) * | 1980-05-14 | 1981-11-19 | Wacker-Chemie GmbH, 8000 München | Zu elastischem strahlenschutzmaterial vernetzbare massen und elastomere aus solchen massen |
| US4418165A (en) * | 1980-06-03 | 1983-11-29 | Dow Corning Corporation | Optically clear silicone compositions curable to elastomers |
| FR2531095B1 (fr) * | 1982-07-30 | 1987-08-14 | Rhone Poulenc Spec Chim | Compositions organopolysiloxaniques monocomposantes comportant en tant que reticulants des silanes a groupements acyloxyle ou cetoniminoxyle et catalysees par des derives organiques du titane |
| FR2539422B1 (fr) * | 1983-01-13 | 1986-05-23 | Rhone Poulenc Spec Chim | Compositions organopolysiloxaniques monocomposantes comportant en tant que reticulants des silanes a groupements acyloxyle ou cetoniminoxyle et catalysees par des derives organiques du titane |
| GB8401016D0 (en) * | 1984-01-14 | 1984-02-15 | Hagen Perennatorwerk | Organopolysiloxane compositions |
| JPS62197454A (ja) * | 1986-02-25 | 1987-09-01 | Toray Silicone Co Ltd | 加熱加硫型オルガノポリシロキサン組成物 |
| US4705877A (en) * | 1987-02-25 | 1987-11-10 | Dow Corning Corporation | Novel aminohydrocarbyl-substituted ketoximosilanes |
| JP2782068B2 (ja) * | 1988-08-08 | 1998-07-30 | 東芝シリコーン株式会社 | 透明シリコーンコンパウンド組成物 |
| DE4033096A1 (de) * | 1990-10-18 | 1992-04-23 | Bayer Ag | Feuchtigkeitshaertende einkomponenten-polysiloxanmasse |
| US6471820B1 (en) * | 1995-01-05 | 2002-10-29 | 3M Innovative Properties | Moisture-curable silicone composition |
| US7291386B2 (en) * | 2004-08-26 | 2007-11-06 | 3M Innovative Properties Company | Antiglare coating and articles |
| US7294405B2 (en) | 2004-08-26 | 2007-11-13 | 3M Innovative Properties Company | Antiglare coating and articles |
| FR2946657A1 (fr) | 2009-06-12 | 2010-12-17 | Bluestar Silicones France | Procede d'etancheification et d'assemblage de composants d'un groupe moto-propulseur |
| FR2946656A1 (fr) | 2009-06-12 | 2010-12-17 | Bluestar Silicones France | Procede d'etancheification et d'assemblage de composants d'un groupe moto-propulseur |
| FR2946654A1 (fr) | 2009-06-15 | 2010-12-17 | Bluestar Silicones France | Procede d'enduction d'une composition silicone ne contenant pas d'etain sur un support souple. |
| FR2946655A1 (fr) | 2009-06-15 | 2010-12-17 | Bluestar Silicones France | Procede d'enduction d'une composition silicone ne contenant pas d'etain sur un support souple. |
| FR3014106B1 (fr) | 2013-12-03 | 2017-03-10 | Bluestar Silicones France | Composition silicone durcissable en presence d'eau ou d'humidite de l'air |
| FR3020067A1 (fr) | 2014-04-18 | 2015-10-23 | Bluestar Silicones France | Procede d'enduction d'un composition silicone sur un support souple |
| CN108329694B (zh) * | 2018-01-31 | 2022-02-11 | 上海璞临医疗科技有限公司 | 一种心血管模型用的高透明高强度硅胶及其制备方法 |
| US11441034B2 (en) | 2018-04-19 | 2022-09-13 | Wacker Chemie Ag | Polysiloxane composition |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| LU35994A1 (fr) * | 1957-07-12 | 1958-06-17 | Rhone Poulenc Sa | Procédé de fabrication d'elastomères à base de diorgano-polysiloxanes et produits ainsi obtenus. |
| US3065194A (en) * | 1959-07-16 | 1962-11-20 | Wacker Chemie Gmbh | Method of preparing silicone rubber compositions |
| US3359237A (en) * | 1964-02-27 | 1967-12-19 | Rhone Poulenc Sa | Organosilicon compounds and their use |
| US3457214A (en) * | 1965-12-15 | 1969-07-22 | Gen Electric | Low temperature vulcanizing composition and article made therefrom |
| US3624023A (en) * | 1970-04-09 | 1971-11-30 | Dow Corning | Transparent silicone rubber vulcanizable under ambient conditions |
| US3689454A (en) * | 1971-01-06 | 1972-09-05 | Gen Electric | Curable compositions |
-
1974
- 1974-03-22 DE DE2413850A patent/DE2413850C3/de not_active Expired
-
1975
- 1975-03-10 NO NO750786A patent/NO144391C/no unknown
- 1975-03-18 US US05/559,473 patent/US4001168A/en not_active Expired - Lifetime
- 1975-03-20 IT IT48691/75A patent/IT1032379B/it active
- 1975-03-20 AT AT214575A patent/AT348761B/de not_active IP Right Cessation
- 1975-03-20 NL NLAANVRAGE7503346,A patent/NL176860C/xx not_active IP Right Cessation
- 1975-03-20 SE SE7503233A patent/SE408802B/sv not_active IP Right Cessation
- 1975-03-20 CH CH357775A patent/CH614226A5/xx not_active IP Right Cessation
- 1975-03-20 FI FI750828A patent/FI62124C/fi not_active IP Right Cessation
- 1975-03-20 CA CA222,647A patent/CA1037186A/en not_active Expired
- 1975-03-21 FR FR7508986A patent/FR2264846B1/fr not_active Expired
- 1975-03-21 GB GB1192375A patent/GB1468467A/en not_active Expired
- 1975-03-21 BE BE154565A patent/BE826962A/xx not_active IP Right Cessation
- 1975-03-22 ES ES435906A patent/ES435906A1/es not_active Expired
- 1975-03-22 JP JP50033548A patent/JPS5825380B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| AT348761B (de) | 1979-03-12 |
| NO750786L (en, 2012) | 1975-09-23 |
| GB1468467A (en) | 1977-03-30 |
| FI750828A7 (en, 2012) | 1975-09-23 |
| NO144391B (no) | 1981-05-11 |
| DE2413850C3 (de) | 1979-01-11 |
| NO144391C (no) | 1981-08-19 |
| US4001168A (en) | 1977-01-04 |
| BE826962A (fr) | 1975-09-22 |
| NL7503346A (nl) | 1975-09-24 |
| FR2264846A1 (en, 2012) | 1975-10-17 |
| JPS5825380B2 (ja) | 1983-05-27 |
| ES435906A1 (es) | 1977-03-16 |
| IT1032379B (it) | 1979-05-30 |
| NL176860B (nl) | 1985-01-16 |
| DE2413850B2 (de) | 1977-04-28 |
| JPS50128748A (en, 2012) | 1975-10-11 |
| FI62124C (fi) | 1982-11-10 |
| FR2264846B1 (en, 2012) | 1978-12-15 |
| FI62124B (fi) | 1982-07-30 |
| SE408802B (sv) | 1979-07-09 |
| NL176860C (nl) | 1985-06-17 |
| DE2413850A1 (de) | 1975-10-16 |
| SE7503233L (en, 2012) | 1975-09-23 |
| CH614226A5 (en, 2012) | 1979-11-15 |
| ATA214575A (de) | 1978-07-15 |
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