CA1021354A - Methanol synthesis catalyst - Google Patents

Methanol synthesis catalyst

Info

Publication number
CA1021354A
CA1021354A CA166,558A CA166558A CA1021354A CA 1021354 A CA1021354 A CA 1021354A CA 166558 A CA166558 A CA 166558A CA 1021354 A CA1021354 A CA 1021354A
Authority
CA
Canada
Prior art keywords
methanol synthesis
synthesis catalyst
catalyst
methanol
synthesis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA166,558A
Other languages
English (en)
Other versions
CA166558S (en
Inventor
Alvin B. Stiles
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Application granted granted Critical
Publication of CA1021354A publication Critical patent/CA1021354A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/86Chromium
    • B01J23/868Chromium copper and chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA166,558A 1972-04-20 1973-03-16 Methanol synthesis catalyst Expired CA1021354A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US24590272A 1972-04-20 1972-04-20

Publications (1)

Publication Number Publication Date
CA1021354A true CA1021354A (en) 1977-11-22

Family

ID=22928571

Family Applications (1)

Application Number Title Priority Date Filing Date
CA166,558A Expired CA1021354A (en) 1972-04-20 1973-03-16 Methanol synthesis catalyst

Country Status (9)

Country Link
US (1) US4111847A (ru)
JP (1) JPS4917391A (ru)
BE (1) BE798219A (ru)
CA (1) CA1021354A (ru)
DE (1) DE2320192A1 (ru)
FR (1) FR2181002B1 (ru)
GB (1) GB1436773A (ru)
IT (1) IT984318B (ru)
NL (1) NL7304618A (ru)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4588848A (en) * 1984-11-01 1986-05-13 Air Products And Chemicals, Inc. Synthesis of neoalkanols
US4593147A (en) * 1984-11-01 1986-06-03 Air Products And Chemicals, Inc. Synthesis of neoalkanes

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2352588A1 (fr) 1976-05-28 1977-12-23 Catalyse Soc Prod Francais Catalyseur renfermant de l'oxyde de cuivre et de l'oxyde de zinc, sa preparation et son utilisation dans les reactions de conversion de l'oxyde de carbone
DE2846614C3 (de) 1978-10-26 1982-05-19 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Methanol
DE3005551A1 (de) * 1980-02-14 1981-08-20 Süd-Chemie AG, 8000 München Katalysator zur synthese von methanol und hoehere alkohole enthaltenden alkoholgemischen
DE3005550A1 (de) * 1980-02-14 1981-08-20 Süd-Chemie AG, 8000 München Verfahren zur herstellung von olefinen
EP0047345B1 (en) * 1980-08-28 1983-12-07 Theodore Oscar Wentworth Process for the synthesis of methanol from hydrogen and the oxides of carbon using catalysts
JPS57130547A (en) * 1981-02-06 1982-08-13 Mitsubishi Gas Chem Co Inc Catalyst for methanol synthesis
US4423155A (en) * 1981-02-20 1983-12-27 Mobil Oil Corporation Dimethyl ether synthesis catalyst
US4376721A (en) * 1981-07-22 1983-03-15 Electric Power Research Institute, Inc. Methanol synthesis catalyst and method for its preparation
US4375424A (en) * 1981-10-21 1983-03-01 Shell Oil Company Catalyst for the preparation of dimethyl ether
JPS5932949A (ja) * 1982-08-13 1984-02-22 Mitsubishi Gas Chem Co Inc メタノ−ル合成用触媒
EP0109703B1 (en) * 1982-11-22 1986-03-19 Shell Internationale Researchmaatschappij B.V. Catalyst preparation
DE3317725A1 (de) * 1983-05-16 1984-11-22 Süd-Chemie AG, 8000 München Katalysator fuer die methanolsynthese
JPS60106534A (ja) * 1983-11-14 1985-06-12 Mitsubishi Gas Chem Co Inc メタノ−ル合成用流動触媒
FR2558738B1 (fr) * 1984-01-27 1987-11-13 Inst Francais Du Petrole Procede de fabrication de catalyseurs contenant du cuivre, du zinc et de l'aluminium, utilisables pour la production de methanol a partir de gaz de synthese
DE3403492A1 (de) * 1984-02-02 1985-08-08 Metallgesellschaft Ag, 6000 Frankfurt Verfahren zur herstellung einer mischung aus methanol und hoeheren alkoholen
DE3403491A1 (de) * 1984-02-02 1985-08-14 Süd-Chemie AG, 8000 München Katalysator zur synthese von methanol und hoehere alkohole enthaltenden alkoholgemischen
FR2560531B1 (fr) * 1984-03-02 1988-04-08 Inst Francais Du Petrole Procede de fabrication de catalyseurs contenant du cuivre, du zinc, de l'aluminium et au moins un metal du groupe forme par les terres rares et le zirconium et utilisation des catalyseurs obtenus pour les reactions mettant en jeu un gaz de synthese
DE3447782A1 (de) * 1984-12-29 1986-07-10 Henkel Kgaa Verfahren zur aktivierung und stabilisierung von katalysatormassen
US4677091A (en) * 1985-07-15 1987-06-30 The Standard Oil Company Process for the preparation of mixed metal oxide catalysts
GB8610196D0 (en) * 1986-04-25 1986-05-29 Ici Plc Sulphur compounds removal
US4876402A (en) * 1986-11-03 1989-10-24 Union Carbide Chemicals And Plastics Company Inc. Improved aldehyde hydrogenation process
US4762817A (en) * 1986-11-03 1988-08-09 Union Carbide Corporation Aldehyde hydrogenation catalyst
US4957893A (en) * 1987-03-05 1990-09-18 Ethyl Corporation Catalyst for making amines from alcohols
DE3837308A1 (de) * 1988-11-03 1990-05-10 Basf Ag Kupferhaltiger katalysator zur tieftemperaturkonvertierung
US5622907A (en) * 1989-04-28 1997-04-22 Electric Power Research Institute, Inc. Post-reducing treatment of alcohol synthesis catalysts with carbon dioxide
US5155086A (en) * 1989-09-12 1992-10-13 Engelhard Corporation Hydrogenation catalyst, process for preparing and process of using said catalyst
US5345005A (en) * 1989-09-12 1994-09-06 Engelhard Corporation Hydrogenation catalyst, process for preparing and process of using said catalyst
JPH0635401B2 (ja) * 1990-09-13 1994-05-11 工業技術院長 二酸化炭素からのメタノールの製造法
JPH0637409B2 (ja) * 1990-09-13 1994-05-18 工業技術院長 炭酸ガスの接触水素化によるメタノールの製造方法
US5134108A (en) * 1991-05-22 1992-07-28 Engelhard Corporation Process for preparing catalyst with copper or zinc and with chromium, molybdenum, tungsten, or vanadium, and product thereof
US5413749A (en) 1993-06-04 1995-05-09 Wheelabrator Engineered Systems Inc. Process of making beads for a liquid purification bed
JPH08299796A (ja) * 1995-05-11 1996-11-19 Mitsubishi Gas Chem Co Inc メタノール合成触媒の製造法
US6147125A (en) * 1996-05-13 2000-11-14 Nkk Corporation Method and apparatus for producing dimethyl ether
US7205258B2 (en) * 2003-06-26 2007-04-17 Scm Metal Products, Inc. Catalysts for the production of methylchlorosilanes using zinc oxide promoters
US20050020446A1 (en) * 2003-07-23 2005-01-27 Choudhary Tushar V. Desulfurization and novel process for same
US7351328B2 (en) * 2003-07-23 2008-04-01 China Petroleum & Chemical Corporation Desulfurization and novel process for same
DE102005020630A1 (de) * 2005-05-03 2006-11-23 Süd-Chemie AG Herstellung von Cu/Zn/Al-Katalysatoren über den Formiatweg
KR20070019428A (ko) * 2005-08-12 2007-02-15 에스케이 주식회사 유기황화합물 제거용 탈황제, 이의 제조방법 및 이를이용한 유기황화합물의 제거방법
AU2008316597B2 (en) 2007-10-25 2014-01-23 Landmark Ip Holdings, Llc System and method for anaerobic digestion of biomasses
US9295978B2 (en) 2012-02-15 2016-03-29 Basf Corporation Catalyst and method for the direct synthesis of dimethyl ether from synthesis gas
CN103372445B (zh) * 2012-04-13 2015-05-13 中国石油化工股份有限公司 一种铜锌系催化剂的制备方法
CN103372442B (zh) * 2012-04-13 2015-04-15 中国石油化工股份有限公司 含铜催化剂的制备方法
WO2015084575A2 (en) 2013-12-06 2015-06-11 Exxonmobil Chemical Patents Inc. Production of c2+ olefins
US9682899B2 (en) 2013-12-06 2017-06-20 Exxonmobil Chemical Patents Inc. Hydrocarbon conversion
WO2015084576A2 (en) 2013-12-06 2015-06-11 Exxonmobil Chemical Patents Inc. Hydrocarbon conversion
US10131588B2 (en) 2013-12-06 2018-11-20 Exxonmobil Chemical Patents Inc. Production of C2+ olefins
WO2015147919A1 (en) 2014-03-25 2015-10-01 Exxonmobil Chemical Patents Inc. Production of aromatics and c2+ olefins
DE102016225171A1 (de) 2016-12-15 2018-06-21 Clariant International Ltd Tablettierter Katalysator für die Methanolsynthese mit erhöhter mechanischer Stabilität
CN113509937B (zh) * 2020-04-10 2023-05-16 中国石油化工股份有限公司 一种含铜催化剂及其制备方法
CN112221509B (zh) * 2020-10-16 2021-10-15 西南化工研究设计院有限公司 一种高稳定性甲醇合成催化剂的制备方法
CN114602477B (zh) * 2022-03-29 2023-10-20 扬州大学 用于co2低温制甲醇的双壳空心铜锌基催化剂及其制备方法
CN114939412B (zh) * 2022-06-08 2023-05-23 西南化工研究设计院有限公司 一种高选择性甲醇合成催化剂的制备方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1908696A (en) * 1930-01-16 1933-05-16 Karpen & Bros S Catalyst for methanol manufacture and method of producing same
US2061470A (en) * 1933-11-16 1936-11-17 Du Pont Production of methanol and other carbon compounds and catalytic agents for use therein
US3326956A (en) * 1962-06-08 1967-06-20 Ici Ltd Production of oxygenated hydrocarbons
GB1010871A (en) * 1962-08-24 1965-11-24 Ici Ltd Water-gas conversion and catalysts therefor
US3961037A (en) * 1965-01-05 1976-06-01 Imperial Chemical Industries Limited Process for forming hydrogen and carbon dioxide using a catalyst consisting essentially of oxides of copper, zinc and aluminum or magnesium
FR1489682A (fr) * 1965-08-18 1967-07-21 Ici Ltd Procédé de synthèse du méthanol
GB1245036A (en) * 1969-05-28 1971-09-02 Haldor Frederik Axel Topsoe Improvements in or relating to the preparation of catalysts
NL7106825A (ru) * 1970-05-19 1971-11-23
US3689575A (en) * 1970-12-11 1972-09-05 Bethlehem Steel Corp Methanol synthesis
US3790505A (en) * 1971-05-04 1974-02-05 Catalysts & Chem Inc Low temperature methanol synthesis catalyst

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4588848A (en) * 1984-11-01 1986-05-13 Air Products And Chemicals, Inc. Synthesis of neoalkanols
US4593147A (en) * 1984-11-01 1986-06-03 Air Products And Chemicals, Inc. Synthesis of neoalkanes

Also Published As

Publication number Publication date
IT984318B (it) 1974-11-20
BE798219A (fr) 1973-07-31
JPS4917391A (ru) 1974-02-15
NL7304618A (ru) 1973-10-23
US4111847A (en) 1978-09-05
FR2181002B1 (ru) 1977-02-04
FR2181002A1 (ru) 1973-11-30
DE2320192A1 (de) 1973-10-25
GB1436773A (ru) 1976-05-26

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