CA1002056A - Catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxides - Google Patents

Catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxides

Info

Publication number
CA1002056A
CA1002056A CA124,017A CA124017A CA1002056A CA 1002056 A CA1002056 A CA 1002056A CA 124017 A CA124017 A CA 124017A CA 1002056 A CA1002056 A CA 1002056A
Authority
CA
Canada
Prior art keywords
hydroperoxides
catalyst
oxirane compounds
epoxidizing olefins
producing oxirane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA124,017A
Other languages
English (en)
Other versions
CA124017S (en
Inventor
Harald P. Wulff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Application granted granted Critical
Publication of CA1002056A publication Critical patent/CA1002056A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0254—Nitrogen containing compounds on mineral substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0275—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Tubes (AREA)
CA124,017A 1970-10-01 1971-09-29 Catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxides Expired CA1002056A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US7738570A 1970-10-01 1970-10-01

Publications (1)

Publication Number Publication Date
CA1002056A true CA1002056A (en) 1976-12-21

Family

ID=22137754

Family Applications (1)

Application Number Title Priority Date Filing Date
CA124,017A Expired CA1002056A (en) 1970-10-01 1971-09-29 Catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxides

Country Status (16)

Country Link
JP (1) JPS5440526B1 (no)
AT (1) AT315135B (no)
BE (1) BE773363A (no)
CA (1) CA1002056A (no)
CH (1) CH568792A5 (no)
DE (1) DE2148637C3 (no)
DK (1) DK150592C (no)
ES (1) ES395527A1 (no)
FR (1) FR2109867A5 (no)
GB (1) GB1339309A (no)
IE (1) IE35681B1 (no)
IT (1) IT938878B (no)
NL (1) NL153872C (no)
NO (2) NO129888B (no)
SE (1) SE377525B (no)
ZA (1) ZA716592B (no)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK151016C (da) * 1972-03-13 1988-06-27 Shell Int Research Fremgangsmaade til fremstilling af oxiranforbindelser ved omsaetning af en olefinisk umaettet forbindelse med et organisk hydroperoxid i naervaerelse af en katalysator
DE3734138A1 (de) * 1987-10-09 1989-04-20 Scharmer Klaus Dr Ing Saurer katalysator und verfahren zum herstellen des katalysators
CA2002341A1 (en) * 1988-11-09 1990-05-09 Takehisa Nakanishi Method for preparing epichlorohydrins
US5081267A (en) * 1989-10-05 1992-01-14 Arco Chemical Technology, Inc. Epoxidation process
US5319114A (en) * 1993-09-23 1994-06-07 Arco Chemical Technology, L. P. Olefin epoxidation using a carbon molecular sieve impregnated with a transition metal
EP0752916B1 (en) * 1994-03-31 1999-12-08 Infineum USA L.P. Polymerisation reactions with supported lewis acid catalysts
DE19545042A1 (de) * 1995-12-02 1997-06-05 Studiengesellschaft Kohle Mbh Amorphe mikroporöse Mischoxidkatalysatoren mit kontrollierter Oberflächenpolarität für die selektive heterogene Katalyse Adsorption und Stofftrennung
DE19743165A1 (de) * 1997-09-30 1999-04-01 Studiengesellschaft Kohle Mbh Selektive Alkylierung von Aromaten mit oberflächenmodifizierten mikroporösen Mischoxiden
WO1999043431A1 (fr) * 1998-02-24 1999-09-02 Japan As Represented By Director-General Of Agency Of Industrial Science And Technology Catalyseur d'oxydation partielle d'hydrocarbure insature
SG82626A1 (en) 1998-08-04 2001-08-21 Sumitomo Chemical Co Titanium-containing silicon oxide catalyst
SG73663A1 (en) * 1998-08-04 2000-06-20 Sumitomo Chemical Co A process for producing propylene oxide
JP2000279809A (ja) * 1999-03-30 2000-10-10 Nippon Shokubai Co Ltd エポキシド製造用触媒及びエポキシドの製法
DE19925926A1 (de) * 1999-06-08 2000-12-14 Bayer Ag Katalysatoren auf Basis Titan-haltiger, organisch-anorganischer Hybridmaterialien zur selektiven Oxidation von Kohlenwasserstoffen
JP4694712B2 (ja) * 2001-01-15 2011-06-08 丸善石油化学株式会社 チタン含有固体触媒及びこれを用いたエポキシ化合物の製造法
JP6634179B1 (ja) * 2018-07-30 2020-01-22 花王株式会社 エポキシアルカンの製造方法、及び固体酸化触媒
WO2021142635A1 (zh) * 2020-01-14 2021-07-22 万华化学集团股份有限公司 一种丙烯环氧化催化剂的制备方法及其用途
CN113181961B (zh) * 2020-01-14 2022-09-20 万华化学集团股份有限公司 一种丙烯环氧化催化剂的制备方法及其用途

Also Published As

Publication number Publication date
NO138883B (no) 1978-08-21
GB1339309A (en) 1973-12-05
DE2148637C3 (de) 1982-04-22
NL153872B (nl) 1977-07-15
CH568792A5 (no) 1975-11-14
NO129888B (no) 1974-06-10
IT938878B (it) 1973-02-10
IE35681L (en) 1972-04-01
DK150592B (da) 1987-04-06
ES395527A1 (es) 1973-12-16
NL153872C (nl) 1981-07-16
BE773363A (nl) 1972-03-30
IE35681B1 (en) 1976-04-28
JPS5440526B1 (no) 1979-12-04
DE2148637B2 (de) 1981-02-26
ZA716592B (en) 1972-06-28
AU3399671A (en) 1973-04-19
FR2109867A5 (no) 1972-05-26
AT315135B (de) 1974-05-10
DE2148637A1 (de) 1972-04-06
DK150592C (da) 1987-10-05
NO138883C (no) 1978-11-29
SE377525B (no) 1975-07-14
NL7113338A (no) 1972-04-05

Similar Documents

Publication Publication Date Title
CA1002056A (en) Catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxides
ZA702171B (en) A process for epoxidizing olefins with hydroperoxides
CA966495A (en) Process for epoxidizing olefins with hydroperoxides for producing oxirane compounds
CA1015761A (en) Catalysts for producing oxirane compounds
ZA702172B (en) A process for epoxidizing olefins with hydroperoxides
ZA7175B (en) Process for epoxidizing olefins with hydroperoxides
AU457594B2 (en) An improved catalyst for producing oxirane compounds by epoxidizing olefins' with hydroperoxides
AU450657B2 (en) A process for epoxidizing olefins with hydroperoxides for producing oxirane compounds
AU3042071A (en) A process for epoxidizing olefins with hydroperoxides for producing oxirane compounds
CA967582A (en) Method for the epoxidation of ethylene
ZA702173B (en) A process for epoxidizing olefins with hydroperoxides
CA980321A (en) Epoxidation of olefins using novel catalyst system
CA939679A (en) Process for epoxidizing olefins with hydroperoxides
AU447972B2 (en) Process for epoxidizing olefins with hydroperoxides
CA910334A (en) Process for epoxidizing olefins with hydroperoxides
CA910337A (en) Process for epoxidizing olefins with hydroperoxides
CA910913A (en) Process for epoxidizing olefins with hydroperoxides
CA910336A (en) Process for epoxidizing olefins with hydroperoxides
CA910335A (en) Process for epoxidizing olefins with hydroperoxides
AU438764B2 (en) A process for epoxidizing olefins with organic hydroperoxides
AU438765B2 (en) A process for epoxidizing olefins with organic hydroperoxides
AU2412971A (en) Process for epoxidizing olefins with hydroperoxides
AU1325470A (en) A process for epoxidizing olefins with organic hydroperoxides
AU1325170A (en) A process for epoxidizing olefins with organic hydroperoxides
AU439374B2 (en) A process for epoxidizing olefins with organic hydroperoxides