BRPI1008919A8 - Processo para separação e retorno parcial de ródio e/ou de compostos complexos cataliticamente ativos do mesmo a partir de uma mistura de reação - Google Patents
Processo para separação e retorno parcial de ródio e/ou de compostos complexos cataliticamente ativos do mesmo a partir de uma mistura de reaçãoInfo
- Publication number
- BRPI1008919A8 BRPI1008919A8 BRPI1008919A BRPI1008919A BRPI1008919A8 BR PI1008919 A8 BRPI1008919 A8 BR PI1008919A8 BR PI1008919 A BRPI1008919 A BR PI1008919A BR PI1008919 A BRPI1008919 A BR PI1008919A BR PI1008919 A8 BRPI1008919 A8 BR PI1008919A8
- Authority
- BR
- Brazil
- Prior art keywords
- reaction mixture
- catalytically active
- complex compounds
- transition metal
- separation
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 5
- 238000000926 separation method Methods 0.000 title abstract 4
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 239000011541 reaction mixture Substances 0.000 title abstract 3
- 229910052703 rhodium Inorganic materials 0.000 title abstract 2
- 239000010948 rhodium Substances 0.000 title abstract 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052723 transition metal Inorganic materials 0.000 abstract 5
- 150000003624 transition metals Chemical class 0.000 abstract 5
- 239000000047 product Substances 0.000 abstract 3
- 239000012528 membrane Substances 0.000 abstract 2
- 238000001179 sorption measurement Methods 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000012465 retentate Substances 0.000 abstract 1
- BGEHHAVMRVXCGR-UHFFFAOYSA-N tridecanal Chemical class CCCCCCCCCCCCC=O BGEHHAVMRVXCGR-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
- B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/027—Nanofiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4061—Regeneration or reactivation of catalysts containing metals involving membrane separation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/26—Further operations combined with membrane separation processes
- B01D2311/2626—Absorption or adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Water Supply & Treatment (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
PROCESSO PARA SEPARAÇÃO E RETORNO PARCIAL DE RÓDIO OU COMPOSTOS COMPLEXOS CATALITICAMENTE ATIVOS DO MESMO DE CORRENTES DE PROCESSO. A presente invenção refere-se a um processo para separação e retorno parcial de metais de transição e/ou compostos complexos cataliticamente ativos dos mesmos de uma mistura de reação por combinação de uma separação por membrana de pelo menos um estágio e uma adsorção, sendo que uma corrente contendo catalisador, que contém um metal de transição, é dividida através de uma etapa de separação por membrana de um estágio em uma corrente de produto de retenção, enriquecida com metal de transição, que é retornada à mistura de reação, e em uma corrente de produto de permeação reduzida em metal de transição, e a corrente de produto de permeação reduzida em metal de transição é conduzida, ainda, a uma etapa de adsorção. A invenção refere-se, adicionalmente, a um processo para produção de tridecanais.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009001230A DE102009001230A1 (de) | 2009-02-27 | 2009-02-27 | Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen |
| DE102009001230.3 | 2009-02-27 | ||
| PCT/EP2010/052390 WO2010097428A1 (de) | 2009-02-27 | 2010-02-25 | Verfahren zur abtrennung und teilweisen rückführung von rhodium bzw. dessen katalytisch wirksamen komplexverbindungen aus prozessströmen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| BRPI1008919A2 BRPI1008919A2 (pt) | 2016-03-15 |
| BRPI1008919A8 true BRPI1008919A8 (pt) | 2017-12-12 |
| BRPI1008919B1 BRPI1008919B1 (pt) | 2020-10-20 |
Family
ID=42236806
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI1008919-5A BRPI1008919B1 (pt) | 2009-02-27 | 2010-02-25 | processo para separação e retorno parcial de ródio e/ou de compostos complexos cataliticamente ativos do mesmo a partir de uma mistura de reação |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US8748643B2 (pt) |
| EP (1) | EP2401060B1 (pt) |
| JP (1) | JP5896748B2 (pt) |
| KR (1) | KR20110124760A (pt) |
| CN (1) | CN102333580A (pt) |
| BR (1) | BRPI1008919B1 (pt) |
| DE (1) | DE102009001230A1 (pt) |
| ES (1) | ES2561653T3 (pt) |
| MX (1) | MX2011009007A (pt) |
| MY (1) | MY153625A (pt) |
| RU (1) | RU2011139167A (pt) |
| SG (1) | SG174171A1 (pt) |
| WO (1) | WO2010097428A1 (pt) |
| ZA (1) | ZA201106307B (pt) |
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| DE102008043422B3 (de) | 2008-11-03 | 2010-01-07 | Evonik Degussa Gmbh | Verfahren zur Aufreinigung niedermolekularer Hydridosilane |
| DE102009001225A1 (de) | 2009-02-27 | 2010-09-02 | Evonik Oxeno Gmbh | Verfahren zur Anreicherung eines Homogenkatalysators aus einem Prozessstrom |
| DE102009027978A1 (de) | 2009-07-23 | 2011-01-27 | Evonik Oxeno Gmbh | Verfahren zur Herstellung von Decancarbonsäuren |
| US20120123079A1 (en) | 2009-07-23 | 2012-05-17 | Evonik Fibres Gmbh | Polyimide membranes made of polymerization solutions |
| DE102009045139A1 (de) | 2009-09-30 | 2011-03-31 | Evonik Oxeno Gmbh | Herstellung von alpha,beta-ungesättigten Aldehyden mittels einer Reaktionsmischpumpe |
| DE102009047351A1 (de) | 2009-12-01 | 2011-06-09 | Evonik Goldschmidt Gmbh | Komposit-Siliconmembranen mit hoher Trennwirkung |
| DE102011082441A1 (de) | 2011-09-09 | 2013-03-14 | Evonik Oxeno Gmbh | Strahlschlaufenreaktor mit Nanofiltration |
| DE102012202779A1 (de) * | 2012-02-23 | 2013-08-29 | Evonik Oxeno Gmbh | Verfahren und Vorrichtung zur technischen Hydroformylierung von Isobuten und zum Auftrennen des Produktgemisches |
| WO2014056735A1 (de) | 2012-10-12 | 2014-04-17 | Evonik Degussa Gmbh | Gemische konstitutionsisomerer bisphosphite |
| DE102012223572A1 (de) | 2012-12-18 | 2014-06-18 | Evonik Industries Ag | Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren |
| DE102013203117A1 (de) * | 2013-02-26 | 2014-08-28 | Evonik Industries Ag | Optimierte Trenntechnik zur Aufarbeitung von homogen katalysierten Hydroformylierungsmischungen |
| DE102013208759A1 (de) * | 2013-05-13 | 2014-11-13 | Evonik Industries Ag | Abtrennung von Homogenkatalysatoren mittels einer geregelten Membrantrenneinheit |
| DE102013215004A1 (de) | 2013-07-31 | 2015-02-05 | Evonik Industries Ag | Membrankaskade mit sinkender Trenntemperatur |
| RU2585285C1 (ru) * | 2015-04-20 | 2016-05-27 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Способ непрерывного гидроформилирования олефинов c2-c8 |
| US10618037B2 (en) | 2015-06-24 | 2020-04-14 | Zeon Corporation | Method for recovering catalyst |
| JP7269238B2 (ja) | 2017-11-13 | 2023-05-08 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化プロセスからロジウムを回収するためのプロセス |
| US11008275B2 (en) * | 2019-06-12 | 2021-05-18 | Evonik Operations Gmbh | Process for preparing carboxylic acids or salts thereof from hydrocarbons |
| US12064755B2 (en) * | 2019-06-12 | 2024-08-20 | Evonik Oxeno Gmbh & Co. Kg | Process for separating one or more components from a mixture |
| WO2022081444A1 (en) | 2020-10-13 | 2022-04-21 | Dow Silicones Corporation | Preparation of organosilicon compounds with aldehyde functionality |
| CN118043331A (zh) | 2021-10-06 | 2024-05-14 | 陶氏环球技术有限责任公司 | 制备氨基官能化有机硅化合物 |
| JP2024536286A (ja) | 2021-10-06 | 2024-10-04 | ダウ グローバル テクノロジーズ エルエルシー | プロピルイミン官能性有機ケイ素化合物及び一級アミノプロピル官能性有機ケイ素化合物の調製 |
| CN118019747A (zh) | 2021-10-06 | 2024-05-10 | 陶氏环球技术有限责任公司 | 丙基亚胺官能化有机硅化合物和伯氨基丙基官能化有机硅化合物的制备 |
| KR20240101860A (ko) | 2021-11-22 | 2024-07-02 | 다우 글로벌 테크놀로지스 엘엘씨 | 카르비놀 관능기를 갖는 유기규소 화합물의 제조 |
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| DE102006003618A1 (de) * | 2006-01-26 | 2007-08-02 | Oxeno Olefinchemie Gmbh | Verfahren zur Abtrennung von Metall-Komplexkatalysatoren aus Telomerisationsgemischen |
| DE102006005100A1 (de) | 2006-02-04 | 2007-08-09 | Goldschmidt Gmbh | Verfahren zur Herstellung organomodifizierter Siloxane |
| DE102006008387A1 (de) | 2006-02-21 | 2007-08-30 | Goldschmidt Gmbh | Verfahren zur Herstellung von siloxanhaltigen Trennbeschichtungen |
| DE102006027339A1 (de) | 2006-06-13 | 2007-12-20 | Goldschmidt Gmbh | Kationisch strahlenhärtende Controlled Release Beschichtungsmassen |
| DE102006041089A1 (de) | 2006-09-01 | 2008-03-06 | Evonik Goldschmidt Gmbh | Verwendung von gepfropften Polyethersiloxanmischpolymeren zur Verbesserung der Kältestabilität von Entschäumern in wässrigen Dispersionen |
| DE102006041088A1 (de) | 2006-09-01 | 2008-03-06 | Evonik Goldschmidt Gmbh | Siliconhaltige, blockweise aufgebaute Pfropfmischpolymere |
| DE102006041971A1 (de) | 2006-09-07 | 2008-03-27 | Evonik Goldschmidt Gmbh | Verwendung von partikulären Emulgatoren in abhäsiven siloxanhaltigen Beschichtungsmassen |
| DE102007005508A1 (de) | 2007-02-03 | 2008-08-07 | Evonik Goldschmidt Gmbh | Verfahren zur Reduktion des Trennwert-Anstiegs bei der Herstellung von No-Label-Look-Etiketten |
| DE102007041028A1 (de) | 2007-08-29 | 2009-03-05 | Evonik Goldschmidt Gmbh | Verwendung estermodifizierter Organopolysiloxane zur Herstellung kosmetischer oder pharmazeutischer Kompositionen |
| DE102007044148A1 (de) | 2007-09-15 | 2009-03-26 | Evonik Goldschmidt Gmbh | Neuartige siloxanhaltige Blockcopolymere, Verfahren zu deren Herstellung und deren Verwendung für Schmiermittel |
| DE102007054885A1 (de) | 2007-11-15 | 2009-05-20 | Evonik Degussa Gmbh | Verfahren zur Fraktionierung oxidischer Nanopartikel durch Querstrom-Membranfiltration |
| DE102008000243A1 (de) | 2008-02-06 | 2009-08-13 | Evonik Goldschmidt Gmbh | Neuartige Kompatibilisierungsmittel zur Verbesserung der Lagerstabilität von Polyolmischungen |
| DE102008000287A1 (de) | 2008-02-13 | 2009-08-20 | Evonik Goldschmidt Gmbh | Reaktives, flüssiges Keramikbindemittel |
| DE102008001788A1 (de) | 2008-05-15 | 2009-11-26 | Evonik Goldschmidt Gmbh | Verwendung organomodifizierter Siloxanblockcopolymere zur Herstellung kosmetischer oder pharmazeutischer Zusammensetzungen |
| DE102008001786A1 (de) | 2008-05-15 | 2009-11-26 | Evonik Goldschmidt Gmbh | Verwendung organomodifizierter Siloxanblockcopolymere als Pflegewirkstoff zur Pflege von menschlichen oder tierischen Körperteilen |
| DE102008040986A1 (de) | 2008-08-05 | 2010-02-11 | Evonik Goldschmidt Gmbh | Hydrophobierung von Bauelementen aus Mineralfasern |
| DE102008041601A1 (de) | 2008-08-27 | 2010-03-04 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung verzweigter SiH-funtioneller Polysiloxane und deren Verwendung zur Herstellung flüssiger, SiC- oder SiOC-verknüpfter, verzweigter organomodifizierter Polysiloxane |
| DE102008041870A1 (de) | 2008-09-08 | 2010-03-11 | Evonik Degussa Gmbh | Reaktor mit Titansilikat-Rezyklierung |
| DE102008042381A1 (de) | 2008-09-26 | 2010-04-01 | Evonik Goldschmidt Gmbh | Emulgator-Systeme für kosmetische und pharmazeutische Öl-in-Wasser-Emulsionen |
| ES2534775T3 (es) | 2008-10-17 | 2015-04-28 | Evonik Degussa Gmbh | Composiciones oleosas agroquímicas que comprenden adyuvantes de alquilpolisiloxano en condición de silicona alta |
| DE102008043422B3 (de) | 2008-11-03 | 2010-01-07 | Evonik Degussa Gmbh | Verfahren zur Aufreinigung niedermolekularer Hydridosilane |
| DE102009001225A1 (de) | 2009-02-27 | 2010-09-02 | Evonik Oxeno Gmbh | Verfahren zur Anreicherung eines Homogenkatalysators aus einem Prozessstrom |
| DE102009015211A1 (de) | 2009-03-31 | 2010-10-14 | Evonik Goldschmidt Gmbh | Selbstvernetzende Polysiloxane in Beschichtungen von Enzymimmobilisaten |
| DE102009002415A1 (de) | 2009-04-16 | 2010-10-21 | Evonik Goldschmidt Gmbh | Emulgator enthaltend glycerinmodifizierte Organopolysiloxane |
| DE102009003275A1 (de) | 2009-05-20 | 2010-11-25 | Evonik Goldschmidt Gmbh | Verzweigte Polydimethylsiloxan-Polyoxyalkylen Copolymere, ein Verfahren zu ihrer Herstellung und ihre Verwendung als Anti-Vernebelungsadditiv in UV-härtenden Silikonen |
| DE102009028640A1 (de) | 2009-08-19 | 2011-02-24 | Evonik Goldschmidt Gmbh | Härtbare Masse enthaltend Urethangruppen aufweisende silylierte Polymere und deren Verwendung in Dicht- und Klebstoffen, Binde- und/oder Oberflächenmodifizierungsmitteln |
| DE102009028636A1 (de) | 2009-08-19 | 2011-02-24 | Evonik Goldschmidt Gmbh | Neuartige Urethangruppen enthaltende silylierte Präpolymere und Verfahren zu deren Herstellung |
| DE102010002178A1 (de) | 2010-02-22 | 2011-08-25 | Evonik Goldschmidt GmbH, 45127 | Verfahren zur Herstellung von Amin-Amid-funktionellen Siloxanen |
| DE102010002180A1 (de) | 2010-02-22 | 2011-08-25 | Evonik Goldschmidt GmbH, 45127 | Stickstoffhaltige silizium-organische Pfropfmischpolymere |
| DE102010031087A1 (de) | 2010-07-08 | 2012-01-12 | Evonik Goldschmidt Gmbh | Neuartige polyestermodifizierte Organopolysiloxane |
-
2009
- 2009-02-27 DE DE102009001230A patent/DE102009001230A1/de not_active Withdrawn
-
2010
- 2010-02-25 SG SG2011062080A patent/SG174171A1/en unknown
- 2010-02-25 KR KR1020117019821A patent/KR20110124760A/ko not_active Application Discontinuation
- 2010-02-25 US US13/203,295 patent/US8748643B2/en not_active Expired - Fee Related
- 2010-02-25 JP JP2011551489A patent/JP5896748B2/ja not_active Expired - Fee Related
- 2010-02-25 EP EP10707252.2A patent/EP2401060B1/de active Active
- 2010-02-25 MY MYPI2011004055A patent/MY153625A/en unknown
- 2010-02-25 BR BRPI1008919-5A patent/BRPI1008919B1/pt not_active IP Right Cessation
- 2010-02-25 CN CN2010800094032A patent/CN102333580A/zh active Pending
- 2010-02-25 WO PCT/EP2010/052390 patent/WO2010097428A1/de active Application Filing
- 2010-02-25 ES ES10707252.2T patent/ES2561653T3/es active Active
- 2010-02-25 MX MX2011009007A patent/MX2011009007A/es not_active Application Discontinuation
- 2010-02-25 RU RU2011139167/05A patent/RU2011139167A/ru not_active Application Discontinuation
-
2011
- 2011-08-26 ZA ZA2011/06307A patent/ZA201106307B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP2401060A1 (de) | 2012-01-04 |
| JP2012519062A (ja) | 2012-08-23 |
| MY153625A (en) | 2015-02-27 |
| RU2011139167A (ru) | 2013-04-10 |
| US20120035382A1 (en) | 2012-02-09 |
| KR20110124760A (ko) | 2011-11-17 |
| ZA201106307B (en) | 2012-05-30 |
| WO2010097428A1 (de) | 2010-09-02 |
| MX2011009007A (es) | 2011-11-18 |
| ES2561653T3 (es) | 2016-02-29 |
| BRPI1008919B1 (pt) | 2020-10-20 |
| DE102009001230A1 (de) | 2010-09-02 |
| EP2401060B1 (de) | 2015-11-25 |
| JP5896748B2 (ja) | 2016-03-30 |
| BRPI1008919A2 (pt) | 2016-03-15 |
| CN102333580A (zh) | 2012-01-25 |
| SG174171A1 (en) | 2011-10-28 |
| US8748643B2 (en) | 2014-06-10 |
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