BRPI0607052B8 - processo para produção contiínua de elastômeros de poliuretano processáveis termoplasticamente , e, uso de elastômeros de poliuretano termplásticos - Google Patents

processo para produção contiínua de elastômeros de poliuretano processáveis termoplasticamente , e, uso de elastômeros de poliuretano termplásticos

Info

Publication number
BRPI0607052B8
BRPI0607052B8 BRPI0607052A BRPI0607052A BRPI0607052B8 BR PI0607052 B8 BRPI0607052 B8 BR PI0607052B8 BR PI0607052 A BRPI0607052 A BR PI0607052A BR PI0607052 A BRPI0607052 A BR PI0607052A BR PI0607052 B8 BRPI0607052 B8 BR PI0607052B8
Authority
BR
Brazil
Prior art keywords
polyurethane elastomers
thermoplastic
polyisocyanate
continuous production
proportion
Prior art date
Application number
BRPI0607052A
Other languages
English (en)
Portuguese (pt)
Inventor
Christoph Bahr
GüNTER SCHOLZ
Horst Papenfuss
Marian Mours
Rudiger Krech
Sven Lawrenz
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of BRPI0607052A2 publication Critical patent/BRPI0607052A2/pt
Publication of BRPI0607052B1 publication Critical patent/BRPI0607052B1/pt
Publication of BRPI0607052B8 publication Critical patent/BRPI0607052B8/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07—Flat, e.g. panels
    • B29C48/08—Flat, e.g. panels flexible, e.g. films
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • B29C48/405—Intermeshing co-rotating screws
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/793—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling upstream of the plasticising zone, e.g. heating in the hopper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/86—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the nozzle zone
    • B29C48/865—Heating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/875—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0895—Manufacture of polymers by continuous processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/664—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/355—Conveyors for extruded articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/375—Plasticisers, homogenisers or feeders comprising two or more stages
    • B29C48/38—Plasticisers, homogenisers or feeders comprising two or more stages using two or more serially arranged screws in the same barrel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2021/00—Use of unspecified rubbers as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
    • B29K2105/0014—Catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
BRPI0607052A 2005-02-03 2006-01-31 processo para produção contiínua de elastômeros de poliuretano processáveis termoplasticamente , e, uso de elastômeros de poliuretano termplásticos BRPI0607052B8 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005004967A DE102005004967A1 (de) 2005-02-03 2005-02-03 Verfahren zur kontinuierlichen Herstellung thermoplastisch verarbeitbarer Polyurethan-Elastomere
PCT/EP2006/050550 WO2006082183A1 (de) 2005-02-03 2006-01-31 Verfahren zur kontinuierlichen herstellung thermoplastisch verarbeitbarer polyurethan-elastomere

Publications (3)

Publication Number Publication Date
BRPI0607052A2 BRPI0607052A2 (pt) 2009-12-01
BRPI0607052B1 BRPI0607052B1 (pt) 2016-10-18
BRPI0607052B8 true BRPI0607052B8 (pt) 2016-11-16

Family

ID=36215574

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0607052A BRPI0607052B8 (pt) 2005-02-03 2006-01-31 processo para produção contiínua de elastômeros de poliuretano processáveis termoplasticamente , e, uso de elastômeros de poliuretano termplásticos

Country Status (10)

Country Link
US (1) US8287788B2 (enExample)
EP (1) EP1846465B1 (enExample)
JP (1) JP5020097B2 (enExample)
KR (1) KR101273844B1 (enExample)
CN (1) CN101115780B (enExample)
AT (1) ATE425197T1 (enExample)
BR (1) BRPI0607052B8 (enExample)
DE (2) DE102005004967A1 (enExample)
ES (1) ES2322194T3 (enExample)
WO (1) WO2006082183A1 (enExample)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006038197A1 (de) * 2006-08-16 2008-02-21 Kraussmaffei Technologies Gmbh Vorrichtung und Verfahren zur Verarbeitung von Duroplasten
CA2698175A1 (en) * 2007-09-12 2009-03-19 Construction Research & Technology Gmbh Continuous production of polyurethanes/polyureas
EP2300149B1 (de) * 2008-07-08 2012-12-12 Construction Research & Technology GmbH Verfahren zur entfernung von nicht umgesetzten isocyanat aus dessen umsetzungsprodukt
DE102009055735A1 (de) * 2009-11-26 2011-07-07 Bayer Material Science AG, 51373 Verfahren zur kontinuierlichen Herstellung von thermoplastisch verarbeitbaren Polyurethanen
US20120116030A1 (en) * 2010-11-10 2012-05-10 Bayer Materialscience Ag Process for continuously producing thermoplastically processable polyurethanes
JP6185989B2 (ja) 2012-06-18 2017-08-23 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ バルブ、膨張可能な柔軟性チューブ及びそれらの製造方法
CN102786652B (zh) * 2012-08-24 2014-04-02 奥斯汀新材料（张家港）有限公司 一种热塑性聚氨酯弹性体的制备方法
ES2596244T3 (es) 2012-10-10 2017-01-05 Basf Se Dispositivo de intercepción de poliuretano termoplástico
DE102012218846A1 (de) * 2012-10-16 2014-04-17 Bayer Materialscience Ag Herstellung und Verwendung neuer thermoplastischer Polyurethan-Elastomere auf Basis von Polyethercarbonatpolyolen
CN103265676A (zh) * 2013-04-20 2013-08-28 北京化工大学 一种连续生产高性能热塑性聚氨酯弹性体的方法
CN103275290A (zh) * 2013-05-30 2013-09-04 中国人民解放军总后勤部建筑工程研究所 热塑性聚氨酯的制备方法
WO2015055631A1 (de) 2013-10-15 2015-04-23 Basf Se Leitfähiges thermoplastisches polyurethan
JP2017512863A (ja) 2014-03-25 2017-05-25 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Ｔｐｕ空気ホース
BR112018004019A2 (pt) * 2015-09-24 2018-12-11 Basf Se ?poliuretano termoplástico, processo para a preparação de um poliuretano termoplástico, utilização de um poliuretano termoplástico e mangueira?
EP3371234B1 (de) 2015-11-04 2023-03-29 Basf Se Verfahren zur herstellung thermoplastischer polyurethane
JP7110109B2 (ja) 2016-03-21 2022-08-01 ビーエーエスエフ ソシエタス・ヨーロピア 架橋ポリウレタン
JP2020507649A (ja) 2017-02-13 2020-03-12 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 熱可塑性ポリウレタン
WO2018146335A1 (de) 2017-02-13 2018-08-16 Basf Se Thermoplastisches polyurethan
WO2019002263A1 (de) 2017-06-26 2019-01-03 Basf Se Thermoplastisches polyurethan
CN110945046A (zh) 2017-07-05 2020-03-31 巴斯夫欧洲公司 Tpu管
CN111094378A (zh) 2017-07-20 2020-05-01 巴斯夫欧洲公司 热塑性聚氨酯
US20220242998A1 (en) 2019-05-20 2022-08-04 Basf Se Improved thermoplastic polyurethanes
CN111285998A (zh) * 2020-03-20 2020-06-16 高鼎精细化工(昆山)有限公司 一种可染色的环保型聚氨酯弹性体及其制备方法
US20230250220A1 (en) 2020-07-10 2023-08-10 Basf Se Process for preparing a crosslinked thermoplastic polyurethane and articles thereof

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE759829A (fr) * 1969-12-03 1971-06-03 Upjohn Co Preparation de polyurethanes
DE2302564C3 (de) * 1973-01-19 1985-02-07 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von Polyurethan-Elastomeren
US3963679A (en) * 1973-01-19 1976-06-15 Bayer Aktiengesellschaft Process for the production of polyurethane elastomers
DE2423764C3 (de) * 1974-05-16 1979-10-18 Bayer Ag, 5090 Leverkusen Verfahren zur kontinuierlichen Herstellung von elastomeren Polyurethanharnstoffen
DE2817456A1 (de) * 1978-04-21 1979-10-31 Bayer Ag Verfahren zur herstellung von thermoplastischen polyurethanelastomeren
AU5949390A (en) 1989-06-27 1991-01-17 Dow Chemical Company, The Melt polymerization process for making polyurethanes
DE4437586A1 (de) 1994-10-20 1996-04-25 Basf Schwarzheide Gmbh Verfahren zur Herstellung von thermoplastischen Polyurethanen
DE19633404A1 (de) * 1996-08-19 1998-02-26 Basf Ag Verfahren zur Herstellung von Biuretgruppen enhaltenden Polyisocyanaten aus (cyclo)aliphatischen Diisocyanaten
DE19924090C1 (de) * 1999-05-26 2001-01-25 Bayer Ag Verfahren zur kontinuierlichen Herstellung von thermoplastisch verarbeitbaren Polyurethanen mit verbessertem Erweichungsverhalten
DE19924089C1 (de) * 1999-05-26 2001-01-25 Bayer Ag Verfahren zur kontinuierlichen Herstellung von thermoplastisch verarbeitbaren Polyurethanen mit verbessertem Erweichungsverhalten
JP2003071829A (ja) * 2001-08-30 2003-03-12 Mitsubishi Chemicals Corp ポリマー変性物の製造方法

Also Published As

Publication number Publication date
CN101115780B (zh) 2010-07-28
DE502006003088D1 (de) 2009-04-23
KR20070100910A (ko) 2007-10-12
BRPI0607052A2 (pt) 2009-12-01
ES2322194T3 (es) 2009-06-17
KR101273844B1 (ko) 2013-06-12
BRPI0607052B1 (pt) 2016-10-18
JP5020097B2 (ja) 2012-09-05
US20080139776A1 (en) 2008-06-12
CN101115780A (zh) 2008-01-30
WO2006082183A1 (de) 2006-08-10
EP1846465B1 (de) 2009-03-11
US8287788B2 (en) 2012-10-16
EP1846465A1 (de) 2007-10-24
JP2008528340A (ja) 2008-07-31
ATE425197T1 (de) 2009-03-15
DE102005004967A1 (de) 2006-08-10

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