BRPI0518906A2 - mÉtodo para inibir e retardar polimerizaÇço prematura e crescimento de polÍmero de monâmeros aromÁticos de vinila, composiÇço - Google Patents
mÉtodo para inibir e retardar polimerizaÇço prematura e crescimento de polÍmero de monâmeros aromÁticos de vinila, composiÇçoInfo
- Publication number
- BRPI0518906A2 BRPI0518906A2 BRPI0518906-3A BRPI0518906A BRPI0518906A2 BR PI0518906 A2 BRPI0518906 A2 BR PI0518906A2 BR PI0518906 A BRPI0518906 A BR PI0518906A BR PI0518906 A2 BRPI0518906 A2 BR PI0518906A2
- Authority
- BR
- Brazil
- Prior art keywords
- inhibiting
- vinyl aromatic
- premature polymerization
- composition
- polymer growth
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
- C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
- C07C211/45—Monoamines
- C07C211/46—Aniline
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C309/41—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton
- C07C309/42—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton having the sulfo groups bound to carbon atoms of non-condensed six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogenated Pyridines (AREA)
Abstract
MÉTODO PARA INIBIR E RETARDAR POLIMERIZAÇçO PREMATURA E CRESCIMENTO DE POLIMERO DE MONâMEROS AROMATICOS DE VINILA, COMPOSIÇçO. É descrito aqui um método para inibir e retardar a polimerização prematura e o crescimento de polímero de monômeros aromáticos de vinila onde o método compreende adicionar aos monômeros uma quantidade eficaz de uma mistura inibidora e retardadora compreendendo: (A) pelo menos um ácido sulfônico aromático; (B) pelo menos uma amina; (C) pelo menos um nitrofenol; e (D) pelo menos um membro do grupo que consiste em compostos contendo radical nitróxi e nitrosoanilinas.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US63252804P | 2004-12-03 | 2004-12-03 | |
US11/170,304 US7696290B2 (en) | 2004-12-03 | 2005-06-28 | Aromatic sulfonic acids, amines, and nitrophenols in combination with nitroxyl radical-containing compounds or C-nitrosanilines as polymerization inhibitors |
PCT/US2005/030673 WO2006062563A1 (en) | 2004-12-03 | 2005-08-26 | Aromatic sulfonic acids, amines, and nitrophenols in combination with nitroxyl radical-containing compounds or c-nitrosanilines as polymerization inhibitors |
Publications (1)
Publication Number | Publication Date |
---|---|
BRPI0518906A2 true BRPI0518906A2 (pt) | 2008-12-16 |
Family
ID=35809543
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0518906-3A BRPI0518906A2 (pt) | 2004-12-03 | 2005-08-26 | mÉtodo para inibir e retardar polimerizaÇço prematura e crescimento de polÍmero de monâmeros aromÁticos de vinila, composiÇço |
Country Status (11)
Country | Link |
---|---|
US (2) | US7696290B2 (pt) |
EP (1) | EP1817271A1 (pt) |
KR (1) | KR20070086820A (pt) |
AR (1) | AR054993A1 (pt) |
BR (1) | BRPI0518906A2 (pt) |
CA (1) | CA2589038C (pt) |
MX (1) | MX2007006608A (pt) |
MY (1) | MY145436A (pt) |
RU (1) | RU2391328C2 (pt) |
TW (1) | TWI376360B (pt) |
WO (1) | WO2006062563A1 (pt) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7691952B2 (en) * | 2004-09-28 | 2010-04-06 | Chemtura Corporation | Sulfonated nitrophenols as polymerization inhibitors |
CN101056832B (zh) * | 2004-11-15 | 2011-12-07 | 伯东株式会社 | 抑制二乙烯基苯和芳香族乙烯基化合物聚合的方法 |
US8246858B2 (en) * | 2006-03-24 | 2012-08-21 | Hakuto Co., Ltd. | Process for inhibiting polymerization of an aromatic vinyl compound |
KR100824587B1 (ko) | 2007-08-10 | 2008-04-24 | 한국바이오젠 주식회사 | 비닐 방향족 단량체 생산 및 정제를 위한 효율적 중합방지조성물 |
EP2233505A1 (en) * | 2009-03-23 | 2010-09-29 | Total Petrochemicals Research Feluy | Stabilised compositions comprising olefins |
JP5675184B2 (ja) * | 2010-06-18 | 2015-02-25 | 伯東株式会社 | ビニル化合物の重合防止剤組成物ならびにこれを用いたビニル化合物の重合防止方法 |
CN102399310B (zh) * | 2010-09-09 | 2013-07-24 | 通用电气公司 | 抑制过早聚合的组合物和方法 |
RU2470911C2 (ru) * | 2011-03-29 | 2012-12-27 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Сибирский государственный технологический университет" (СибГТУ) | Способ получения n-алкил-3-метил-4-нитрозоанилинов |
CN102516005A (zh) * | 2011-11-21 | 2012-06-27 | 上海泰顿化工有限公司 | 一种硝酰基化合物组合及用途 |
CA2857384C (en) * | 2011-11-29 | 2016-08-16 | Dorf Ketal Chemicals (India) Private Limited | Amine based additive composition for control and inhibition of polymerization of styrene, and method of use thereof |
MY168537A (en) * | 2011-12-26 | 2018-11-12 | Dorf Ketal Chemicals India Private Ltd | Improved amine based additive composition for control and inhibition of polymerization of aromatic vinyl monomers, and method of use thereof |
EP2958949A1 (en) * | 2013-02-19 | 2015-12-30 | General Electric Company | Use of aliphatic nitroso compounds as inhibitors of radical polymerization of activated vinyl monomers |
IN2013MU01165A (pt) * | 2013-03-26 | 2015-04-24 | Dorf Ketal Chemicals India Private Ltd | |
US11180578B2 (en) | 2018-07-13 | 2021-11-23 | Ecolab Usa Inc. | Polymerization inhibitor and retarder compositions with amine stabilizer |
CN112513005A (zh) | 2018-07-13 | 2021-03-16 | 埃科莱布美国股份有限公司 | 氧化胺和甲基化醌的组合物作为乙烯单体的抗污剂 |
Family Cites Families (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2046356A (en) | 1933-12-27 | 1936-07-07 | Ici Ltd | Manufacture of diarylamine derivatives |
US2867672A (en) | 1955-08-29 | 1959-01-06 | Shell Dev | Method of minimizing styrene polymerization during storage |
US3163677A (en) | 1961-08-07 | 1964-12-29 | American Cyanamid Co | Process for preparing n, n, o-trisubstituted hydroxyl amines and n, n-disubstituted nitroxides and products |
US3502692A (en) | 1962-06-13 | 1970-03-24 | American Cyanamid Co | Cyclic nitroxides and process for preparing same |
GB983134A (en) | 1962-06-13 | 1965-02-10 | American Cyanamid Co | Cyclic nitroxides and process for preparing same |
NL137479C (pt) | 1962-08-14 | |||
US3422144A (en) | 1965-04-27 | 1969-01-14 | American Cyanamid Co | Stable free radical nitroxides |
US3372182A (en) | 1965-04-27 | 1968-03-05 | American Cyanamid Co | Process for preparation of stable, free radical nitroxides |
GB1064845A (en) * | 1966-03-10 | 1967-04-12 | Ferenc Tudos | Inhibiting polymerisation |
FR1501769A (fr) | 1966-07-04 | 1967-11-18 | Commissariat Energie Atomique | Radicaux libres du type nitroxyde |
US3873564A (en) | 1971-03-03 | 1975-03-25 | Synvar Ass | 2-Imidazolinyl-3-oxide-1-oxypropionic acid |
GB1354420A (en) | 1971-05-17 | 1974-06-05 | Volgogradsky Politekh Inst | Isoprene treatment |
CH579118A5 (pt) | 1973-06-22 | 1976-08-31 | Ciba Geigy Ag | |
US4210493A (en) * | 1976-03-30 | 1980-07-01 | Rohm And Haas Company | C-Nitroso compounds as anaerobic polymerization inhibitors for acrylic acid or methacrylic acid |
JPS52153817A (en) | 1976-06-18 | 1977-12-21 | Masatoshi Tsuda | Flux for modification of proeutectic silicon in the high silicon aluminium alloy |
US4086147A (en) | 1976-12-10 | 1978-04-25 | Cosden Technology, Inc. | Polymerization inhibitor for vinyl aromatic compounds |
SU1027150A1 (ru) | 1981-10-21 | 1983-07-07 | Научно-Исследовательский Институт Механики И Физики При Саратовском Ордена Трудового Красного Знамени Государственном Университете Им.Н.Г.Чернышевского | Способ стабилизации стирола или метилметакрилата |
US4468343A (en) | 1983-04-11 | 1984-08-28 | Cosden Technology, Inc. | Polymerization co-inhibitors for vinyl aromatic compounds |
SU1139722A1 (ru) | 1983-04-12 | 1985-02-15 | Ереванское Отделение Охтинского Ордена Ленина И Ордена Трудового Красного Знамени Научно-Производственного Объединения "Пластполимер" | Способ ингибировани полимеризации стирола |
US4665185A (en) | 1984-03-22 | 1987-05-12 | Ciba-Geigy Corporation | Process for preparing nitroxyls of sterically hindered amines |
US4664845A (en) | 1986-01-09 | 1987-05-12 | Uniroyal Chemical Company, Inc. | Phenylenediamine solubilizer for dinitrophenol in aromatic solvent |
US4670131A (en) * | 1986-01-13 | 1987-06-02 | Exxon Chemical Patents Inc. | Method for controlling fouling of hydrocarbon compositions containing olefinic compounds |
SU1558888A1 (ru) | 1987-12-11 | 1990-04-23 | Всесоюзный Научно-Исследовательский Институт Химических Реактивов И Особочистых Химических Веществ | Способ ингибировани полимеризации стирола |
US5023372A (en) | 1989-05-16 | 1991-06-11 | Betz Laboratories, Inc. | Methods and compositions for inhibiting (meth)acrylic acid polymerization |
US5290888A (en) | 1990-07-20 | 1994-03-01 | Ciba-Geigy Corporation | Process for stabilizing ethylenically unsaturated compounds and stabilized monomer compositions |
US5212272A (en) * | 1990-10-31 | 1993-05-18 | Peach State Labs, Inc. | Polyacrylic acid compositions for textile processing |
US5157175A (en) | 1991-09-09 | 1992-10-20 | Nalco Chemical Company | Composition and method for inhibition of styrene polymerization |
US5254888A (en) * | 1992-03-27 | 1993-10-19 | Picopower Technology Inc. | Switchable clock circuit for microprocessors to thereby save power |
US5254760A (en) | 1992-07-29 | 1993-10-19 | Ciba-Geigy Corporation | Inhibiting polymerization of vinyl aromatic monomers |
JPH06234700A (ja) | 1993-02-12 | 1994-08-23 | Dainippon Ink & Chem Inc | (メタ)アクリル酸エステル類の製造方法 |
US5728872A (en) | 1994-06-27 | 1998-03-17 | Lutz Riemenschneider | Stabilized acrylic acid compositions |
US5446220A (en) * | 1994-08-24 | 1995-08-29 | Betz Laboratories, Inc. | Methods for inhibiting vinyl aromatic monomer polymerization |
US5545786C1 (en) | 1994-11-28 | 2001-10-16 | Ciba Geigy Corp | Method for inhibiting premature polymerization of vinyl aromatic monomers |
US5590232A (en) | 1995-02-16 | 1996-12-31 | Motorola, Inc. | Optical package and method of making |
DE19510184A1 (de) | 1995-03-21 | 1996-09-26 | Basf Ag | 4-Acylaminopiperidin-N-oxyle |
US5648573A (en) | 1995-06-12 | 1997-07-15 | Betzdearborn Inc. | Compositions and methods for inhibiting vinyl aromatic monomer polymerization |
CN1082499C (zh) | 1996-06-05 | 2002-04-10 | Basf公司 | 含单体和稳定剂的混合物 |
DE19651307A1 (de) | 1996-12-10 | 1998-06-18 | Basf Ag | Stoffmischungen, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
US5932735A (en) | 1997-06-13 | 1999-08-03 | Ciba Specialty Chemicals Corporation | Derivatives of 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers |
US6136951A (en) | 1999-08-16 | 2000-10-24 | Uniroyal Chemical Company, Inc. | Test method for evaluating insoluble polymer growth |
ATE307789T1 (de) | 1999-12-02 | 2005-11-15 | Crompton Corp | Polymerisationsinhibierung von ungesättigten monomeren |
AR029410A1 (es) | 1999-12-02 | 2003-06-25 | Crompton Corp | Metodo para inhibir la polimerizacion prematura de monomeros etilenicamente insaturados y composiciones de los mismos |
WO2002033026A1 (en) | 2000-10-16 | 2002-04-25 | Uniroyal Chemical Company, Inc. | Blends of quinone alkide and nitroxyl compounds as polymerization inhibitors |
US6685823B2 (en) * | 2000-10-16 | 2004-02-03 | Uniroyal Chemical Company, Inc. | C-nitrosoaniline compounds and their blends as polymerization inhibitors |
JP3788950B2 (ja) | 2001-04-25 | 2006-06-21 | 伯東株式会社 | 芳香族ビニル化合物の重合抑制方法 |
US7125475B2 (en) | 2002-02-15 | 2006-10-24 | Crompton Corporation | Nitrosophenols and C-nitrosoanilines as polymerization inhibitors |
JP4165816B2 (ja) | 2003-03-31 | 2008-10-15 | 伯東株式会社 | 芳香族ビニル化合物の重合抑制剤組成物 |
-
2005
- 2005-06-28 US US11/170,304 patent/US7696290B2/en not_active Expired - Fee Related
- 2005-08-26 CA CA2589038A patent/CA2589038C/en not_active Expired - Fee Related
- 2005-08-26 RU RU2007125138/04A patent/RU2391328C2/ru not_active IP Right Cessation
- 2005-08-26 WO PCT/US2005/030673 patent/WO2006062563A1/en active Application Filing
- 2005-08-26 KR KR1020077014968A patent/KR20070086820A/ko not_active Application Discontinuation
- 2005-08-26 MX MX2007006608A patent/MX2007006608A/es active IP Right Grant
- 2005-08-26 BR BRPI0518906-3A patent/BRPI0518906A2/pt not_active IP Right Cessation
- 2005-08-26 EP EP05809940A patent/EP1817271A1/en not_active Ceased
- 2005-11-11 TW TW094139698A patent/TWI376360B/zh not_active IP Right Cessation
- 2005-11-28 AR ARP050104960A patent/AR054993A1/es unknown
- 2005-12-02 MY MYPI20055658A patent/MY145436A/en unknown
-
2010
- 2010-01-27 US US12/694,693 patent/US7728083B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US20060122341A1 (en) | 2006-06-08 |
EP1817271A1 (en) | 2007-08-15 |
MY145436A (en) | 2012-02-15 |
US7728083B1 (en) | 2010-06-01 |
CA2589038A1 (en) | 2006-06-15 |
AR054993A1 (es) | 2007-08-01 |
WO2006062563A1 (en) | 2006-06-15 |
TWI376360B (en) | 2012-11-11 |
US7696290B2 (en) | 2010-04-13 |
KR20070086820A (ko) | 2007-08-27 |
RU2007125138A (ru) | 2009-01-10 |
US20100127218A1 (en) | 2010-05-27 |
CA2589038C (en) | 2013-06-25 |
TW200635894A (en) | 2006-10-16 |
RU2391328C2 (ru) | 2010-06-10 |
MX2007006608A (es) | 2007-08-14 |
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Legal Events
Date | Code | Title | Description |
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B07A | Technical examination (opinion): publication of technical examination (opinion) [chapter 7.1 patent gazette] | ||
B08F | Application fees: application dismissed [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 9A ANUIDADE. |
|
B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2269 DE 01/07/2014. |