AR054993A1 - Acidos sulfonicos, aminas y nitrofenoles aromaticos en combinacion con compuestos con contenido de radicales nitroxilo o c- nitrosanilinas como inhibidores de la polimerizacion - Google Patents

Acidos sulfonicos, aminas y nitrofenoles aromaticos en combinacion con compuestos con contenido de radicales nitroxilo o c- nitrosanilinas como inhibidores de la polimerizacion

Info

Publication number
AR054993A1
AR054993A1 ARP050104960A ARP050104960A AR054993A1 AR 054993 A1 AR054993 A1 AR 054993A1 AR P050104960 A ARP050104960 A AR P050104960A AR P050104960 A ARP050104960 A AR P050104960A AR 054993 A1 AR054993 A1 AR 054993A1
Authority
AR
Argentina
Prior art keywords
polymerization
compounds
nitrosanilin
nitrophenols
nitroxyl
Prior art date
Application number
ARP050104960A
Other languages
English (en)
Original Assignee
Chemtura Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemtura Corp filed Critical Chemtura Corp
Publication of AR054993A1 publication Critical patent/AR054993A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/45—Monoamines
    • C07C211/46—Aniline
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/41—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton
    • C07C309/42—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton having the sulfo groups bound to carbon atoms of non-condensed six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogenated Pyridines (AREA)

Abstract

En la presente se describe un método para inhibir y retardar la polimerizacion prematura y desarrollo de polímeros a partir de los monomeros aromáticos de vinilo, que comprende agregar a dichos monomeros una cantidad efectiva de una mezcla inhibidora y retardadora que comprende: a) por lo menos un ácido sulfonico aromático; b) por lo menos una amina; c) por lo menos un nitrofenol; y d) por lo menos un miembro del grupo constituido por compuestos con contenido de radicales nitroxi y nitrosoanilinas.
ARP050104960A 2004-12-03 2005-11-28 Acidos sulfonicos, aminas y nitrofenoles aromaticos en combinacion con compuestos con contenido de radicales nitroxilo o c- nitrosanilinas como inhibidores de la polimerizacion AR054993A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US63252804P 2004-12-03 2004-12-03
US11/170,304 US7696290B2 (en) 2004-12-03 2005-06-28 Aromatic sulfonic acids, amines, and nitrophenols in combination with nitroxyl radical-containing compounds or C-nitrosanilines as polymerization inhibitors

Publications (1)

Publication Number Publication Date
AR054993A1 true AR054993A1 (es) 2007-08-01

Family

ID=35809543

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP050104960A AR054993A1 (es) 2004-12-03 2005-11-28 Acidos sulfonicos, aminas y nitrofenoles aromaticos en combinacion con compuestos con contenido de radicales nitroxilo o c- nitrosanilinas como inhibidores de la polimerizacion

Country Status (11)

Country Link
US (2) US7696290B2 (es)
EP (1) EP1817271A1 (es)
KR (1) KR20070086820A (es)
AR (1) AR054993A1 (es)
BR (1) BRPI0518906A2 (es)
CA (1) CA2589038C (es)
MX (1) MX2007006608A (es)
MY (1) MY145436A (es)
RU (1) RU2391328C2 (es)
TW (1) TWI376360B (es)
WO (1) WO2006062563A1 (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7691952B2 (en) * 2004-09-28 2010-04-06 Chemtura Corporation Sulfonated nitrophenols as polymerization inhibitors
US20080200616A1 (en) * 2004-11-15 2008-08-21 Seiji Tanizaki Method of Inhibiting Polymerization Giving Copolymer of Divinylbenzene and Aromatic Vinyl Compound
CN101410355B (zh) * 2006-03-24 2013-09-18 伯东株式会社 芳族乙烯基化合物的聚合抑制方法
KR100824587B1 (ko) 2007-08-10 2008-04-24 한국바이오젠 주식회사 비닐 방향족 단량체 생산 및 정제를 위한 효율적 중합방지조성물
EP2233505A1 (en) * 2009-03-23 2010-09-29 Total Petrochemicals Research Feluy Stabilised compositions comprising olefins
JP5675184B2 (ja) * 2010-06-18 2015-02-25 伯東株式会社 ビニル化合物の重合防止剤組成物ならびにこれを用いたビニル化合物の重合防止方法
CN102399310B (zh) * 2010-09-09 2013-07-24 通用电气公司 抑制过早聚合的组合物和方法
RU2470911C2 (ru) * 2011-03-29 2012-12-27 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Сибирский государственный технологический университет" (СибГТУ) Способ получения n-алкил-3-метил-4-нитрозоанилинов
CN102516005A (zh) * 2011-11-21 2012-06-27 上海泰顿化工有限公司 一种硝酰基化合物组合及用途
EP2785669B1 (en) * 2011-11-29 2016-02-03 Dorf Ketal Chemicals (India) Private Limited Amine based additive composition for control and inhibition of polymerization of styrene, and method of use thereof
JP6006331B2 (ja) * 2011-12-26 2016-10-12 ドルフ ケタール ケミカルズ（インド）プライベート リミテッドＤｏｒｆ Ｋｅｔａｌ Ｃｈｅｍｉｃａｌｓ （Ｉｎｄｉａ） Ｐｒｉｖａｔｅ Ｌｉｍｉｔｅｄ 芳香族ビニルモノマーの重合を制御及び阻害する改善されたアミン系添加剤組成物、及びその使用方法
WO2014130008A1 (en) * 2013-02-19 2014-08-28 General Electric Company Use of aliphatic nitroso compounds as inhibitors of radical polymerization of activated vinyl monomers
IN2013MU01165A (es) * 2013-03-26 2015-04-24 Dorf Ketal Chemicals India Private Ltd
TW202005938A (zh) 2018-07-13 2020-02-01 美商藝康美國公司 具有胺穩定劑之聚合抑制劑及阻滯劑組合物
TWI826485B (zh) 2018-07-13 2023-12-21 美商藝康美國公司 作為乙烯系單體之防垢劑之含氧胺及醌甲基化物之組合物

Family Cites Families (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2046356A (en) 1933-12-27 1936-07-07 Ici Ltd Manufacture of diarylamine derivatives
US2867672A (en) 1955-08-29 1959-01-06 Shell Dev Method of minimizing styrene polymerization during storage
US3163677A (en) 1961-08-07 1964-12-29 American Cyanamid Co Process for preparing n, n, o-trisubstituted hydroxyl amines and n, n-disubstituted nitroxides and products
US3502692A (en) 1962-06-13 1970-03-24 American Cyanamid Co Cyclic nitroxides and process for preparing same
GB983134A (en) 1962-06-13 1965-02-10 American Cyanamid Co Cyclic nitroxides and process for preparing same
NL296169A (es) 1962-08-14
US3422144A (en) 1965-04-27 1969-01-14 American Cyanamid Co Stable free radical nitroxides
US3372182A (en) 1965-04-27 1968-03-05 American Cyanamid Co Process for preparation of stable, free radical nitroxides
GB1064845A (en) * 1966-03-10 1967-04-12 Ferenc Tudos Inhibiting polymerisation
FR1501769A (fr) 1966-07-04 1967-11-18 Commissariat Energie Atomique Radicaux libres du type nitroxyde
US3873564A (en) 1971-03-03 1975-03-25 Synvar Ass 2-Imidazolinyl-3-oxide-1-oxypropionic acid
GB1354420A (en) 1971-05-17 1974-06-05 Volgogradsky Politekh Inst Isoprene treatment
CH579118A5 (es) 1973-06-22 1976-08-31 Ciba Geigy Ag
US4210493A (en) * 1976-03-30 1980-07-01 Rohm And Haas Company C-Nitroso compounds as anaerobic polymerization inhibitors for acrylic acid or methacrylic acid
JPS52153817A (en) 1976-06-18 1977-12-21 Masatoshi Tsuda Flux for modification of proeutectic silicon in the high silicon aluminium alloy
US4086147A (en) 1976-12-10 1978-04-25 Cosden Technology, Inc. Polymerization inhibitor for vinyl aromatic compounds
SU1027150A1 (ru) 1981-10-21 1983-07-07 Научно-Исследовательский Институт Механики И Физики При Саратовском Ордена Трудового Красного Знамени Государственном Университете Им.Н.Г.Чернышевского Способ стабилизации стирола или метилметакрилата
US4468343A (en) 1983-04-11 1984-08-28 Cosden Technology, Inc. Polymerization co-inhibitors for vinyl aromatic compounds
SU1139722A1 (ru) 1983-04-12 1985-02-15 Ереванское Отделение Охтинского Ордена Ленина И Ордена Трудового Красного Знамени Научно-Производственного Объединения "Пластполимер" Способ ингибировани полимеризации стирола
US4665185A (en) 1984-03-22 1987-05-12 Ciba-Geigy Corporation Process for preparing nitroxyls of sterically hindered amines
US4664845A (en) 1986-01-09 1987-05-12 Uniroyal Chemical Company, Inc. Phenylenediamine solubilizer for dinitrophenol in aromatic solvent
US4670131A (en) * 1986-01-13 1987-06-02 Exxon Chemical Patents Inc. Method for controlling fouling of hydrocarbon compositions containing olefinic compounds
SU1558888A1 (ru) 1987-12-11 1990-04-23 Всесоюзный Научно-Исследовательский Институт Химических Реактивов И Особочистых Химических Веществ Способ ингибировани полимеризации стирола
US5023372A (en) 1989-05-16 1991-06-11 Betz Laboratories, Inc. Methods and compositions for inhibiting (meth)acrylic acid polymerization
US5290888A (en) 1990-07-20 1994-03-01 Ciba-Geigy Corporation Process for stabilizing ethylenically unsaturated compounds and stabilized monomer compositions
US5212272A (en) * 1990-10-31 1993-05-18 Peach State Labs, Inc. Polyacrylic acid compositions for textile processing
US5157175A (en) 1991-09-09 1992-10-20 Nalco Chemical Company Composition and method for inhibition of styrene polymerization
US5254888A (en) * 1992-03-27 1993-10-19 Picopower Technology Inc. Switchable clock circuit for microprocessors to thereby save power
US5254760A (en) 1992-07-29 1993-10-19 Ciba-Geigy Corporation Inhibiting polymerization of vinyl aromatic monomers
JPH06234700A (ja) 1993-02-12 1994-08-23 Dainippon Ink & Chem Inc （メタ）アクリル酸エステル類の製造方法
US5728872A (en) 1994-06-27 1998-03-17 Lutz Riemenschneider Stabilized acrylic acid compositions
US5446220A (en) * 1994-08-24 1995-08-29 Betz Laboratories, Inc. Methods for inhibiting vinyl aromatic monomer polymerization
US5545786C1 (en) 1994-11-28 2001-10-16 Ciba Geigy Corp Method for inhibiting premature polymerization of vinyl aromatic monomers
US5590232A (en) 1995-02-16 1996-12-31 Motorola, Inc. Optical package and method of making
DE19510184A1 (de) 1995-03-21 1996-09-26 Basf Ag 4-Acylaminopiperidin-N-oxyle
US5648573A (en) 1995-06-12 1997-07-15 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
ES2162299T5 (es) 1996-06-05 2010-09-13 Basf Se Mezclas que contienen monomeros y estabilizantes.
DE19651307A1 (de) 1996-12-10 1998-06-18 Basf Ag Stoffmischungen, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren
US5932735A (en) 1997-06-13 1999-08-03 Ciba Specialty Chemicals Corporation Derivatives of 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers
US6136951A (en) 1999-08-16 2000-10-24 Uniroyal Chemical Company, Inc. Test method for evaluating insoluble polymer growth
AR029410A1 (es) 1999-12-02 2003-06-25 Crompton Corp Metodo para inhibir la polimerizacion prematura de monomeros etilenicamente insaturados y composiciones de los mismos
BR0016112A (pt) 1999-12-02 2002-11-26 Crompton Corp Método para inibir a polimerização prematura de monÈmeros etilenicamente insaturados e composição
US6685823B2 (en) * 2000-10-16 2004-02-03 Uniroyal Chemical Company, Inc. C-nitrosoaniline compounds and their blends as polymerization inhibitors
WO2002033026A1 (en) 2000-10-16 2002-04-25 Uniroyal Chemical Company, Inc. Blends of quinone alkide and nitroxyl compounds as polymerization inhibitors
JP3788950B2 (ja) 2001-04-25 2006-06-21 伯東株式会社 芳香族ビニル化合物の重合抑制方法
KR100927635B1 (ko) 2002-02-15 2009-11-20 켐트라 코포레이션 중합 억제제로서 니트로소페놀 및 ｃ-니트로소아닐린
JP4165816B2 (ja) 2003-03-31 2008-10-15 伯東株式会社 芳香族ビニル化合物の重合抑制剤組成物

Also Published As

Publication number Publication date
MX2007006608A (es) 2007-08-14
US7696290B2 (en) 2010-04-13
US7728083B1 (en) 2010-06-01
KR20070086820A (ko) 2007-08-27
MY145436A (en) 2012-02-15
WO2006062563A1 (en) 2006-06-15
CA2589038A1 (en) 2006-06-15
US20060122341A1 (en) 2006-06-08
RU2007125138A (ru) 2009-01-10
EP1817271A1 (en) 2007-08-15
US20100127218A1 (en) 2010-05-27
TWI376360B (en) 2012-11-11
BRPI0518906A2 (pt) 2008-12-16
TW200635894A (en) 2006-10-16
RU2391328C2 (ru) 2010-06-10
CA2589038C (en) 2013-06-25

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