BRPI0515540A - método para inibir polimerização prematura e composição - Google Patents

método para inibir polimerização prematura e composição

Info

Publication number
BRPI0515540A
BRPI0515540A BRPI0515540-1A BRPI0515540A BRPI0515540A BR PI0515540 A BRPI0515540 A BR PI0515540A BR PI0515540 A BRPI0515540 A BR PI0515540A BR PI0515540 A BRPI0515540 A BR PI0515540A
Authority
BR
Brazil
Prior art keywords
composition
group
premature polymerization
inhibit premature
hydrogen
Prior art date
Application number
BRPI0515540-1A
Other languages
English (en)
Inventor
Vilden Kosover
Jesus R Fabian
Istvan Lippai
Brigitte Benage
Gerald J Abruscato
Original Assignee
Chemtura Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemtura Corp filed Critical Chemtura Corp
Publication of BRPI0515540A publication Critical patent/BRPI0515540A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/41—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton
    • C07C309/42—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton having the sulfo groups bound to carbon atoms of non-condensed six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols
    • C08K5/375—Thiols containing six-membered aromatic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogenated Pyridines (AREA)

Abstract

"MéTODO PARA INIBIR POLIMERIZAçãO PREMATURA E COMPOSIçãO". Aqui revelamos um método para inibir a polimerização prematura e o crescimento polimérico de monómeros etilenicamente insaturados compreendendo adicionar aos monómeros uma quantidade eficaz de uma combinação de: (A) pelo menos um inibidor que é um fenol sulfonado da fórmula: em que (1) R~ 2~ é selecionado do grupo consistindo em hidrogênio e hidrocarbil; e (2) R~ 1~ e R~ 3~ são independentemente selecionados do grupo consistindo em hidrogênio e SO~ 3~H, contanto que pelo menos um dentre R~ 1~ e R~ 3~ seja SO~ 3~H; (B) pelo menos um inibidor que é um nitrofenol; e opcionalmente, (C) um inibidor selecionado do grupo consistindo em compostos de nitroxil e nitrosoanilinas; e (D) uma amina.
BRPI0515540-1A 2004-09-28 2005-07-20 método para inibir polimerização prematura e composição BRPI0515540A (pt)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US61437804P 2004-09-28 2004-09-28
US63124104P 2004-11-29 2004-11-29
US11/172,517 US20060069219A1 (en) 2004-09-28 2005-06-29 Sulfonated phenols with nitrophenols as polymerization inhibitors
PCT/US2005/026016 WO2006036274A1 (en) 2004-09-28 2005-07-20 Sulfonated phenols with nitrophenols as polymerization inhibitors

Publications (1)

Publication Number Publication Date
BRPI0515540A true BRPI0515540A (pt) 2008-07-29

Family

ID=35385340

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0515540-1A BRPI0515540A (pt) 2004-09-28 2005-07-20 método para inibir polimerização prematura e composição

Country Status (16)

Country Link
US (1) US20060069219A1 (pt)
EP (1) EP1794106B1 (pt)
JP (1) JP5175550B2 (pt)
KR (1) KR101181599B1 (pt)
CN (1) CN102766009A (pt)
AR (1) AR050962A1 (pt)
AT (1) ATE463473T1 (pt)
BR (1) BRPI0515540A (pt)
CA (1) CA2581526C (pt)
DE (1) DE602005020473D1 (pt)
ES (1) ES2343071T3 (pt)
MX (1) MX2007003663A (pt)
MY (1) MY146410A (pt)
PL (1) PL1794106T3 (pt)
TW (1) TWI374131B (pt)
WO (1) WO2006036274A1 (pt)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006083923A1 (en) * 2005-02-04 2006-08-10 Chemtura Corporation Means for controlling the exothermic reaction of styrenic monomers with sulfonic acids
US9206268B2 (en) * 2011-09-16 2015-12-08 General Electric Company Methods and compositions for inhibiting polystyrene formation during styrene production
AU2012364217B2 (en) * 2011-12-26 2015-05-14 Dorf Ketal Chemicals (India) Private Limited Improved amine based additive composition for control and inhibition of polymerization of aromatic vinyl monomers, and method of use thereof

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* Cited by examiner, † Cited by third party
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US2867672A (en) * 1955-08-29 1959-01-06 Shell Dev Method of minimizing styrene polymerization during storage
US3163677A (en) * 1961-08-07 1964-12-29 American Cyanamid Co Process for preparing n, n, o-trisubstituted hydroxyl amines and n, n-disubstituted nitroxides and products
US3502692A (en) * 1962-06-13 1970-03-24 American Cyanamid Co Cyclic nitroxides and process for preparing same
GB983134A (en) * 1962-06-13 1965-02-10 American Cyanamid Co Cyclic nitroxides and process for preparing same
US3422144A (en) * 1965-04-27 1969-01-14 American Cyanamid Co Stable free radical nitroxides
US3372182A (en) * 1965-04-27 1968-03-05 American Cyanamid Co Process for preparation of stable, free radical nitroxides
FR1501769A (fr) * 1966-07-04 1967-11-18 Commissariat Energie Atomique Radicaux libres du type nitroxyde
US3873564A (en) * 1971-03-03 1975-03-25 Synvar Ass 2-Imidazolinyl-3-oxide-1-oxypropionic acid
GB1354420A (en) * 1971-05-17 1974-06-05 Volgogradsky Politekh Inst Isoprene treatment
US4086147A (en) * 1976-12-10 1978-04-25 Cosden Technology, Inc. Polymerization inhibitor for vinyl aromatic compounds
US4468343A (en) * 1983-04-11 1984-08-28 Cosden Technology, Inc. Polymerization co-inhibitors for vinyl aromatic compounds
US4665185A (en) * 1984-03-22 1987-05-12 Ciba-Geigy Corporation Process for preparing nitroxyls of sterically hindered amines
US4664845A (en) * 1986-01-09 1987-05-12 Uniroyal Chemical Company, Inc. Phenylenediamine solubilizer for dinitrophenol in aromatic solvent
US4670131A (en) * 1986-01-13 1987-06-02 Exxon Chemical Patents Inc. Method for controlling fouling of hydrocarbon compositions containing olefinic compounds
US5290888A (en) * 1990-07-20 1994-03-01 Ciba-Geigy Corporation Process for stabilizing ethylenically unsaturated compounds and stabilized monomer compositions
US5212272A (en) * 1990-10-31 1993-05-18 Peach State Labs, Inc. Polyacrylic acid compositions for textile processing
US5157175A (en) * 1991-09-09 1992-10-20 Nalco Chemical Company Composition and method for inhibition of styrene polymerization
JP2914075B2 (ja) * 1992-04-30 1999-06-28 大日本インキ化学工業株式会社 （メタ）アクリル酸エステルの製造法
US5254760A (en) * 1992-07-29 1993-10-19 Ciba-Geigy Corporation Inhibiting polymerization of vinyl aromatic monomers
JPH06234700A (ja) * 1993-02-12 1994-08-23 Dainippon Ink & Chem Inc （メタ）アクリル酸エステル類の製造方法
US5446220A (en) * 1994-08-24 1995-08-29 Betz Laboratories, Inc. Methods for inhibiting vinyl aromatic monomer polymerization
US5545786C1 (en) * 1994-11-28 2001-10-16 Ciba Geigy Corp Method for inhibiting premature polymerization of vinyl aromatic monomers
JPH08217726A (ja) * 1995-02-15 1996-08-27 Dainippon Ink & Chem Inc ペンタエリスリトール（メタ）アクリルエステルの製造方法
DE59704135D1 (de) * 1996-06-05 2001-09-13 Basf Ag Mischungen, enthaltend monomere und stabilisatoren
US5932735A (en) * 1997-06-13 1999-08-03 Ciba Specialty Chemicals Corporation Derivatives of 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers
US6200461B1 (en) * 1998-11-05 2001-03-13 Betzdearborn Inc. Method for inhibiting polymerization of ethylenically unsaturated hydrocarbons
US6403850B1 (en) * 2000-01-18 2002-06-11 Uniroyal Chemical Company, Inc. Inhibition of polymerization of unsaturated monomers
CA2422655A1 (en) * 2000-10-16 2002-04-25 Uniroyal Chemical Company, Inc. Blends of quinone alkide and nitroxyl compounds as polymerization inhibitors
JP3788950B2 (ja) * 2001-04-25 2006-06-21 伯東株式会社 芳香族ビニル化合物の重合抑制方法
ATE496019T1 (de) * 2002-02-15 2011-02-15 Chemtura Corp Nitrosophenole und c-nitrosoaniline als polymerisationsinhibitoren
US7691952B2 (en) * 2004-09-28 2010-04-06 Chemtura Corporation Sulfonated nitrophenols as polymerization inhibitors

Also Published As

Publication number Publication date
MY146410A (en) 2012-08-15
CA2581526C (en) 2013-02-12
ATE463473T1 (de) 2010-04-15
TWI374131B (en) 2012-10-11
EP1794106A1 (en) 2007-06-13
EP1794106B1 (en) 2010-04-07
CA2581526A1 (en) 2006-04-06
CN102766009A (zh) 2012-11-07
KR101181599B1 (ko) 2012-09-13
KR20070058528A (ko) 2007-06-08
WO2006036274A1 (en) 2006-04-06
JP5175550B2 (ja) 2013-04-03
PL1794106T3 (pl) 2010-09-30
AR050962A1 (es) 2006-12-06
DE602005020473D1 (de) 2010-05-20
JP2008514598A (ja) 2008-05-08
MX2007003663A (es) 2007-06-13
TW200616938A (en) 2006-06-01
ES2343071T3 (es) 2010-07-22
US20060069219A1 (en) 2006-03-30

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Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 9A ANUIDADE.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2264 DE 27/05/2014.