BRPI0514800B1 - processo para oxidação em fase líquida, e reator de coluna de bolhas - Google Patents
processo para oxidação em fase líquida, e reator de coluna de bolhas Download PDFInfo
- Publication number
- BRPI0514800B1 BRPI0514800B1 BRPI0514800A BRPI0514800A BRPI0514800B1 BR PI0514800 B1 BRPI0514800 B1 BR PI0514800B1 BR PI0514800 A BRPI0514800 A BR PI0514800A BR PI0514800 A BRPI0514800 A BR PI0514800A BR PI0514800 B1 BRPI0514800 B1 BR PI0514800B1
- Authority
- BR
- Brazil
- Prior art keywords
- reaction medium
- reaction
- bubble column
- oxidation
- reaction zone
- Prior art date
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- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011175 product filtration Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000008521 reorganization Effects 0.000 description 1
- 238000001226 reprecipitation Methods 0.000 description 1
- 238000006798 ring closing metathesis reaction Methods 0.000 description 1
- SMQUZDBALVYZAC-UHFFFAOYSA-N salicylaldehyde Chemical class OC1=CC=CC=C1C=O SMQUZDBALVYZAC-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000000000 tetracarboxylic acids Chemical class 0.000 description 1
- 150000005201 tetramethylbenzenes Chemical class 0.000 description 1
- 229920006345 thermoplastic polyamide Polymers 0.000 description 1
- 150000005199 trimethylbenzenes Chemical class 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
- 150000003739 xylenols Chemical class 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1872—Details of the fluidised bed reactor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/006—Baffles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1836—Heating and cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
- B01J2208/0015—Plates; Cylinders
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60685604P | 2004-09-02 | 2004-09-02 | |
| US63132004P | 2004-11-29 | 2004-11-29 | |
| US63139904P | 2004-11-29 | 2004-11-29 | |
| US11/154,202 US7692036B2 (en) | 2004-11-29 | 2005-06-16 | Optimized liquid-phase oxidation |
| US11/154,218 US7568361B2 (en) | 2004-09-02 | 2005-06-16 | Optimized liquid-phase oxidation |
| PCT/US2005/030546 WO2006028752A2 (en) | 2004-09-02 | 2005-08-29 | Optimized liquid-phase oxidation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0514800A BRPI0514800A (pt) | 2008-06-24 |
| BRPI0514800B1 true BRPI0514800B1 (pt) | 2015-11-24 |
Family
ID=35504618
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0514800A BRPI0514800B1 (pt) | 2004-09-02 | 2005-08-29 | processo para oxidação em fase líquida, e reator de coluna de bolhas |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP1791800B1 (enExample) |
| JP (1) | JP2008511638A (enExample) |
| KR (2) | KR101363824B1 (enExample) |
| CN (2) | CN101023046B (enExample) |
| BR (1) | BRPI0514800B1 (enExample) |
| CA (1) | CA2576632A1 (enExample) |
| ES (1) | ES2655728T3 (enExample) |
| LT (1) | LT1791800T (enExample) |
| MX (1) | MX2007002565A (enExample) |
| PL (1) | PL1791800T3 (enExample) |
| PT (1) | PT1791800T (enExample) |
| WO (1) | WO2006028752A2 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8066949B2 (en) | 2008-09-26 | 2011-11-29 | Exxonmobil Research & Engineering Company | Scrubber for fluid coker unit |
| US8933265B2 (en) * | 2010-06-30 | 2015-01-13 | Uop Llc | Process for oxidizing alkyl aromatic compounds |
| US8933266B2 (en) * | 2010-06-30 | 2015-01-13 | Uop Llc | Process for producing terephthalic acid |
| WO2015043698A1 (de) * | 2013-09-25 | 2015-04-02 | Linde Aktiengesellschaft | Kolonne mit flüssigkeitsverteiler und stoffaustauschboden aus winkelprofilen |
| CN109772236B (zh) * | 2017-11-14 | 2022-08-12 | 中国石油化工股份有限公司 | 一种流体分布器、反应装置及其应用 |
| KR102849255B1 (ko) | 2021-12-10 | 2025-08-21 | 주식회사 엘지화학 | 기포탑 반응기 |
| CN116351334B (zh) * | 2022-12-14 | 2026-05-08 | 安徽利科新材料科技有限公司 | Mnmp生产装置及生产方法 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT236346B (de) * | 1961-01-25 | 1964-10-12 | Union Carbide Corp | Boden zum Inberührungbringen von Flüssigkeit und Gas |
| DE1493192A1 (de) * | 1963-04-30 | 1969-02-20 | Standard Oil Co | Verfahren zur Herstellung von aromatischen Saeuren |
| GB1250222A (enExample) * | 1968-10-25 | 1971-10-20 | ||
| US3660476A (en) * | 1968-10-30 | 1972-05-02 | Teijin Ltd | Method for the preparation of terephthalic acid |
| BE724040A (enExample) * | 1968-11-18 | 1969-05-02 | ||
| JPS5912096B2 (ja) * | 1975-10-31 | 1984-03-21 | 三菱化学株式会社 | ホウコウゾクポリカルボンサンノセイゾウホウ |
| JPS58177106A (ja) * | 1982-04-13 | 1983-10-17 | Jgc Corp | 多段式高流速気液接触装置 |
| JPS59104345A (ja) * | 1982-12-03 | 1984-06-16 | Kuraray Yuka Kk | 直接重合用に適したテレフタル酸の製造方法 |
| DE4318893A1 (de) * | 1993-06-07 | 1994-12-08 | Bayer Ag | Reaktor und damit durchzuführendes kontinuierliches Verfahren zur Herstellung von Ethylenglykolcarbonat bzw. Propylenglykolcarbonat |
| JP3719448B2 (ja) * | 1993-07-29 | 2005-11-24 | 三菱瓦斯化学株式会社 | 芳香族ジカルボン酸製造用酸化反応器 |
| SI9500109A (en) * | 1995-04-05 | 1996-10-31 | Levec Janez Dipl Ing Prof Dr | Apparatus and Process for Thermal Oxidative Treatment of Waste Waters |
| US5929274A (en) * | 1995-06-07 | 1999-07-27 | Hfm International, Inc. | Method to reduce carboxybenzaldehyde isomers in terephthalic acid or isophthalic acid |
| JPH09278709A (ja) * | 1996-02-13 | 1997-10-28 | Mitsubishi Chem Corp | 芳香族カルボン酸の製造方法 |
| US6084125A (en) * | 1996-02-27 | 2000-07-04 | Praxair Technology, Inc. | Process for producing aliphatic acids using a reactor system having a shell and a tube reactor configuration to force circulation of reaction liquid |
| ID19133A (id) * | 1996-12-12 | 1998-06-18 | Praxair Technology Inc | Pengisian oksigen langsung kedalam reaktor-reaktor ruang gelembung |
| GB9701251D0 (en) * | 1997-01-22 | 1997-03-12 | Bp Chem Int Ltd | Process |
| DE19843573A1 (de) * | 1998-09-23 | 2000-03-30 | Degussa | Blasensäule und deren Verwendung |
| AU2001232878A1 (en) * | 2000-01-21 | 2001-07-31 | Bp Corporation North America Inc. | Production of high purity aromatic carboxylic acid by oxidation in benzoic acid and water solvent |
| AU2003293251A1 (en) * | 2002-12-09 | 2004-06-30 | Eastman Chemical Company | Process for the oxidative purification of terephthalic acid |
| JP2006509044A (ja) * | 2002-12-09 | 2006-03-16 | イーストマン ケミカル カンパニー | 粗製カルボン酸スラリーの精製方法 |
| US7074954B2 (en) * | 2002-12-09 | 2006-07-11 | Eastman Chemical Company | Process for the oxidative purification of terephthalic acid |
-
2005
- 2005-08-29 PT PT57929143T patent/PT1791800T/pt unknown
- 2005-08-29 KR KR1020127032262A patent/KR101363824B1/ko not_active Expired - Lifetime
- 2005-08-29 KR KR1020077006865A patent/KR101281347B1/ko not_active Expired - Lifetime
- 2005-08-29 PL PL05792914T patent/PL1791800T3/pl unknown
- 2005-08-29 JP JP2007530196A patent/JP2008511638A/ja active Pending
- 2005-08-29 EP EP05792914.3A patent/EP1791800B1/en not_active Expired - Lifetime
- 2005-08-29 CN CN200580029558.1A patent/CN101023046B/zh not_active Expired - Lifetime
- 2005-08-29 ES ES05792914.3T patent/ES2655728T3/es not_active Expired - Lifetime
- 2005-08-29 CN CN2010101169790A patent/CN101766979B/zh not_active Expired - Lifetime
- 2005-08-29 WO PCT/US2005/030546 patent/WO2006028752A2/en not_active Ceased
- 2005-08-29 BR BRPI0514800A patent/BRPI0514800B1/pt active IP Right Grant
- 2005-08-29 MX MX2007002565A patent/MX2007002565A/es active IP Right Grant
- 2005-08-29 LT LTEP05792914.3T patent/LT1791800T/lt unknown
- 2005-08-29 CA CA002576632A patent/CA2576632A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| MX2007002565A (es) | 2007-04-24 |
| CN101023046B (zh) | 2019-01-18 |
| EP1791800B1 (en) | 2017-11-01 |
| WO2006028752A3 (en) | 2006-06-01 |
| KR101281347B1 (ko) | 2013-07-02 |
| KR20130003039A (ko) | 2013-01-08 |
| CN101023046A (zh) | 2007-08-22 |
| CN101766979A (zh) | 2010-07-07 |
| CN101766979B (zh) | 2012-12-26 |
| LT1791800T (lt) | 2018-01-25 |
| WO2006028752A2 (en) | 2006-03-16 |
| BRPI0514800A (pt) | 2008-06-24 |
| CA2576632A1 (en) | 2006-03-16 |
| JP2008511638A (ja) | 2008-04-17 |
| EP1791800A2 (en) | 2007-06-06 |
| KR20070048256A (ko) | 2007-05-08 |
| KR101363824B1 (ko) | 2014-02-17 |
| ES2655728T3 (es) | 2018-02-21 |
| PL1791800T3 (pl) | 2018-04-30 |
| PT1791800T (pt) | 2018-02-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 9A ANUIDADE. |
|
| B08H | Application fees: decision cancelled [chapter 8.8 patent gazette] |
Free format text: REFERENTE AO DESPACHO PUBLICADO 8.6 NA RPI 2269 DE 01/07/2014 |
|
| B25G | Requested change of headquarter approved |
Owner name: EASTMAN CHEMICAL COMPANY (US) |
|
| B25A | Requested transfer of rights approved |
Owner name: GRUPO PETROTEMEX, S.A. DE C.V. (MX) |
|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 24/11/2015, OBSERVADAS AS CONDICOES LEGAIS. |