BRPI0513183A - método para a produção de camadas de bordas resistentes à fatiga e resistentes ao desgaste em ligas de titánio, e componentes produzidos com as mesmas - Google Patents
método para a produção de camadas de bordas resistentes à fatiga e resistentes ao desgaste em ligas de titánio, e componentes produzidos com as mesmasInfo
- Publication number
- BRPI0513183A BRPI0513183A BRPI0513183-9A BRPI0513183A BRPI0513183A BR PI0513183 A BRPI0513183 A BR PI0513183A BR PI0513183 A BRPI0513183 A BR PI0513183A BR PI0513183 A BRPI0513183 A BR PI0513183A
- Authority
- BR
- Brazil
- Prior art keywords
- resistant
- titanium
- wear resistant
- produced
- reaction gas
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/20—Carburising
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/20—Bonding
- B23K26/32—Bonding taking account of the properties of the material involved
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/34—Laser welding for purposes other than joining
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K31/00—Processes relevant to this subclass, specially adapted for particular articles or purposes, but not covered by only one of the preceding main groups
- B23K31/02—Processes relevant to this subclass, specially adapted for particular articles or purposes, but not covered by only one of the preceding main groups relating to soldering or welding
- B23K31/025—Connecting cutting edges or the like to tools; Attaching reinforcements to workpieces, e.g. wear-resisting zones to tableware
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/32—Selection of soldering or welding materials proper with the principal constituent melting at more than 1550 degrees C
- B23K35/325—Ti as the principal constituent
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/08—Coating starting from inorganic powder by application of heat or pressure and heat
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/24—Nitriding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2101/00—Articles made by soldering, welding or cutting
- B23K2101/001—Turbines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/08—Non-ferrous metals or alloys
- B23K2103/14—Titanium or alloys thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T50/00—Aeronautics or air transport
- Y02T50/60—Efficient propulsion technologies, e.g. for aircraft
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Optics & Photonics (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Laser Beam Processing (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Chemical Vapour Deposition (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Laminated Bodies (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
Abstract
MéTODO PARA A PRODUçãO DE CAMADAS DE BORDAS RESISTENTES à FATIGA E RESISTENTES AO DESGASTE EM LIGAS DE TITáNIO, E COMPONENTES PRODUZIDOS COM AS MESMAS. A invenção refere-se ao acabamento de camada de borda de componentes funcionais, e desse modo em particular a um método para a produção de camadas de borda resistentes à fatiga e resistentes ao desgaste em ligas de titânio, e componentes produzidos com as mesmas. O método de acordo com a invenção para a produção de camadas de borda resistentes à fatiga e resistentes ao desgaste em ligas de titânio por meio de ligação de gás de laser é essencialmente caracterizado pelo fato de que a ligação de gás de laser é realizada com um gás de reação que contém ou libera elementos intersticialmente solúveis na liga de titânio usada, pelo que a pressão parcial do gás de reação é selecionada tal que a pressão parcial permanece abaixo do valor limiar acima do qual fases de titânio de boreto, carbeto ou nitreto são produzidas. As características de acordo com a invenção do componente resistente à fatiga e resistente ao desgaste produzido de uma liga de titânio com uma camada de borda ligada a gás essencialmente são que a camada de borda resistente ao desgaste é constituída de uma mistura de grão fino de grãos de alfa- e beta-titânio com um gás de reação intersticialmente dissolvido, tem uma dureza de superfície H~ s~, medida na superfície esmerilada, de 360 HV0 5 <243> H~ s~<243> 500 HV0.5, ou uma microdureza de camada de borda H~ r~, medida em uma seção transversal polida a 0,1 mm abaixo da superfície, de 360 HV0.1 <243> HR <243> 560 HV0.1, estende acima de uma profundidade t~ R~ de 0,1 mm <243> t~ R~ <243> 3,5 mm, e não contém quaisquer fases de nitreto, carbeto, óxido ou boreto produzidas pelo gás de reação.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004033342A DE102004033342A1 (de) | 2004-07-09 | 2004-07-09 | Verfahren zur Herstellung von verschleißbeständigen und ermüdungsresistenten Randschichten in Titan-Legierungen und damit hergestellte Bauteile |
PCT/EP2005/007393 WO2006005527A1 (de) | 2004-07-09 | 2005-07-08 | Verfahren zur herstellung von verschleissbeständigen und ermüdungsresistenten randschichten in titan-legierungen und damit hergestellte bauteile |
Publications (1)
Publication Number | Publication Date |
---|---|
BRPI0513183A true BRPI0513183A (pt) | 2008-04-29 |
Family
ID=34982370
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0513183-9A BRPI0513183A (pt) | 2004-07-09 | 2005-07-08 | método para a produção de camadas de bordas resistentes à fatiga e resistentes ao desgaste em ligas de titánio, e componentes produzidos com as mesmas |
Country Status (12)
Country | Link |
---|---|
US (1) | US20080011391A1 (pt) |
EP (1) | EP1769099B1 (pt) |
JP (1) | JP2008506532A (pt) |
KR (1) | KR100939799B1 (pt) |
CN (1) | CN1985019B (pt) |
BR (1) | BRPI0513183A (pt) |
CA (1) | CA2572732A1 (pt) |
DE (1) | DE102004033342A1 (pt) |
MX (1) | MX2007000196A (pt) |
PL (1) | PL1769099T3 (pt) |
RU (1) | RU2407822C2 (pt) |
WO (1) | WO2006005527A1 (pt) |
Families Citing this family (23)
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DE102004033342A1 (de) * | 2004-07-09 | 2006-02-02 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung von verschleißbeständigen und ermüdungsresistenten Randschichten in Titan-Legierungen und damit hergestellte Bauteile |
US8079120B2 (en) * | 2006-12-30 | 2011-12-20 | General Electric Company | Method for determining initial burnishing parameters |
US20090202955A1 (en) * | 2008-02-07 | 2009-08-13 | General Electric Company | Gasification feed injectors and methods of modifying the cast surfaces thereof |
US20110056919A1 (en) * | 2008-02-13 | 2011-03-10 | Bernd Burbaum | Method for Fusing Curved Surfaces, and a Device |
US8322004B2 (en) | 2009-04-29 | 2012-12-04 | Caterpilar Inc. | Indirect laser induced residual stress in a fuel system component and fuel system using same |
FR2949204B1 (fr) * | 2009-08-21 | 2011-10-14 | Snecma | Machine d'usinage pour cmc par fraisage et abrasion par ultrasons |
RU2443800C1 (ru) * | 2010-07-09 | 2012-02-27 | Учреждение Российской академии наук Институт ядерной физики им. Г.И. Будкера Сибирского отделения РАН (ИЯФ СО РАН) | Способ формирования антикоррозионного покрытия на титановых изделиях |
CN102676981B (zh) * | 2011-03-07 | 2014-05-14 | 山东万丰煤化工设备制造有限公司 | 一种钛及钛合金表面激光制备氮化钛梯度涂层的方法 |
RU2473715C2 (ru) * | 2011-03-18 | 2013-01-27 | Федеральное государственное образовательное учреждение высшего профессионального образования "Брянская государственная сельскохозяйственная академия" | Способ нанесения композиционных электрохимических покрытий на изделия с последующей электротермической обработкой |
RU2522919C1 (ru) * | 2013-01-15 | 2014-07-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Владимирский государственный университет имени Александра Григорьевича и Николая Григорьевича Столетовых" (ВлГУ) | Способ формирования микроструктурированного слоя нитрида титана |
US10829857B2 (en) * | 2013-03-12 | 2020-11-10 | United States Of America As Represented By The Administrator Of Nasa | Gas phase alloying for wire fed joining and deposition processes |
RU2551331C2 (ru) * | 2013-07-10 | 2015-05-20 | Российская Федерация, от имени которой выступает Министерство промышленности и торговли Российской Федерации (Минпромторг России) | Способ получения многослойного градиентного покрытия методом магнетронного напыления |
RU2538880C1 (ru) * | 2013-07-23 | 2015-01-10 | Общество с ограниченной ответственностью "ИННОВАТЕХПРОМ" ООО "ИННОВАТЕХПРОМ" | Тонкопленочное покрытие полюсных наконечников эндокардиальных электродов электрокардиостимуляторов и способ его получения |
DE102016211202A1 (de) * | 2016-06-22 | 2017-12-28 | Zf Friedrichshafen Ag | Verfahren und Vorrichtung zur Verbesserung der Spannungsbelastbarkeit eines druckbeaufschlagbaren Bauteils |
RU2647963C2 (ru) * | 2016-08-03 | 2018-03-21 | Общество с ограниченной ответственностью "ТБ композит" | Композиционный материал на основе титанового сплава и способ его получения |
US20190308283A1 (en) * | 2018-04-04 | 2019-10-10 | The Boeing Company | Welded titanium structure utilizing dissimilar titanium alloy filler metal for enhanced fatigue life |
CN108914048B (zh) * | 2018-07-24 | 2020-11-20 | 南华大学 | 激光微熔原位反应制备氮化钛涂层的方法 |
RU2701974C1 (ru) * | 2018-12-07 | 2019-10-02 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Казанский национальный исследовательский технический университет им. А.Н. Туполева-КАИ" (КНИТУ-КАИ) | Способ обработки листа из титанового сплава |
CN110904404B (zh) * | 2019-12-25 | 2023-07-11 | 浙江工业大学 | 基于钛合金表面激光氮化和喷丸同步复合技术的工艺方法与装置 |
CN112391625B (zh) * | 2020-11-05 | 2023-03-28 | 浙江工业大学 | 一种激光合金化复合微弧氧化制备钛合金防高温氧化涂层的方法 |
CN113529008B (zh) * | 2021-07-15 | 2022-08-19 | 西北有色金属研究院 | 一种在钛或钛合金表面制备梯度复合耐磨涂层的方法 |
DE102021215050A1 (de) | 2021-12-27 | 2023-06-29 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Verfahren und Vorrichtung zur Herstellung eines Bauteils, das mehrere Bereiche mit verschiedenen Materialeigenschaften aufweist |
CN115125463B (zh) * | 2022-07-04 | 2023-09-01 | 贵州大学 | 一种提高高强韧钛合金扭转疲劳性能的嵌套式梯度组织的制备方法 |
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JP2002097914A (ja) * | 2000-07-18 | 2002-04-05 | Fuji Oozx Inc | チタン合金製エンジンバルブ及びその製造方法 |
US20060048862A1 (en) * | 2004-06-03 | 2006-03-09 | Frank Ernst | Surface hardening of Ti alloys by gas-phase nitridation: kinetic control of the nitrogen activity |
DE102004033342A1 (de) * | 2004-07-09 | 2006-02-02 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung von verschleißbeständigen und ermüdungsresistenten Randschichten in Titan-Legierungen und damit hergestellte Bauteile |
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2004
- 2004-07-09 DE DE102004033342A patent/DE102004033342A1/de not_active Ceased
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2005
- 2005-07-08 BR BRPI0513183-9A patent/BRPI0513183A/pt not_active IP Right Cessation
- 2005-07-08 CN CN2005800232277A patent/CN1985019B/zh not_active Expired - Fee Related
- 2005-07-08 EP EP05759892.2A patent/EP1769099B1/de active Active
- 2005-07-08 JP JP2007519732A patent/JP2008506532A/ja active Pending
- 2005-07-08 PL PL05759892T patent/PL1769099T3/pl unknown
- 2005-07-08 KR KR1020077000177A patent/KR100939799B1/ko active IP Right Grant
- 2005-07-08 RU RU2007104837/02A patent/RU2407822C2/ru not_active IP Right Cessation
- 2005-07-08 WO PCT/EP2005/007393 patent/WO2006005527A1/de active Application Filing
- 2005-07-08 CA CA002572732A patent/CA2572732A1/en not_active Abandoned
- 2005-07-08 MX MX2007000196A patent/MX2007000196A/es active IP Right Grant
- 2005-07-08 US US11/571,818 patent/US20080011391A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
KR100939799B1 (ko) | 2010-02-02 |
JP2008506532A (ja) | 2008-03-06 |
CN1985019A (zh) | 2007-06-20 |
CA2572732A1 (en) | 2006-01-19 |
RU2407822C2 (ru) | 2010-12-27 |
WO2006005527A1 (de) | 2006-01-19 |
DE102004033342A1 (de) | 2006-02-02 |
EP1769099B1 (de) | 2015-02-18 |
KR20070047760A (ko) | 2007-05-07 |
CN1985019B (zh) | 2010-04-21 |
US20080011391A1 (en) | 2008-01-17 |
EP1769099A1 (de) | 2007-04-04 |
RU2007104837A (ru) | 2009-02-27 |
MX2007000196A (es) | 2007-07-09 |
PL1769099T3 (pl) | 2015-08-31 |
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