BRPI0513147B1 - composição, método para provisão de resistência a arranhão a um substrato de poliolefina, e uso de uma mistura de componentes - Google Patents
composição, método para provisão de resistência a arranhão a um substrato de poliolefina, e uso de uma mistura de componentes Download PDFInfo
- Publication number
- BRPI0513147B1 BRPI0513147B1 BRPI0513147A BRPI0513147A BRPI0513147B1 BR PI0513147 B1 BRPI0513147 B1 BR PI0513147B1 BR PI0513147 A BRPI0513147 A BR PI0513147A BR PI0513147 A BRPI0513147 A BR PI0513147A BR PI0513147 B1 BRPI0513147 B1 BR PI0513147B1
- Authority
- BR
- Brazil
- Prior art keywords
- olefin
- alpha
- tert
- butyl
- maleate
- Prior art date
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- 229920000098 polyolefin Polymers 0.000 title claims abstract description 51
- 239000000758 substrate Substances 0.000 title claims abstract description 12
- 239000000203 mixture Substances 0.000 title claims description 66
- 238000000034 method Methods 0.000 title claims description 12
- -1 polypropylene Polymers 0.000 claims abstract description 110
- 239000004711 α-olefin Substances 0.000 claims abstract description 47
- 239000000654 additive Substances 0.000 claims abstract description 39
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 26
- 150000001412 amines Chemical class 0.000 claims abstract description 23
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 23
- 239000000194 fatty acid Substances 0.000 claims abstract description 23
- 229930195729 fatty acid Natural products 0.000 claims abstract description 23
- 239000004743 Polypropylene Substances 0.000 claims abstract description 20
- 150000002148 esters Chemical class 0.000 claims abstract description 20
- 150000004665 fatty acids Chemical group 0.000 claims abstract description 18
- 229920001155 polypropylene Polymers 0.000 claims abstract description 18
- FUSNPOOETKRESL-ZPHPHTNESA-N (z)-n-octadecyldocos-13-enamide Chemical compound CCCCCCCCCCCCCCCCCCNC(=O)CCCCCCCCCCC\C=C/CCCCCCCC FUSNPOOETKRESL-ZPHPHTNESA-N 0.000 claims abstract description 9
- 239000004698 Polyethylene Substances 0.000 claims abstract description 8
- 229920000573 polyethylene Polymers 0.000 claims abstract description 8
- 239000003760 tallow Substances 0.000 claims abstract description 6
- VMRGZRVLZQSNHC-ZCXUNETKSA-N n-[(z)-octadec-9-enyl]hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(=O)NCCCCCCCC\C=C/CCCCCCCC VMRGZRVLZQSNHC-ZCXUNETKSA-N 0.000 claims abstract 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 33
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 31
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 150000001408 amides Chemical class 0.000 claims description 11
- 239000003381 stabilizer Substances 0.000 claims description 11
- 125000003342 alkenyl group Chemical group 0.000 claims description 10
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 claims description 8
- 150000003949 imides Chemical class 0.000 claims description 7
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 6
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 claims description 6
- UAUDZVJPLUQNMU-UHFFFAOYSA-N Erucasaeureamid Natural products CCCCCCCCC=CCCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-UHFFFAOYSA-N 0.000 claims description 5
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims description 5
- ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical compound C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000004611 light stabiliser Substances 0.000 claims description 4
- 229940037312 stearamide Drugs 0.000 claims description 4
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 claims description 2
- ZCILGMFPJBRCNO-UHFFFAOYSA-N 4-phenyl-2H-benzotriazol-5-ol Chemical compound OC1=CC=C2NN=NC2=C1C1=CC=CC=C1 ZCILGMFPJBRCNO-UHFFFAOYSA-N 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 2
- 239000012965 benzophenone Substances 0.000 claims description 2
- ALSTYHKOOCGGFT-UHFFFAOYSA-N cis-oleyl alcohol Natural products CCCCCCCCC=CCCCCCCCCO ALSTYHKOOCGGFT-UHFFFAOYSA-N 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 229940124543 ultraviolet light absorber Drugs 0.000 claims description 2
- 125000005313 fatty acid group Chemical group 0.000 claims 3
- OXDXXMDEEFOVHR-CLFAGFIQSA-N (z)-n-[2-[[(z)-octadec-9-enoyl]amino]ethyl]octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCNC(=O)CCCCCCC\C=C/CCCCCCCC OXDXXMDEEFOVHR-CLFAGFIQSA-N 0.000 claims 1
- NJCDRURWJZAMBM-UHFFFAOYSA-N 6-phenyl-1h-1,3,5-triazin-2-one Chemical compound OC1=NC=NC(C=2C=CC=CC=2)=N1 NJCDRURWJZAMBM-UHFFFAOYSA-N 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 150000002466 imines Chemical class 0.000 claims 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 125000001749 primary amide group Chemical group 0.000 claims 1
- 150000003334 secondary amides Chemical class 0.000 claims 1
- 229920002397 thermoplastic olefin Polymers 0.000 abstract description 10
- 230000000996 additive effect Effects 0.000 abstract description 9
- 238000010348 incorporation Methods 0.000 abstract description 6
- 230000003678 scratch resistant effect Effects 0.000 abstract description 5
- 150000002191 fatty alcohols Chemical class 0.000 abstract description 2
- 230000014759 maintenance of location Effects 0.000 abstract description 2
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- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 10
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- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 229920001684 low density polyethylene Polymers 0.000 description 9
- 239000004702 low-density polyethylene Substances 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 7
- 239000007795 chemical reaction product Substances 0.000 description 7
- 229920001903 high density polyethylene Polymers 0.000 description 7
- 239000004700 high-density polyethylene Substances 0.000 description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 7
- 239000007983 Tris buffer Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
- KXPXKNBDCUOENF-UHFFFAOYSA-N 2-(Octylthio)ethanol Chemical compound CCCCCCCCSCCO KXPXKNBDCUOENF-UHFFFAOYSA-N 0.000 description 4
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- UKJARPDLRWBRAX-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine Chemical compound C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 UKJARPDLRWBRAX-UHFFFAOYSA-N 0.000 description 4
- FPQJEXTVQZHURJ-UHFFFAOYSA-N n,n'-bis(2-hydroxyethyl)oxamide Chemical compound OCCNC(=O)C(=O)NCCO FPQJEXTVQZHURJ-UHFFFAOYSA-N 0.000 description 4
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 4
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- BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- RXFCIXRFAJRBSG-UHFFFAOYSA-N 3,2,3-tetramine Chemical compound NCCCNCCNCCCN RXFCIXRFAJRBSG-UHFFFAOYSA-N 0.000 description 3
- HSEMFIZWXHQJAE-UHFFFAOYSA-N Amide-Hexadecanoic acid Natural products CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 3
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- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
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- SEPPVOUBHWNCAW-FNORWQNLSA-N (E)-4-oxonon-2-enal Chemical compound CCCCCC(=O)\C=C\C=O SEPPVOUBHWNCAW-FNORWQNLSA-N 0.000 description 2
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- BWJKLDGAAPQXGO-UHFFFAOYSA-N 2,2,6,6-tetramethyl-4-octadecoxypiperidine Chemical compound CCCCCCCCCCCCCCCCCCOC1CC(C)(C)NC(C)(C)C1 BWJKLDGAAPQXGO-UHFFFAOYSA-N 0.000 description 2
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/48—Isomerisation; Cyclisation
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L23/04—Homopolymers or copolymers of ethene
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
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| US58609304P | 2004-07-07 | 2004-07-07 | |
| PCT/EP2005/052981 WO2006003127A1 (en) | 2004-07-07 | 2005-06-27 | Scratch resistant polyolefins |
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| BRPI0513147A BRPI0513147A (pt) | 2008-04-29 |
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| CA2606584A1 (en) * | 2005-05-12 | 2006-11-23 | Dow Global Technologies Inc. | Thermoformed, extruded sheeting with reduced gloss |
| DK1888686T3 (da) * | 2005-06-07 | 2013-04-29 | Basf Se | Ridsefaste polyolefiner |
| US7790795B2 (en) * | 2006-05-25 | 2010-09-07 | Exxonmobil Chemical Patents Inc. | Scratch and mar resistant polymer compositions, methods for making and articles made from the same |
| WO2008079998A1 (en) * | 2006-12-21 | 2008-07-03 | Dow Global Technologies Inc. | Filled tpo compositions, methods of making the same, and articles prepared from the same |
| JP2008260887A (ja) * | 2007-04-13 | 2008-10-30 | Yokohama Rubber Co Ltd:The | 熱可塑性エラストマーおよび熱可塑性エラストマー組成物 |
| BRPI0815429B1 (pt) * | 2007-09-07 | 2018-12-11 | Dow Global Technologies Inc | composição de poliolefina termoplástica com carga e artigo moldado |
| JP2009079117A (ja) * | 2007-09-26 | 2009-04-16 | Prime Polymer:Kk | ポリプロピレン系樹脂組成物 |
| US8721946B2 (en) | 2008-01-25 | 2014-05-13 | Borealis Ag | Low-sticky additive package for automotive interior applications |
| ES2433216T3 (es) * | 2008-05-15 | 2013-12-10 | Saudi Basic Industries Corporation | Artículo moldeado resistente al rayado hecho a partir de una composición de polipropileno cargada |
| JP5631331B2 (ja) * | 2008-12-22 | 2014-11-26 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 引掻耐性の向上方法及び関連製品及びその使用 |
| TWI477547B (zh) * | 2009-05-26 | 2015-03-21 | Basf Corp | 抗刮聚丙烯 |
| EP2557117B1 (en) * | 2011-08-11 | 2014-06-11 | Borealis AG | Composition with improved scratch visibility and low surface tack |
| WO2013021003A1 (en) * | 2011-08-11 | 2013-02-14 | Borealis Ag | Composition with improved long term scratch resistance and reduced surface tack |
| JP6523166B2 (ja) * | 2013-07-08 | 2019-05-29 | 株式会社プライムポリマー | プロピレン系樹脂組成物およびその用途 |
| CN108610553A (zh) * | 2018-04-20 | 2018-10-02 | 苏州睿烁环境科技有限公司 | 一种耐划伤pp塑料及其制备方法和应用 |
| CN113150436B (zh) * | 2021-03-31 | 2022-12-02 | 金发科技股份有限公司 | 一种聚丙烯组合物及其制备方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS61233033A (ja) * | 1985-04-09 | 1986-10-17 | Mitsui Petrochem Ind Ltd | ポリオレフィン組成物 |
| JPH0749499B2 (ja) | 1985-09-26 | 1995-05-31 | 住友化学工業株式会社 | ポリプロピレン系樹脂組成物 |
| JPH064733B2 (ja) * | 1986-02-03 | 1994-01-19 | 日本石油化学株式会社 | 高剛性かつ耐衝撃性ポリオレフイン樹脂組成物 |
| JPS6323964A (ja) * | 1986-07-16 | 1988-02-01 | Kao Corp | 結晶性高分子用改質剤 |
| US5731376A (en) | 1991-07-29 | 1998-03-24 | Imperial Chemical Industries Plc | Scratch resistant polymer compositions and articles |
| TW285680B (enExample) * | 1992-03-31 | 1996-09-11 | Hoechst Ag | |
| GB9302069D0 (en) | 1993-02-03 | 1993-03-24 | Ici Plc | Scratch resistant polymer compositions |
| US6497337B1 (en) | 1993-05-26 | 2002-12-24 | White Cap, Inc. | Composition and method for promoting adhesion of thermoplastic elastomers to metal substrates |
| NO309384B1 (no) | 1995-01-16 | 2001-01-22 | Borealis Holding As | Polyolefinlegering med forbedret overflatehårdhet og ripefasthet |
| US6048942A (en) | 1996-09-30 | 2000-04-11 | Montell North America Inc. | Thermoplastic olefin articles having high surface gloss and mar resistance |
| WO1999046321A1 (en) * | 1998-03-10 | 1999-09-16 | Ferro Corporation | Polymer compositions comprising polyolefins and reaction products of a polyolefin and an unsaturated carboxylic reagent and articles made therefrom |
| US6177515B1 (en) * | 1998-12-17 | 2001-01-23 | Montell Technology Company Bv | Polypropylene graft copolymers with improved scratch and mar resistance |
| US6300419B1 (en) | 1999-12-08 | 2001-10-09 | The Dow Chemical Company | Propylene polymer composition |
| JP2001261902A (ja) | 2000-03-17 | 2001-09-26 | Tokuyama Corp | ポリプロピレン系樹脂組成物 |
| JP2002003692A (ja) | 2000-04-18 | 2002-01-09 | Japan Polychem Corp | 耐傷付き性に優れたポリプロピレン系樹脂組成物 |
| KR100412452B1 (ko) * | 2001-03-08 | 2003-12-31 | 현대자동차주식회사 | 폴리프로필렌 수지 조성물 |
| JP2002338778A (ja) | 2001-05-16 | 2002-11-27 | Nof Corp | グラフト共重合体組成物、それを含有する熱可塑性樹脂組成物及びその成形体 |
| US6967225B2 (en) | 2003-05-05 | 2005-11-22 | Honda Motor Co., Ltd. | Scratch-resistant polypropylene composition |
-
2005
- 2005-02-15 US US11/058,499 patent/US7390574B2/en not_active Expired - Fee Related
- 2005-06-27 CA CA2573027A patent/CA2573027C/en not_active Expired - Fee Related
- 2005-06-27 ES ES05762950T patent/ES2307190T3/es not_active Expired - Lifetime
- 2005-06-27 JP JP2007519769A patent/JP5209304B2/ja not_active Expired - Fee Related
- 2005-06-27 AU AU2005259262A patent/AU2005259262B9/en not_active Ceased
- 2005-06-27 EP EP05762950A patent/EP1776416B1/en not_active Expired - Lifetime
- 2005-06-27 BR BRPI0513147A patent/BRPI0513147B1/pt not_active IP Right Cessation
- 2005-06-27 DE DE602005007243T patent/DE602005007243D1/de not_active Expired - Lifetime
- 2005-06-27 AT AT05762950T patent/ATE397038T1/de active
- 2005-06-27 RU RU2007104326A patent/RU2386652C2/ru not_active IP Right Cessation
- 2005-06-27 CN CN2005800230623A patent/CN1997703B/zh not_active Expired - Fee Related
- 2005-06-27 WO PCT/EP2005/052981 patent/WO2006003127A1/en not_active Ceased
- 2005-07-05 TW TW94122639A patent/TWI427112B/zh not_active IP Right Cessation
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2006
- 2006-12-15 ZA ZA200610568A patent/ZA200610568B/xx unknown
- 2006-12-28 KR KR1020067027566A patent/KR101175641B1/ko not_active Expired - Fee Related
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| US20060009554A1 (en) | 2006-01-12 |
| ZA200610568B (en) | 2008-08-27 |
| DE602005007243D1 (de) | 2008-07-10 |
| AU2005259262B2 (en) | 2011-02-24 |
| TWI427112B (zh) | 2014-02-21 |
| WO2006003127A1 (en) | 2006-01-12 |
| AU2005259262B9 (en) | 2011-03-31 |
| JP2008505993A (ja) | 2008-02-28 |
| AU2005259262A1 (en) | 2006-01-12 |
| EP1776416B1 (en) | 2008-05-28 |
| EP1776416A1 (en) | 2007-04-25 |
| CA2573027A1 (en) | 2006-01-12 |
| US7390574B2 (en) | 2008-06-24 |
| CN1997703A (zh) | 2007-07-11 |
| BRPI0513147A (pt) | 2008-04-29 |
| TW200613424A (en) | 2006-05-01 |
| JP5209304B2 (ja) | 2013-06-12 |
| RU2007104326A (ru) | 2008-08-27 |
| RU2386652C2 (ru) | 2010-04-20 |
| ES2307190T3 (es) | 2008-11-16 |
| KR101175641B1 (ko) | 2012-08-22 |
| KR20070038979A (ko) | 2007-04-11 |
| ATE397038T1 (de) | 2008-06-15 |
| CA2573027C (en) | 2013-04-02 |
| CN1997703B (zh) | 2011-07-13 |
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