BRPI0508649A - material cristalino apresentando estrutura de lta de natureza zeolìtica, método de preparação do mesmo e usos do mesmo em processos de separação e transformação de compostos orgánicos - Google Patents
material cristalino apresentando estrutura de lta de natureza zeolìtica, método de preparação do mesmo e usos do mesmo em processos de separação e transformação de compostos orgánicosInfo
- Publication number
- BRPI0508649A BRPI0508649A BRPI0508649-3A BRPI0508649A BRPI0508649A BR PI0508649 A BRPI0508649 A BR PI0508649A BR PI0508649 A BRPI0508649 A BR PI0508649A BR PI0508649 A BRPI0508649 A BR PI0508649A
- Authority
- BR
- Brazil
- Prior art keywords
- processes
- separation
- organic compounds
- crystalline material
- value
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 6
- 238000000926 separation method Methods 0.000 title abstract 3
- 239000002178 crystalline material Substances 0.000 title abstract 2
- 150000002894 organic compounds Chemical class 0.000 title abstract 2
- 230000009466 transformation Effects 0.000 title 1
- 239000000463 material Substances 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 229910004298 SiO 2 Inorganic materials 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 238000007171 acid catalysis Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001767 cationic compounds Chemical class 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 229910052729 chemical element Inorganic materials 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 229910052732 germanium Inorganic materials 0.000 abstract 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 abstract 1
- 229910001411 inorganic cation Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
- B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/14—Type A
- C01B39/145—Type A using at least one organic template directing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Catalysts (AREA)
Abstract
MATERIAL CRISTALINO APRESENTANDO ESTRUTURA DE LTA DE NATUREZA ZEOLìTICA, MéTODO DE PREPARAçãO DO MESMO E USOS DO MESMO EM PROCESSOS DE SEPARAçãO E TRANSFORMAçãO DE COMPOSTOS ORGáNICOS. A presente invenção refere-se a um material que, uma vez calcinado e no estado anidro, apresenta a fómula geral: x (M~ 1~/n ~ XO~ 2~) : z ZO~ 2~: y GeO~ 2~: (1-y) SiO~ 2~, onde x apresenta um valor inferior a 0,2, preferencialmente, inferior a 0,15, podendo ser igual a zero; apresenta um valor entre 0 e 0,1, preferencialmente, entre o e 0,05; y apresenta um valor entre 0 e 1, preferencialmente, entre 0 e 0,75; M representa um ou mais cátions inorgânicos carregados +n; X representa um ou mais elementos químicos no estado de oxidação +3 (A1, B, Ga, Fe); e Z representa um ou mais cátions no estado de oxidação +4, diferentes de silício e germânio, sendo, preferencialmente , Ti ou Sn. O dito material pode ser usado como um componente de catalisador em processos de catálise ácida ou como um suporte de metal ou óxido em processos de separação e absorção/adsorção.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ESP200400662 | 2004-03-11 | ||
ES200400662A ES2245588B1 (es) | 2004-03-11 | 2004-03-11 | Material cristalino microporoso de naturaleza zeolitica con estructura lta (itq-29), su procedimiento de preparacion y usos del mismo en procesos de transformacion y separacion de compuestos organicos. |
PCT/ES2005/000120 WO2005087663A1 (es) | 2004-03-11 | 2005-03-09 | Material cristalino microporoso de naturaleza zeolítica con estructura lta (itq-29), su procedimiento de preparación y usos del mismo en procesos de transformación y separación de compuestos orgánicos |
Publications (2)
Publication Number | Publication Date |
---|---|
BRPI0508649A true BRPI0508649A (pt) | 2007-08-14 |
BRPI0508649B1 BRPI0508649B1 (pt) | 2014-08-26 |
Family
ID=34975482
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0508649-3A BRPI0508649B1 (pt) | 2004-03-11 | 2005-03-09 | Material cristalino apresentando estrutura de lta de natureza zeolítica, método de preparação do mesmo e usos do mesmo em processos de separação e transformação de compostos orgânicos |
Country Status (13)
Country | Link |
---|---|
US (1) | US7553477B2 (pt) |
EP (1) | EP1736441A1 (pt) |
JP (1) | JP4833195B2 (pt) |
CN (1) | CN1980863B (pt) |
AU (1) | AU2005221845B2 (pt) |
BR (1) | BRPI0508649B1 (pt) |
CA (1) | CA2559112A1 (pt) |
EA (1) | EA200601676A1 (pt) |
ES (1) | ES2245588B1 (pt) |
MX (1) | MXPA06010176A (pt) |
NO (1) | NO20064592L (pt) |
NZ (1) | NZ550468A (pt) |
WO (1) | WO2005087663A1 (pt) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2249183B1 (es) * | 2004-09-15 | 2007-12-01 | Universidad Politecnica De Valencia | Uso de material cristalino microporoso de naturaleza zeolitica con estructura lta (itq-29) en procesos de adsorcion y separacion de compuestos organicos. |
US8337808B1 (en) | 2011-09-15 | 2012-12-25 | Chevron U.S.A. Inc. | Method for preparing LTA-type zeolites using a novel structure directing agent |
ES2430404B1 (es) * | 2012-04-18 | 2014-09-29 | Consejo Superior De Investigaciones Científicas (Csic) | Material ITQ-49, su procedimiento de obtención y su uso |
KR101905566B1 (ko) * | 2016-11-16 | 2018-10-08 | 현대자동차 주식회사 | 배기가스 정화장치 |
CN108502898B (zh) * | 2018-06-28 | 2019-10-25 | 沈阳理工大学 | 一种制备钛锗分子筛的方法 |
ES2871374B2 (es) * | 2020-04-28 | 2022-03-01 | Consejo Superior Investigacion | Material microporoso quiral enantio-enriquecido gtm-3, procedimiento de preparacion y usos |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2882243A (en) * | 1953-12-24 | 1959-04-14 | Union Carbide Corp | Molecular sieve adsorbents |
US3314752A (en) * | 1961-08-30 | 1967-04-18 | Mobil Oil Corp | Synthetic zeolite |
US3375205A (en) * | 1962-11-13 | 1968-03-26 | Mobil Oil Corp | Synthetic zeolite |
US4503023A (en) * | 1979-08-14 | 1985-03-05 | Union Carbide Corporation | Silicon substituted zeolite compositions and process for preparing same |
DE3812592A1 (de) | 1988-04-15 | 1989-10-26 | Deggendorfer Werft Eisenbau | Verfahren zur herstellung von zeolithen |
US5225179A (en) * | 1992-08-27 | 1993-07-06 | Chevron Research And Technology Company | Method of making molecular sieves |
ES2179753B1 (es) | 2000-10-11 | 2005-02-16 | Universidad Politecnica De Valencia | Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion gasolina. |
US6713041B1 (en) * | 2002-02-12 | 2004-03-30 | Uop Llc | Crystalline aluminosilicate zeolitic composition: UZM-9 |
US6723300B2 (en) | 2002-03-15 | 2004-04-20 | Exxonmobil Research And Engineering Company | Synthesis of porous crystalline materials in fluoride media |
FR2858334B1 (fr) * | 2003-07-30 | 2005-09-02 | Inst Francais Du Petrole | Solide cristallise im-11 de type structural lta et son procede de preparation |
US7109130B2 (en) * | 2004-05-04 | 2006-09-19 | California Institute Of Technology | Zeolite films for low k applications |
ES2249183B1 (es) * | 2004-09-15 | 2007-12-01 | Universidad Politecnica De Valencia | Uso de material cristalino microporoso de naturaleza zeolitica con estructura lta (itq-29) en procesos de adsorcion y separacion de compuestos organicos. |
-
2004
- 2004-03-11 ES ES200400662A patent/ES2245588B1/es not_active Expired - Fee Related
-
2005
- 2005-03-09 CN CN2005800145353A patent/CN1980863B/zh not_active Expired - Fee Related
- 2005-03-09 MX MXPA06010176A patent/MXPA06010176A/es active IP Right Grant
- 2005-03-09 NZ NZ550468A patent/NZ550468A/en unknown
- 2005-03-09 CA CA002559112A patent/CA2559112A1/en not_active Abandoned
- 2005-03-09 EA EA200601676A patent/EA200601676A1/ru unknown
- 2005-03-09 WO PCT/ES2005/000120 patent/WO2005087663A1/es active Application Filing
- 2005-03-09 AU AU2005221845A patent/AU2005221845B2/en not_active Ceased
- 2005-03-09 JP JP2007502355A patent/JP4833195B2/ja not_active Expired - Fee Related
- 2005-03-09 BR BRPI0508649-3A patent/BRPI0508649B1/pt not_active IP Right Cessation
- 2005-03-09 EP EP05717203A patent/EP1736441A1/en not_active Withdrawn
-
2006
- 2006-09-08 US US11/517,949 patent/US7553477B2/en not_active Expired - Fee Related
- 2006-10-10 NO NO20064592A patent/NO20064592L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
AU2005221845B2 (en) | 2010-08-26 |
US20070098629A1 (en) | 2007-05-03 |
EA200601676A1 (ru) | 2007-04-27 |
EP1736441A1 (en) | 2006-12-27 |
ES2245588B1 (es) | 2007-08-16 |
WO2005087663A1 (es) | 2005-09-22 |
BRPI0508649B1 (pt) | 2014-08-26 |
WO2005087663A8 (es) | 2006-10-26 |
MXPA06010176A (es) | 2007-03-07 |
NZ550468A (en) | 2010-02-26 |
CN1980863B (zh) | 2011-05-18 |
AU2005221845A1 (en) | 2005-09-22 |
NO20064592L (no) | 2006-12-06 |
JP4833195B2 (ja) | 2011-12-07 |
JP2007527843A (ja) | 2007-10-04 |
CA2559112A1 (en) | 2005-09-22 |
CN1980863A (zh) | 2007-06-13 |
ES2245588A1 (es) | 2006-01-01 |
US7553477B2 (en) | 2009-06-30 |
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Legal Events
Date | Code | Title | Description |
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B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 09/03/2005, OBSERVADAS AS CONDICOES LEGAIS. |
|
B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 11A ANUIDADE. |
|
B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2368 DE 24-05-2016 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |