BRPI0419166A - produção de biodiesel a partir da matéria-prima de sabão - Google Patents
produção de biodiesel a partir da matéria-prima de sabãoInfo
- Publication number
- BRPI0419166A BRPI0419166A BRPI0419166-8A BRPI0419166A BRPI0419166A BR PI0419166 A BRPI0419166 A BR PI0419166A BR PI0419166 A BRPI0419166 A BR PI0419166A BR PI0419166 A BRPI0419166 A BR PI0419166A
- Authority
- BR
- Brazil
- Prior art keywords
- neutralizing
- followed
- fatty acid
- raw material
- soapstock
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B13/00—Recovery of fats, fatty oils or fatty acids from waste materials
- C11B13/02—Recovery of fats, fatty oils or fatty acids from waste materials from soap stock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/74—Recovery of fats, fatty oils, fatty acids or other fatty substances, e.g. lanolin or waxes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Fats And Perfumes (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Detergent Compositions (AREA)
Abstract
PRODUçãO DE BIODIESEL A PARTIR DA MATéRIA-PRIMA DE SABãO. A presente invenção refere-se a um processo para produção de ésteres de ácido graxa diretamente de qualquer matéria-prima de sabão gerada no processo de refino de álcali que contém 10 a 60% de água, 0,1 a 2,0% de esteróis, 35 a 85% de derivados graxos incluindo glicerídeos parciais, por: neutralizar e separar os sabões com ácidos fortes até atingir pH 2-8; seguido por esterificação enzimática usando Lipase com concentração variando de l00ppm a 10% em peso, usando alcanol de C1 a C6 em uma razão em peso de 5 a 100% em relação aos componentes graxas trabalhando a temperatura de 15 a 70<198C> através de processos intermitentes ou contínuos; a mistura é agitada mecanicamente ou justa pela circulação durante três à cinco dias a temperatura de 15 a 70<198>C. O valor de ácido é medido na camada orgânica ao longo dos dias. A reação é interrompida quando o valor do ácido não decresce após 24 horas; para separar a fase de éster, a mistura seria decantada, bombeada a uma centrifuga ou sólidos são filtrados para facilitar a separação; o valor do ácido residual proveniente da esterificação enzimática incompleta é neutralizado usando solução alcalina selecionada do grupo consistindo em sódio, potássio, cálcio, alumínio, lítio ou hidróxido de amónio e seus derivados tais como aminas orgânicas; os ésteres brutos são destilados usando técnica intermitente ou destiladores instantâneos contínuos. A quantidade residual de umidade ou metanol é separada usando um desgaseificador justo antes do destilador de destilação principal. 80 a 90% de ésteres de cor clara são produzidos contínuamente. A invenção também refere-se ao uso de ésteres de ácido graxo produzidos de acordo com a invenção como biodiesel.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/BR2004/000218 WO2006050589A1 (en) | 2004-11-09 | 2004-11-09 | “biodiesel production from soapstock” |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0419166A true BRPI0419166A (pt) | 2007-12-11 |
Family
ID=34959291
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0419166-8A BRPI0419166A (pt) | 2004-11-09 | 2004-11-09 | produção de biodiesel a partir da matéria-prima de sabão |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20080118961A1 (pt) |
| EP (1) | EP1809755B1 (pt) |
| JP (1) | JP4696124B2 (pt) |
| CN (1) | CN101056985B (pt) |
| AT (1) | ATE435919T1 (pt) |
| BR (1) | BRPI0419166A (pt) |
| CA (1) | CA2586889A1 (pt) |
| DE (1) | DE602004021976D1 (pt) |
| ES (1) | ES2329686T3 (pt) |
| MX (1) | MX2007005376A (pt) |
| MY (1) | MY146386A (pt) |
| WO (1) | WO2006050589A1 (pt) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007055661A1 (en) * | 2005-11-14 | 2007-05-18 | Agency For Science, Technology And Research | Enzymatic production of biodiesels |
| EP1876222A1 (en) * | 2006-07-06 | 2008-01-09 | Cognis IP Management GmbH | Process for production of fatty acids, fatty acid esters and sterolesters from soapstock |
| ES2289943B1 (es) * | 2006-07-21 | 2008-12-16 | Universidad De Cordoba | Procedimiento de produccion de biodiesel mediante el uso de lipasa pancreatica de cerdo como biocatalizador enzimatico. |
| AU2008210273A1 (en) * | 2007-02-02 | 2008-08-07 | Dalriada Meat Pty Ltd | Biodiesel production |
| EP2189535A1 (en) | 2008-11-21 | 2010-05-26 | Centre National de la Recherche Scientifique | Use of ionic liquids for implementing a process for the preparation of biodiesel |
| JP5405193B2 (ja) * | 2009-05-15 | 2014-02-05 | 水澤化学工業株式会社 | バイオ燃料の製造方法 |
| GB2490324B (en) * | 2011-04-21 | 2014-06-11 | Desmet Ballestra Engineering S A Nv | Improved enzyme interesterification process |
| WO2013116342A2 (en) * | 2012-02-02 | 2013-08-08 | Revolution Fuels, Inc. | Mobile processing systems and methods for producing biodiesel fuel from waste oils |
| KR101599997B1 (ko) * | 2012-11-27 | 2016-03-04 | 한국생명공학연구원 | 신규한 고온 효모 피키아 길리에르몬디 y-2 및 이의 용도 |
| KR101727292B1 (ko) * | 2013-11-01 | 2017-04-14 | 고려대학교 산학협력단 | 비누분 유래 애시드 오일 및 효소를 이용한 바이오디젤의 제조 방법 |
| CN105001894A (zh) * | 2014-04-18 | 2015-10-28 | 栖霞市海怡污水处理材料厂 | 一种使生物质转化为原油的改性剂及生产方法和应用工艺 |
| BR112016027689B1 (pt) * | 2014-05-28 | 2024-01-02 | Novozymes A/S | Produção de ésteres alquílicos de ácidos graxos usando tratamento cáustico |
| US20150344797A1 (en) * | 2014-05-30 | 2015-12-03 | Blue Sun Energy, Inc. | Fatty acid reduction of feedstock and neutral and acidic alkyl ester |
| WO2021030258A1 (en) * | 2019-08-09 | 2021-02-18 | Locus Ip Company, Llc | Production of fatty acid esters using a yeast culture |
| CN115404245A (zh) * | 2021-05-27 | 2022-11-29 | 丰益(上海)生物技术研发中心有限公司 | 脂肪酸的制造方法及脂肪酸 |
| CN113717796A (zh) * | 2021-08-20 | 2021-11-30 | 南京林业大学 | 一种超声波辅助皂脚加压水解一步转化脂肪酸的方法 |
| CN113698993B (zh) * | 2021-08-23 | 2024-02-27 | 湖州联创环保科技有限公司 | 一种皂脚酸化脱磷设备及工艺 |
| EP4036197A1 (en) | 2022-01-26 | 2022-08-03 | Rigas Tehniska universitate | Method for refining of soapstock by acidulation and solvent extraction |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2045727A (en) * | 1932-02-11 | 1936-06-30 | Wm S Merrell Co | Method of purifying ricinoleic acid |
| US6632952B1 (en) * | 1984-01-18 | 2003-10-14 | Carrie Lee Mahoney | Agricultural oil processing using potassium hydroxide |
| US5156879A (en) * | 1988-10-31 | 1992-10-20 | Cargill, Incorporated | Fluidization of soapstock |
| GB9404483D0 (en) * | 1994-03-08 | 1994-04-20 | Norsk Hydro As | Refining marine oil compositions |
| US5713965A (en) * | 1996-04-12 | 1998-02-03 | The United States Of America As Represented By The Secretary Of Agriculture | Production of biodiesel, lubricants and fuel and lubricant additives |
| ES2188855T3 (es) * | 1997-07-22 | 2003-07-01 | Nestle Sa | Composicion lipida para formula infantil y procedimiento de preparacion. |
| US6281373B1 (en) * | 1998-05-19 | 2001-08-28 | Henkel Corporation | Process for the preparation of dimeric fatty acid C1-4 alkyl esters |
| US6399800B1 (en) * | 1999-09-22 | 2002-06-04 | The United States Of America As Represented By The Secretary Of Agriculture | Process for the production of fatty acid alkyl esters |
| CA2401069C (en) * | 2000-03-13 | 2010-05-04 | Feed Energy Company | Soapstock hydrolysis and acidulation by acidogenic bacteria |
| US6398707B1 (en) * | 2001-05-31 | 2002-06-04 | Wen-Teng Wu | Method of preparing lower alkyl fatty acids esters and in particular biodiesel |
| US6855838B2 (en) * | 2002-01-09 | 2005-02-15 | The United States Of America, As Represented By The Secretary Of Agriculture | Lipid rich compositions, production of lipid rich compositions, production of fatty acid alkyl esters from heterogeneous lipid mixtures |
-
2004
- 2004-11-09 JP JP2007540461A patent/JP4696124B2/ja not_active Expired - Fee Related
- 2004-11-09 EP EP04797135A patent/EP1809755B1/en not_active Not-in-force
- 2004-11-09 WO PCT/BR2004/000218 patent/WO2006050589A1/en active Application Filing
- 2004-11-09 ES ES04797135T patent/ES2329686T3/es active Active
- 2004-11-09 CA CA 2586889 patent/CA2586889A1/en not_active Abandoned
- 2004-11-09 AT AT04797135T patent/ATE435919T1/de active IP Right Revival
- 2004-11-09 MX MX2007005376A patent/MX2007005376A/es active IP Right Grant
- 2004-11-09 US US11/667,390 patent/US20080118961A1/en not_active Abandoned
- 2004-11-09 CN CN2004800443733A patent/CN101056985B/zh not_active Expired - Fee Related
- 2004-11-09 DE DE200460021976 patent/DE602004021976D1/de active Active
- 2004-11-09 BR BRPI0419166-8A patent/BRPI0419166A/pt not_active Application Discontinuation
-
2005
- 2005-11-08 MY MYPI20055224 patent/MY146386A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE602004021976D1 (de) | 2009-08-20 |
| CA2586889A1 (en) | 2006-05-18 |
| MY146386A (en) | 2012-08-15 |
| CN101056985A (zh) | 2007-10-17 |
| CN101056985B (zh) | 2012-07-04 |
| MX2007005376A (es) | 2007-07-04 |
| EP1809755B1 (en) | 2009-07-08 |
| WO2006050589A1 (en) | 2006-05-18 |
| JP2008518638A (ja) | 2008-06-05 |
| EP1809755A1 (en) | 2007-07-25 |
| US20080118961A1 (en) | 2008-05-22 |
| JP4696124B2 (ja) | 2011-06-08 |
| ES2329686T3 (es) | 2009-11-30 |
| ATE435919T1 (de) | 2009-07-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BRPI0419166A (pt) | produção de biodiesel a partir da matéria-prima de sabão | |
| Shuit et al. | Reactive extraction and in situ esterification of Jatropha curcas L. seeds for the production of biodiesel | |
| US8426622B2 (en) | Process for production of fatty acids, fatty acid esters and sterolesters from soapstock | |
| US6855838B2 (en) | Lipid rich compositions, production of lipid rich compositions, production of fatty acid alkyl esters from heterogeneous lipid mixtures | |
| Sulaiman et al. | Reactive extraction of solid coconut waste to produce biodiesel | |
| CA2767280C (en) | A process for the production of bio-naphtha from complex mixtures of natural occurring fats & oils | |
| SG140551A1 (en) | Production of biodiesel and glycerin from high free fatty acid feedstocks | |
| EP2665825B1 (en) | Production of fatty acid alkyl esters | |
| KR20060046398A (ko) | 알킬 에스테르의 제조 방법 | |
| WO2008120223A3 (en) | An integrated process for the preparation of fatty acid methyl ester (biodiesel) | |
| BRPI0809570A2 (pt) | Processo para a produção de ésteres de ácidos graxos e alcoóis alquílicos c1-c3 de um material graxo | |
| WO2008080391A3 (de) | Verfahren zur biodieselherstellung aus altölen und altfetten | |
| MY143824A (en) | Method of producing bio-fuels | |
| MY145468A (en) | Production of a refinery feedstock from soaps produced during a chemical pulping process | |
| JP7365346B2 (ja) | リパーゼ加水分解反応を用いる高度不飽和脂肪酸含有グリセリドの製造方法 | |
| MY145007A (en) | Preparation of fatty acid esters of glycerol formal and its use as biofuel | |
| MY163129A (en) | A process for autocatalytic esterification of fatty acids | |
| MY156261A (en) | Method for producing fats and oils | |
| CN113293183A (zh) | 采用碱处理进行脂肪酸烷基酯生产 | |
| Li et al. | The enhancement of rice bran oil quality through a novel moderate biorefining process | |
| Wang et al. | 1, 3-Dioleoyl-2-palmitoylglycerol-rich triacylglycerol characterization by three processing methods | |
| Liu et al. | The two-step synthesis of 1, 3-oleoyl-2-palmitoylglycerol by Candida sp. 99–125 lipase | |
| Shao et al. | Process optimisation for the production of biodiesel from rapeseed soapstock by a novel method of short path distillation | |
| WO2010115764A3 (en) | Triglycerides with high content of unsaturated fatty acids | |
| FI20030540A0 (fi) | Hydrolyysimenetelmä |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B11B | Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements |