BR9810869A - Inibição de polimerização de acrilatos usando misturas de nitróxidos - Google Patents

Inibição de polimerização de acrilatos usando misturas de nitróxidos

Info

Publication number
BR9810869A
BR9810869A BR9810869-7A BR9810869A BR9810869A BR 9810869 A BR9810869 A BR 9810869A BR 9810869 A BR9810869 A BR 9810869A BR 9810869 A BR9810869 A BR 9810869A
Authority
BR
Brazil
Prior art keywords
water
mixtures
absence
nitroxides
inhibition
Prior art date
Application number
BR9810869-7A
Other languages
English (en)
Inventor
Matthew Edward Gande
Glen Thomas Cunkle
Leslie Robert Gatechair
Stephen Daniel Pastor
Raymond Seltzer
Roland Arthur Edwin Winter
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Publication of BR9810869A publication Critical patent/BR9810869A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/32—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogenated Pyridines (AREA)

Abstract

Patente de Invenção: <B>INIBIçãO DE POLIMERIZAçãO DE ACRILATOS USANDO MISTURAS DE NITRÈXIDOS"<D>. Monómeros carboxílicos etilenicamente insaturados como ácido acrílico ou metacrílico ou seus ésteres são protegidos de polimerização prematura durante manufatura e estocagem na presença ou na ausência de água pela incorporação de um montante estabilizador eficaz de uma mistura de dois ou mais nitróxidos. Algumas dessas misturas proporcionam eficácia de estabilização sinérgica muito superior a resultados de estabilização obtidos pelo uso de cada nitróxido sozinho.
BR9810869-7A 1997-06-13 1998-06-04 Inibição de polimerização de acrilatos usando misturas de nitróxidos BR9810869A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/876,017 US5877344A (en) 1997-06-13 1997-06-13 Polymerization inhibition of acrylates using blends of nitroxides
PCT/EP1998/003342 WO1998056746A1 (en) 1997-06-13 1998-06-04 Polymerization inhibition of acrylates using blends of nitroxides

Publications (1)

Publication Number Publication Date
BR9810869A true BR9810869A (pt) 2000-12-26

Family

ID=25366806

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9810869-7A BR9810869A (pt) 1997-06-13 1998-06-04 Inibição de polimerização de acrilatos usando misturas de nitróxidos

Country Status (10)

Country Link
US (1) US5877344A (pt)
EP (1) EP0988273B1 (pt)
JP (1) JP2002510297A (pt)
KR (1) KR100530095B1 (pt)
CN (1) CN1259114A (pt)
AU (1) AU7918198A (pt)
BR (1) BR9810869A (pt)
DE (1) DE69808083T2 (pt)
TW (1) TW486488B (pt)
WO (1) WO1998056746A1 (pt)

Families Citing this family (30)

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EP0845448B1 (en) * 1996-12-02 2002-01-30 Ondeo Nalco Energy Services, L.P. Inhibiting polymerization of vinyl aromatic monomers
US5932735A (en) * 1997-06-13 1999-08-03 Ciba Specialty Chemicals Corporation Derivatives of 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers
US6037014A (en) * 1997-11-06 2000-03-14 The Edgington Co. Coating composition
WO1999024402A1 (fr) * 1997-11-12 1999-05-20 Mitsubishi Rayon Co., Ltd. Composes n-oxyle, leur procede de preparation et procede les utilisant pour inhiber la polymerisation de monomeres vinyliques
CA2337032C (en) * 1998-07-14 2008-12-02 Glen Thomas Cunkle Derivatives of 1-oxyl-4-hydroxy- or 4-amino-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers
KR100417098B1 (ko) * 1998-07-27 2004-02-05 니폰 쇼쿠바이 컴파니 리미티드 비닐 화합물의 중합 억제 방법
US6472486B2 (en) 1999-03-09 2002-10-29 Symyx Technologies, Inc. Controlled stable free radical emulsion polymerization processes
DE19923389A1 (de) * 1999-05-21 2000-08-17 Basf Ag Verfahren zum Lagern und/oder Transportieren von Reinacrylsäure
US6716948B1 (en) 1999-07-31 2004-04-06 Symyx Technologies, Inc. Controlled-architecture polymers and use thereof as separation media
US6300533B1 (en) 1999-08-16 2001-10-09 Uniroyal Chemical Company, Inc. Inhibition of polymerization of ethylenically unsaturated monomers
AU5917200A (en) * 1999-08-18 2001-03-13 Nalco/Exxon Energy Chemicals, L.P. Method of inhibiting vapor phase fouling in vinyl monomer systems
DE19939328A1 (de) * 1999-08-19 2001-02-22 Basf Ag Polymerisationsverfahren
US6989449B1 (en) * 1999-09-15 2006-01-24 Ciba Specialty Chemicals Corporation Chlorohydrin and cationic compounds having high affinity for pulp or paper
AR029410A1 (es) 1999-12-02 2003-06-25 Crompton Corp Metodo para inhibir la polimerizacion prematura de monomeros etilenicamente insaturados y composiciones de los mismos
KR100715592B1 (ko) 1999-12-02 2007-05-10 켐트라 코포레이션 불포화 모노머의 중합 억제방법
JP3863694B2 (ja) * 1999-12-24 2006-12-27 株式会社日本触媒 ビニル化合物中のｎ−オキシル化合物の安定化方法
FR2807439B1 (fr) 2000-04-07 2003-06-13 Atofina Polymeres multimodaux par polymerisation radicalaire controlee en presence d'alcoxyamines
US6447649B1 (en) 2000-07-24 2002-09-10 Ge Betz, Inc. Polymerization inhibitor for vinyl-containing materials
JP4048076B2 (ja) * 2001-07-10 2008-02-13 株式会社日本触媒 ミカエル型付加物の分解方法
US7226964B2 (en) * 2003-04-03 2007-06-05 Arkema France Composition comprising a nitroxide, a promoter and optionally a free-radical initiator
FR2868790B1 (fr) * 2004-04-08 2008-07-25 Arkema Sa Melange odorisant pour combustible gazeux inodore
JP4428144B2 (ja) * 2004-05-31 2010-03-10 三菱化学株式会社 （メタ）アクリル酸エステルの保存方法
FR2891841B1 (fr) * 2005-10-11 2007-12-28 Arkema Sa Melange odorisant pour combustible gazeux inodore
FR2902798B1 (fr) * 2006-06-26 2009-04-24 Arkema France Melange odorisant pour combustible gazeux inodore
CN102516005A (zh) * 2011-11-21 2012-06-27 上海泰顿化工有限公司 一种硝酰基化合物组合及用途
JP5752579B2 (ja) * 2011-12-09 2015-07-22 伯東株式会社 安定化された４−オキソ−２，２，６，６−テトラメチルピペリジン−１−オキシル含有組成物、ビニル化合物の重合禁止剤組成物、及びこれを用いたビニル化合物の重合禁止方法
US9388118B2 (en) 2012-10-01 2016-07-12 Basf Se Continuous process for preparing (meth)acrylates of C10-alcohol mixtures
DE102012217943A1 (de) * 2012-10-01 2014-05-15 Basf Se Kontinuierliches Verfahren zur Herstellung von (Meth)acrylaten von C10-Alkoholgemischen
CN106905188A (zh) * 2017-02-24 2017-06-30 北京誉天利化工有限公司 一种阻聚剂及其在丙烯腈生产装置中的应用
JP7228877B2 (ja) * 2018-12-05 2023-02-27 精工化学株式会社 重合性ビニル化合物の製造方法

Family Cites Families (9)

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Publication number Priority date Publication date Assignee Title
GB1127127A (en) * 1966-04-26 1968-09-11 Bp Chem Int Ltd Stabilization of acrylic acid
JPS5846496B2 (ja) * 1979-09-07 1983-10-17 大阪有機化学工業株式会社 α，β−不飽和カルボン酸エステルのポツプコ−ン重合防止法
US5171888A (en) * 1989-05-16 1992-12-15 Betz Laboratories, Inc. Methods and compositions for inhibiting (meth)acrylic acid polymerization
DE69212925T2 (de) * 1991-07-12 1997-01-16 Uniroyal Chem Co Inc Polymerisationsinhibitoren für Acrylsäure und Ester
US5221764A (en) * 1992-02-18 1993-06-22 Betz Laboratories, Inc. Methods and compositions for inhibiting acrylic acid polymerization
US5221461A (en) * 1992-06-09 1993-06-22 Betz Laboratories, Inc. Antioxidant compositions and methods using catechol compounds and organic acid compounds
US5322960A (en) * 1993-04-15 1994-06-21 Nippon Shokubai Co., Ltd. Method for inhibiting polymerization of (meth) acrylic acid and esters thereof
TW294658B (pt) * 1994-06-02 1997-01-01 Nippon Catalytic Chem Ind
US5728872A (en) * 1994-06-27 1998-03-17 Lutz Riemenschneider Stabilized acrylic acid compositions

Also Published As

Publication number Publication date
DE69808083D1 (de) 2002-10-24
AU7918198A (en) 1998-12-30
KR20010013620A (ko) 2001-02-26
JP2002510297A (ja) 2002-04-02
US5877344A (en) 1999-03-02
DE69808083T2 (de) 2003-04-30
EP0988273B1 (en) 2002-09-18
TW486488B (en) 2002-05-11
EP0988273A1 (en) 2000-03-29
WO1998056746A1 (en) 1998-12-17
CN1259114A (zh) 2000-07-05
KR100530095B1 (ko) 2005-11-22

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