BR9712553A - Processo para produzir uma composição de alquilaluminoxano solúvel em hidrocarboneto, e, composição de catalisador de polimerização - Google Patents

Processo para produzir uma composição de alquilaluminoxano solúvel em hidrocarboneto, e, composição de catalisador de polimerização

Info

Publication number
BR9712553A
BR9712553A BR9712553-9A BR9712553A BR9712553A BR 9712553 A BR9712553 A BR 9712553A BR 9712553 A BR9712553 A BR 9712553A BR 9712553 A BR9712553 A BR 9712553A
Authority
BR
Brazil
Prior art keywords
alkylaluminoxane
composition
soluble
hydrolytic
precursor
Prior art date
Application number
BR9712553-9A
Other languages
English (en)
Inventor
Jonthan S Rogers
Dennis B Malpass
Stanley W Palmaka
Gregory M Smith
Original Assignee
Akzo Nobel Nv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akzo Nobel Nv filed Critical Akzo Nobel Nv
Publication of BR9712553A publication Critical patent/BR9712553A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C07F5/068—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Toxicology (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Colloid Chemistry (AREA)

Abstract

"PROCESSO PARA PRODUZIR UMA COMPOSIçãO DE ALQUILALUMINOXANO SOLúVEL EM HIDROCARBONETO, E, COMPOSIçãO DE CATALISADOR DE POLIMERIZAçãO". Uma composição de alquilaluminoxano solúvel em hidrocarboneto, tal que metilaluminoxano, ou mesmo um metilaluminoxano modificado, pode ser preparada pela preparação de um precursor de alquilaluminoxano através de meios não-hidrolíticos, tais que, pelo tratamento de pelo menos um composto de trialquilalumínio com um composto contendo uma ligação oxigênio-carbono, adição àquele precursor de uma quantidade efetiva de um composto de organoalumínio, que evita a formação de espécies insolúveis, tal que, um composto de trialquilalumínio, em que cada grupo alquila contém dois ou mais átomos de carbono, e conversão daquele precursor modificado a um alquilaluminoxano, tal que, por termólise. Em uma modalidade distinta da invenção, de um produto de metilaluminoxano insolúvel for formado usando a técnica não-hidrolítica, ele pode ser solubilizado por tratamento com uma quantidade solubilizante de um alquilaluminoxano, preparado seja por meio hidrolítico ou não-hidrolítico, em que as porções alquila contêm dois ou mais átomos de carbono. Os produtos de aluminoxano apresentam solubilidade elevada em hidrocarbonetos alifáticos e estabilidade térmica aperfeiçoada em hidrocarbonetos aromáticos.
BR9712553-9A 1996-10-25 1997-10-09 Processo para produzir uma composição de alquilaluminoxano solúvel em hidrocarboneto, e, composição de catalisador de polimerização BR9712553A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/736,075 US5777143A (en) 1995-12-22 1996-10-25 Hydrocarbon soluble alkylaluminoxane compositions formed by use of non-hydrolytic means
PCT/EP1997/005672 WO1998018801A1 (en) 1996-10-25 1997-10-09 Hydrocarbon soluble alkylaluminoxane compositions formed by use of non-hydrolytic means

Publications (1)

Publication Number Publication Date
BR9712553A true BR9712553A (pt) 1999-10-19

Family

ID=24958414

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9712553-9A BR9712553A (pt) 1996-10-25 1997-10-09 Processo para produzir uma composição de alquilaluminoxano solúvel em hidrocarboneto, e, composição de catalisador de polimerização

Country Status (10)

Country Link
US (1) US5777143A (pt)
EP (1) EP0934322B1 (pt)
JP (1) JP4142746B2 (pt)
AT (1) ATE211477T1 (pt)
BR (1) BR9712553A (pt)
CA (1) CA2269667C (pt)
DE (1) DE69709890T2 (pt)
ES (1) ES2166985T3 (pt)
PT (1) PT934322E (pt)
WO (1) WO1998018801A1 (pt)

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US6153550A (en) * 1997-12-18 2000-11-28 Mobile Oil Corporation Olefin polymerization catalyst based on metallocene complexes and perfluorinated oligoaryl derivatives of aluminates
US6015766A (en) * 1997-12-18 2000-01-18 Mobil Oil Corporation Catalyst systems for olefin polymerization based on metallocene complexes and oligoalkylaluminates with sterically hindered alkyl groups as cocatalysts
WO2000004057A1 (en) * 1998-07-17 2000-01-27 Bp Chemicals Limited Method for preparing an activator for the polymerisation of olefins
US6046347A (en) * 1998-09-24 2000-04-04 Akzo Nobel Nv Aluminoxane synthesis employing reduced amount of trialkylaluminum compound
US7220804B1 (en) 2000-10-13 2007-05-22 Univation Technologies, Llc Method for preparing a catalyst system and its use in a polymerization process
US6518445B1 (en) * 2000-12-15 2003-02-11 Albemarle Corporation Methylaluminoxane compositions, enriched solutions of such compositions, and the preparation thereof
JP4770044B2 (ja) * 2001-03-30 2011-09-07 住友化学株式会社 オレフィン重合用触媒成分、オレフィン重合用触媒、およびオレフィン重合体の製造方法
WO2005095473A1 (en) 2004-03-12 2005-10-13 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
US7943716B2 (en) 2004-03-12 2011-05-17 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
JP2007528924A (ja) 2004-03-12 2007-10-18 バセル ポリオレフィン ジーエムビーエイチ オレフィンの重合用触媒システム
JP5611833B2 (ja) * 2008-11-11 2014-10-22 東ソー・ファインケム株式会社 固体状ポリメチルアルミノキサン組成物およびその製造方法
US20120209047A1 (en) * 2009-07-29 2012-08-16 Wright Michael E Homogeneous metallocene ziegler-natta catalysts for the oligomerization of olefins in aliphatic-hydrocarbon solvents
WO2011078923A1 (en) 2009-12-23 2011-06-30 Univation Technologies, Llc Methods for producing catalyst systems
KR101812365B1 (ko) * 2010-05-11 2017-12-26 토소 화인켐 가부시키가이샤 고체 형태 담체-폴리메틸알루미녹산 복합체, 그 제조 방법, 올레핀류의 중합 촉매 및 폴리올레핀류의 제조 방법
CA2737713C (en) * 2011-04-20 2018-10-30 Nova Chemicals Corporation Activation for oligomerization
US9340630B2 (en) 2012-03-28 2016-05-17 Tosoh Finechem Corporation Method for manufacturing a small particle diameter product of solid polymethylaluminoxane composition
US9676879B2 (en) * 2013-02-08 2017-06-13 Mitsui Chemicals, Inc. Solid polyaluminoxane composition, olefin polymerization catalyst, olefin polymer production method and solid polyaluminoxane composition production method
WO2015062977A1 (en) * 2013-10-28 2015-05-07 Akzo Nobel Chemicals International B.V. Process to prepare aluminoxanes by reaction of alkylaluminium with allylic alcohols
KR102574150B1 (ko) * 2015-11-26 2023-09-04 토소 화인켐 가부시키가이샤 Al2O3를 함유하는 고체상태 MAO 조성물 및 그 제조 방법
CN109153743B (zh) * 2016-04-05 2021-02-23 东曹精细化工株式会社 固体状pmao组合物及其制造方法
EP3676299B1 (en) 2017-08-29 2023-08-30 ExxonMobil Chemical Patents Inc. Carbon dioxide as a catalyst quench agent in solution polymerization, and products made therefrom
WO2019089145A1 (en) 2017-10-31 2019-05-09 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents
US11161922B2 (en) 2017-10-31 2021-11-02 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported MAO formation in aliphatic solvents
CN111662398A (zh) * 2020-06-19 2020-09-15 上海东化环境工程有限公司 一种改性烷基铝氧烷、制备方法及用于聚烯烃聚合反应的催化剂
WO2022015370A1 (en) 2020-07-17 2022-01-20 Dow Global Technologies Llc Hydrocarbyl-modified methylaluminoxane cocatalyst for bis-phenylphenoxy metal-ligand complexes
KR20230039700A (ko) 2020-07-17 2023-03-21 다우 글로벌 테크놀로지스 엘엘씨 구속된 기하학 전촉매를 위한 히드로카르빌-개질된 메틸알루미녹산 공촉매
CN116234834A (zh) 2020-07-17 2023-06-06 陶氏环球技术有限责任公司 双苯基苯氧基金属-配体络合物的烃基改性甲基铝氧烷助催化剂
EP4182366A1 (en) 2020-07-17 2023-05-24 Dow Global Technologies LLC Hydrocarbyl-modified methylaluminoxane cocatalysts for bis-phenylphenoxy metal-ligand complexes
CN116601160A (zh) 2020-11-23 2023-08-15 埃克森美孚化学专利公司 由原位形成的铝氧烷制备催化剂的改进方法
CN116438212A (zh) 2020-11-23 2023-07-14 埃克森美孚化学专利公司 不含甲苯的负载型甲基铝氧烷前体
EP4247825A1 (en) 2020-11-23 2023-09-27 ExxonMobil Chemical Patents Inc. Metallocene polypropylene prepared using aromatic solvent-free supports
CN116490510A (zh) 2020-11-23 2023-07-25 埃克森美孚化学专利公司 Smao和催化剂的非水解制备
MX2024008503A (es) 2022-01-13 2024-07-19 Dow Global Tech Llc Composiciones de polietileno.

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Also Published As

Publication number Publication date
EP0934322B1 (en) 2002-01-02
JP2001502714A (ja) 2001-02-27
WO1998018801A1 (en) 1998-05-07
ATE211477T1 (de) 2002-01-15
CA2269667A1 (en) 1998-05-07
CA2269667C (en) 2005-08-30
DE69709890D1 (de) 2002-02-28
PT934322E (pt) 2002-06-28
ES2166985T3 (es) 2002-05-01
US5777143A (en) 1998-07-07
DE69709890T2 (de) 2002-06-20
EP0934322A1 (en) 1999-08-11
JP4142746B2 (ja) 2008-09-03

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Legal Events

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 8A ANUIDADE.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1834 DE 01/03/2006.