ATE211477T1 - In kohlenwasserstoff lösliche alkylaluminoxanzusammensetzungen hergestellt in einem nicht-hydrolytischen verfahren - Google Patents

In kohlenwasserstoff lösliche alkylaluminoxanzusammensetzungen hergestellt in einem nicht-hydrolytischen verfahren

Info

Publication number
ATE211477T1
ATE211477T1 AT97913142T AT97913142T ATE211477T1 AT E211477 T1 ATE211477 T1 AT E211477T1 AT 97913142 T AT97913142 T AT 97913142T AT 97913142 T AT97913142 T AT 97913142T AT E211477 T1 ATE211477 T1 AT E211477T1
Authority
AT
Austria
Prior art keywords
alkylaluminoxane
hydrolytic
methylaluminoxane
precursor
compound
Prior art date
Application number
AT97913142T
Other languages
English (en)
Inventor
Dennis B Malpass
Stanley W Palmaka
Gregory M Smith
Jonathan S Rogers
Original Assignee
Akzo Nobel Nv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akzo Nobel Nv filed Critical Akzo Nobel Nv
Application granted granted Critical
Publication of ATE211477T1 publication Critical patent/ATE211477T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C07F5/068—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Toxicology (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Colloid Chemistry (AREA)
AT97913142T 1996-10-25 1997-10-09 In kohlenwasserstoff lösliche alkylaluminoxanzusammensetzungen hergestellt in einem nicht-hydrolytischen verfahren ATE211477T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/736,075 US5777143A (en) 1995-12-22 1996-10-25 Hydrocarbon soluble alkylaluminoxane compositions formed by use of non-hydrolytic means
PCT/EP1997/005672 WO1998018801A1 (en) 1996-10-25 1997-10-09 Hydrocarbon soluble alkylaluminoxane compositions formed by use of non-hydrolytic means

Publications (1)

Publication Number Publication Date
ATE211477T1 true ATE211477T1 (de) 2002-01-15

Family

ID=24958414

Family Applications (1)

Application Number Title Priority Date Filing Date
AT97913142T ATE211477T1 (de) 1996-10-25 1997-10-09 In kohlenwasserstoff lösliche alkylaluminoxanzusammensetzungen hergestellt in einem nicht-hydrolytischen verfahren

Country Status (10)

Country Link
US (1) US5777143A (de)
EP (1) EP0934322B1 (de)
JP (1) JP4142746B2 (de)
AT (1) ATE211477T1 (de)
BR (1) BR9712553A (de)
CA (1) CA2269667C (de)
DE (1) DE69709890T2 (de)
ES (1) ES2166985T3 (de)
PT (1) PT934322E (de)
WO (1) WO1998018801A1 (de)

Families Citing this family (33)

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US6153550A (en) * 1997-12-18 2000-11-28 Mobile Oil Corporation Olefin polymerization catalyst based on metallocene complexes and perfluorinated oligoaryl derivatives of aluminates
US6015766A (en) * 1997-12-18 2000-01-18 Mobil Oil Corporation Catalyst systems for olefin polymerization based on metallocene complexes and oligoalkylaluminates with sterically hindered alkyl groups as cocatalysts
AU4919499A (en) * 1998-07-17 2000-02-07 Bp Chemicals Limited Method for preparing an activator for the polymerisation of olefins
US6046347A (en) * 1998-09-24 2000-04-04 Akzo Nobel Nv Aluminoxane synthesis employing reduced amount of trialkylaluminum compound
US7220804B1 (en) * 2000-10-13 2007-05-22 Univation Technologies, Llc Method for preparing a catalyst system and its use in a polymerization process
US6518445B1 (en) * 2000-12-15 2003-02-11 Albemarle Corporation Methylaluminoxane compositions, enriched solutions of such compositions, and the preparation thereof
JP4770044B2 (ja) * 2001-03-30 2011-09-07 住友化学株式会社 オレフィン重合用触媒成分、オレフィン重合用触媒、およびオレフィン重合体の製造方法
US7943716B2 (en) 2004-03-12 2011-05-17 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
KR20070004712A (ko) * 2004-03-12 2007-01-09 바젤 폴리올레핀 게엠베하 올레핀 중합용 촉매 시스템
JP2007528925A (ja) 2004-03-12 2007-10-18 バセル ポリオレフィン ジーエムビーエイチ １−ヘキセンまたは高級α−オレフィンの重合方法
US8404880B2 (en) 2008-11-11 2013-03-26 Tosoh Finechem Corporation Solid polymethylaluminoxane composition and method for manufacturing same
US8969636B2 (en) * 2009-07-29 2015-03-03 The United States Of America As Represented By The Secretary Of The Navy Homogeneous metallocene ziegler-natta catalysts for the oligomerization of olefins in aliphatic-hydrocarbon solvents
WO2011078923A1 (en) 2009-12-23 2011-06-30 Univation Technologies, Llc Methods for producing catalyst systems
KR101812365B1 (ko) * 2010-05-11 2017-12-26 토소 화인켐 가부시키가이샤 고체 형태 담체-폴리메틸알루미녹산 복합체, 그 제조 방법, 올레핀류의 중합 촉매 및 폴리올레핀류의 제조 방법
CA2737713C (en) * 2011-04-20 2018-10-30 Nova Chemicals Corporation Activation for oligomerization
EP2862889B1 (de) 2012-03-28 2017-01-04 Tosoh Finechem Corporation Verfahren zur herstellung einer festen polymethylaluminoxanzusammensetzung mit kleinem teilchendurchmesser
KR101746744B1 (ko) 2013-02-08 2017-06-13 미쓰이 가가쿠 가부시키가이샤 고체상 폴리알루미녹세인 조성물, 올레핀 중합용 촉매, 올레핀 중합체의 제조 방법, 및 고체상 폴리알루미녹세인 조성물의 제조 방법
CN105745216B (zh) * 2013-10-28 2018-03-09 阿克苏诺贝尔化学品国际有限公司 通过使烷基铝与烯丙型醇反应而制备铝氧烷的方法
KR102574150B1 (ko) * 2015-11-26 2023-09-04 토소 화인켐 가부시키가이샤 Al2O3를 함유하는 고체상태 MAO 조성물 및 그 제조 방법
EP3441406A4 (de) * 2016-04-05 2020-01-08 Tosoh Finechem Corporation Feste pmao-zusammensetzung und verfahren zur herstellung davon
US11117983B2 (en) 2017-08-29 2021-09-14 Exxonmobil Chemical Patents Inc. Carbon dioxide as a catalyst quench agent in solution polymerization, and products made therefrom
US11161922B2 (en) 2017-10-31 2021-11-02 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported MAO formation in aliphatic solvents
US11021552B2 (en) 2017-10-31 2021-06-01 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents
CN111662398A (zh) * 2020-06-19 2020-09-15 上海东化环境工程有限公司 一种改性烷基铝氧烷、制备方法及用于聚烯烃聚合反应的催化剂
US20240010770A1 (en) 2020-07-17 2024-01-11 Dow Global Technologies Llc Hydrocarbyl-modified methylaluminoxane cocatalysts for bis-phenylphenoxy metal-ligand complexes
EP4182364A1 (de) 2020-07-17 2023-05-24 Dow Global Technologies LLC Hydrocarbylmodifizierte methylaluminoxan-cokatalysatoren für bis-phenylphenoxy-metall-ligandkomplexe
KR20230039700A (ko) 2020-07-17 2023-03-21 다우 글로벌 테크놀로지스 엘엘씨 구속된 기하학 전촉매를 위한 히드로카르빌-개질된 메틸알루미녹산 공촉매
CN116194491A (zh) 2020-07-17 2023-05-30 陶氏环球技术有限责任公司 双苯基苯氧基金属-配体络合物的烃基改性甲基铝氧烷助催化剂
EP4247825A1 (de) 2020-11-23 2023-09-27 ExxonMobil Chemical Patents Inc. Metallocen-polypropylen, das unter verwendung von aromatischen lösungsmittelfreien trägern hergestellt wurde
EP4247821A1 (de) 2020-11-23 2023-09-27 ExxonMobil Chemical Patents Inc. Nicht-hydrolytische herstellung von smac und katalysatoren
EP4247820A1 (de) 2020-11-23 2023-09-27 ExxonMobil Chemical Patents Inc. <smallcaps/>?in-situ ?verbessertes verfahren zur herstellung eines katalysators aus geformtem alumoxan
EP4247819A1 (de) 2020-11-23 2023-09-27 ExxonMobil Chemical Patents Inc. Toluolfreier, geträgerter methylalumoxanvorläufer
WO2023136825A1 (en) 2022-01-13 2023-07-20 Dow Global Technologies Llc Polyethylene compositions

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US5066631A (en) * 1990-10-16 1991-11-19 Ethyl Corporation Hydrocarbon solutions of alkylaluminoxane compounds
US5354721A (en) * 1993-06-22 1994-10-11 Phillips Petroleum Company Organo-aluminoxy product and use

Also Published As

Publication number Publication date
EP0934322B1 (de) 2002-01-02
DE69709890D1 (de) 2002-02-28
PT934322E (pt) 2002-06-28
JP2001502714A (ja) 2001-02-27
EP0934322A1 (de) 1999-08-11
US5777143A (en) 1998-07-07
CA2269667C (en) 2005-08-30
CA2269667A1 (en) 1998-05-07
BR9712553A (pt) 1999-10-19
JP4142746B2 (ja) 2008-09-03
ES2166985T3 (es) 2002-05-01
DE69709890T2 (de) 2002-06-20
WO1998018801A1 (en) 1998-05-07

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