BR9704714A - Processo para a preparação de um composto de biscilclopentadienila ligado por meio de ponte de metileno - Google Patents

Processo para a preparação de um composto de biscilclopentadienila ligado por meio de ponte de metileno

Info

Publication number
BR9704714A
BR9704714A BR9704714A BR9704714A BR9704714A BR 9704714 A BR9704714 A BR 9704714A BR 9704714 A BR9704714 A BR 9704714A BR 9704714 A BR9704714 A BR 9704714A BR 9704714 A BR9704714 A BR 9704714A
Authority
BR
Brazil
Prior art keywords
preparation
biscilclopentadienila
linked
compound
methylene bridge
Prior art date
Application number
BR9704714A
Other languages
English (en)
Inventor
Frank Kueber
Berthold Schiemenz
Michael Riedel
Original Assignee
Hoechst Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst Ag filed Critical Hoechst Ag
Publication of BR9704714A publication Critical patent/BR9704714A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/20—Polycyclic condensed hydrocarbons
    • C07C15/24—Polycyclic condensed hydrocarbons containing two rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/867—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an aldehyde or a ketone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/56—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals polycyclic condensed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49—Hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/02—Ortho- or ortho- and peri-condensed systems
    • C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
    • C07C2603/06—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
    • C07C2603/10—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings
    • C07C2603/12—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings only one five-membered ring
    • C07C2603/18—Fluorenes; Hydrogenated fluorenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
BR9704714A 1996-09-16 1997-09-15 Processo para a preparação de um composto de biscilclopentadienila ligado por meio de ponte de metileno BR9704714A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19637669A DE19637669A1 (de) 1996-09-16 1996-09-16 Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung

Publications (1)

Publication Number Publication Date
BR9704714A true BR9704714A (pt) 1999-01-12

Family

ID=7805765

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9704714A BR9704714A (pt) 1996-09-16 1997-09-15 Processo para a preparação de um composto de biscilclopentadienila ligado por meio de ponte de metileno

Country Status (9)

Country Link
US (2) US5945553A (pt)
EP (2) EP0832866B1 (pt)
JP (1) JP4116684B2 (pt)
KR (2) KR100517390B1 (pt)
CN (3) CN1100784C (pt)
AT (1) ATE211721T1 (pt)
BR (1) BR9704714A (pt)
DE (2) DE19637669A1 (pt)
ES (1) ES2170312T3 (pt)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998043931A1 (en) * 1997-03-29 1998-10-08 Montell Technology Company B.V. Process for preparing cyclopentadienyl compounds
EP0914323B1 (en) * 1997-03-29 2003-08-06 Basell Polyolefine GmbH Metallocenes and catalysts for polymerization of olefins
US6693156B1 (en) * 1998-11-18 2004-02-17 Basell Polyolefine Gmbh Methylene bridged metallocenes as olefin-polymerization-catalyst components
US6380447B1 (en) * 2000-06-09 2002-04-30 Wake Forest University Diels-alder adducts of epoxybutene and epoxybutene derivatives
US7868440B2 (en) * 2006-08-25 2011-01-11 Micron Technology, Inc. Packaged microdevices and methods for manufacturing packaged microdevices
CN114008084B (zh) * 2019-11-01 2024-04-12 株式会社Lg化学 生产茂金属负载型催化剂的方法和茂金属负载型催化剂

Family Cites Families (58)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4015059A (en) 1975-12-29 1977-03-29 Union Carbide Corporation Fused ring catalyst and ethylene polymerization process therewith
DE3443087A1 (de) 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US4794096A (en) 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
DE3808268A1 (de) 1988-03-12 1989-09-21 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
DE3808267A1 (de) 1988-03-12 1989-09-21 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
US5120867A (en) 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US5017714A (en) 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5304523A (en) 1988-07-15 1994-04-19 Fina Technology, Inc. Process and catalyst for producing crystalline polyolefins
US5158920A (en) 1988-07-15 1992-10-27 Fina Technology, Inc. Process for producing stereospecific polymers
US4892851A (en) 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5162278A (en) 1988-07-15 1992-11-10 Fina Technology, Inc. Non-bridged syndiospecific metallocene catalysts and polymerization process
DE3840772A1 (de) 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
US5218071A (en) 1988-12-26 1993-06-08 Mitsui Petrochemical Industries, Ltd. Ethylene random copolymers
JP2685264B2 (ja) 1988-12-27 1997-12-03 三井石油化学工業株式会社 α―オレフィン系ランダム共重合体の製造方法
IT8919252A0 (it) 1989-01-31 1989-01-31 Ilano Catalizzatori per la polimerizzazione di olefine.
IT1228906B (it) 1989-02-28 1991-07-09 Giampiero Cislaghi Chiusura per contenitori con sigillo di garanzia incorporato, particolarmente per vasetti di prodotti alimentari,cosmetici e simili.
DE3907964A1 (de) 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
US5441920A (en) 1989-03-21 1995-08-15 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
DE3916553A1 (de) 1989-05-20 1990-11-22 Hoechst Ag Syndio- isoblockpolymer und verfahren zu seiner herstellung
DE3916555A1 (de) * 1989-05-20 1990-11-22 Hoechst Ag Verfahren zur herstellung von ethylenpolymeren
DE3922546A1 (de) 1989-07-08 1991-01-17 Hoechst Ag Verfahren zur herstellung von cycloolefinpolymeren
US5117020A (en) 1989-10-30 1992-05-26 Fina Research, S.A. Process for the preparation of metallocenes
DE3942366A1 (de) 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen propylen-copolymers
DE59107926D1 (de) * 1990-11-12 1996-07-18 Hoechst Ag Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
US5252677A (en) 1990-11-20 1993-10-12 Mitsubishi Petrochemical Company Limited Functionalized olefin polymers
JP3048653B2 (ja) * 1991-02-07 2000-06-05 三菱化学株式会社 α‐オレフィン重合体の製造
JP3193066B2 (ja) 1991-05-02 2001-07-30 三菱化学株式会社 プロピレンランダム共重合体の製造法
US5631335A (en) 1991-05-09 1997-05-20 Phillips Petroleum Company Process of polymerizing olefins using diphenylsilyl or dimethyl tin bridged 1-methyl fluorenyl metallocenes
US5401817A (en) 1991-05-09 1995-03-28 Phillips Petroleum Company Olefin polymerization using silyl-bridged metallocenes
US5393911A (en) 1991-05-09 1995-02-28 Phillips Petroleum Company Cyclopentadiene type compounds and method for making
US5451649A (en) 1991-05-09 1995-09-19 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
US5191132A (en) 1991-05-09 1993-03-02 Phillips Petroleum Company Cyclopentadiene type compounds and method for making
US5571880A (en) 1991-05-09 1996-11-05 Phillips Petroleum Company Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process
US5627247A (en) 1991-05-09 1997-05-06 Phillips Petroleum Company Organometallic fluorenyl compounds and use thereof in olefin polymerization
US5436305A (en) * 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
US5594078A (en) 1991-07-23 1997-01-14 Phillips Petroleum Company Process for producing broad molecular weight polyolefin
US5610247A (en) 1991-07-23 1997-03-11 Phillips Petroleum Company Unbridged metallocenes of 9-substituted fluorenyl compounds and use thereof
US5668230A (en) 1991-07-23 1997-09-16 Phillips Petroleum Company Olefin polymerization
US5391789A (en) 1991-08-08 1995-02-21 Hoechst Aktiengesellschaft Bridged, chiral metallocenes, processes for their preparation and their use as catalysts
TW300901B (pt) * 1991-08-26 1997-03-21 Hoechst Ag
US5416228A (en) 1991-10-07 1995-05-16 Fina Technology, Inc. Process and catalyst for producing isotactic polyolefins
DE59206948D1 (de) * 1991-11-30 1996-09-26 Hoechst Ag Metallocene mit benzokondensierten Indenylderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
US5308817A (en) 1992-05-18 1994-05-03 Fina Technology, Inc. Metallocene catalyst component with good catalyst efficiency after aging
ATE165832T1 (de) * 1992-08-03 1998-05-15 Targor Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden
ES2128371T3 (es) * 1992-08-15 1999-05-16 Targor Gmbh Procedimiento para la obtencion de poliolefinas.
US5461127A (en) 1992-09-22 1995-10-24 Idemitsu Kosan Co., Ltd. Polymerization catalysts and process for producing polymers
US5631202A (en) 1993-09-24 1997-05-20 Montell Technology Company B.V. Stereospecific metallocene catalysts with stereolocking α-CP substituents
DE4344688A1 (de) 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4434640C1 (de) 1994-09-28 1996-02-01 Hoechst Ag Verfahren zur Herstellung verbrückter Metallocene
KR100368194B1 (ko) 1994-10-13 2003-04-03 니혼폴리올레핀 가부시키가이샤 폴리올레핀제조용촉매성분,당해촉매성분을포함하는폴리올레핀제조용촉매및당해촉매존재하의폴리올레핀의제조방법
IT1275856B1 (it) 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
DE19519884A1 (de) 1995-05-31 1996-12-05 Basf Ag Verfahren zur Herstellung von verbrückten Metallocenkomplexen
DE19523595A1 (de) * 1995-06-30 1997-01-02 Hoechst Ag Verfahren zur Herstellung einer kohlenstoffverbrückten Biscyclopentadienverbindung
IT1275777B1 (it) 1995-07-06 1997-10-17 Enichem Spa Catalizzatore metallocenico per la (co)polimerizzazione delle olefine
US5780659A (en) 1996-03-29 1998-07-14 Phillips Petroleum Company Substituted indenyl unbridged metallocenes
US5886202A (en) 1997-01-08 1999-03-23 Jung; Michael Bridged fluorenyl/indenyl metallocenes and the use thereof
EP0914323B1 (en) * 1997-03-29 2003-08-06 Basell Polyolefine GmbH Metallocenes and catalysts for polymerization of olefins

Also Published As

Publication number Publication date
CN1317470A (zh) 2001-10-17
EP1134227A3 (de) 2001-09-26
JPH10101589A (ja) 1998-04-21
CN1217950C (zh) 2005-09-07
CN1320588A (zh) 2001-11-07
KR20070087704A (ko) 2007-08-29
KR19980024646A (ko) 1998-07-06
CN1100784C (zh) 2003-02-05
KR100517390B1 (ko) 2006-01-12
ES2170312T3 (es) 2002-08-01
CN1176955A (zh) 1998-03-25
DE19637669A1 (de) 1998-03-19
US6255508B1 (en) 2001-07-03
CN1217891C (zh) 2005-09-07
ATE211721T1 (de) 2002-01-15
JP4116684B2 (ja) 2008-07-09
DE59705959D1 (de) 2002-02-14
US5945553A (en) 1999-08-31
EP0832866A2 (de) 1998-04-01
EP1134227A2 (de) 2001-09-19
EP0832866B1 (de) 2002-01-09
EP0832866A3 (de) 1998-07-08

Similar Documents

Publication Publication Date Title
KR927003650A (ko) 트리메틸알루미늄 혼합물, 실리카겔 및 메탈로센으로부터 제조된 올레핀 중합 촉매
EP0969010A3 (en) Transition metal compound and catalyst containing the same for polymerization of olefins
DE59209972D1 (de) Verfahren zur Herstellung eines Indens und Verwendung zur Herstellung eines Metallocens
FI951780A0 (fi) Menetelmä katalyyttikomponenttien valmistamiseksi
ATE199018T1 (de) Verfahren zur herstellung von äthylenpolymeren
EP0693506A3 (en) Process for the preparation of amorphous polymers of propylene
BR9403590A (pt) Processo para a preparação de compostos
BR8901866A (pt) Processo para a sintese de n-t-alquil-1,2-diacil-hildrazina
BR9302808A (pt) Processo para preparar polimeros de polissuccinimida
KR900014409A (ko) 균일한 알루미녹산 용액의 제조방법
BR9704714A (pt) Processo para a preparação de um composto de biscilclopentadienila ligado por meio de ponte de metileno
PT97796A (pt) Processo para a preparacao de piperidinas substituidas
DE69612494D1 (de) Verfahren zur herstellung und anwendung eines geträgerten metallocen-alumoxan katalysators
FR2669621B1 (fr) Procede de fabrication d'articles durcis legers a base de ciment-platre laitier renforces par fibres.
ES2106754T3 (es) Procedimiento para la preparacion de una poliolefina.
BR9805355A (pt) Processo contínuo para a preparação de polímeros.
BR8800716A (pt) Processo de preparacao de polimeros com grupamentos imidas e polimeros
BR9602932A (pt) Processo para a preparação de um composto de bisciclopentadieno ligado em ponte com carbono processo para a preparação de um metaloceno de bisciclopentadienila ligado em ponte com carbono e aplicações
RU94040253A (ru) Катализаторная система на основе металлоцена для полимеризации алкенов с 2 - 10 атомами углерода и способ получения полимеров алкена с 2 - 10 атомами углерода
BR8703039A (pt) Processo para a para-alquilacao seletiva de compostos aromaticos mono-substituidos;processo para a producao seletiva de para-xileno
BR9105424A (pt) Processo para preparacao de um composto pesticida
FR2603501B1 (fr) Procede d'obtention de fibres echangeuses d'anions a base de polymeres organiques
BR8905432A (pt) Processo de preparacao de polimeros com grupamentos imidas,a partir de diaminas impedidas
BR9004367A (pt) Catalisador de polimerizacao de olefinas,precursor de catalisador,poliolefina e processo para sua producao
DE69031690D1 (de) Thermisch stabilisierte Polyacrylonitrilpolymerfasern für die Herstellung von Kohlenstoffasern

Legal Events

Date Code Title Description
FA10 Dismissal: dismissal - article 33 of industrial property law
B11Y Definitive dismissal - extension of time limit for request of examination expired [chapter 11.1.1 patent gazette]