KR900014409A - 균일한 알루미녹산 용액의 제조방법 - Google Patents

균일한 알루미녹산 용액의 제조방법 Download PDF

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Publication number
KR900014409A
KR900014409A KR1019900003770A KR900003770A KR900014409A KR 900014409 A KR900014409 A KR 900014409A KR 1019900003770 A KR1019900003770 A KR 1019900003770A KR 900003770 A KR900003770 A KR 900003770A KR 900014409 A KR900014409 A KR 900014409A
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South Korea
Prior art keywords
organoaluminum compound
aluminoxane solution
uniform
producing
solution according
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KR1019900003770A
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English (en)
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KR950002859B1 (ko
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노리오 도모쓰
마사히꼬 구라모또
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이데미쓰 쇼스께
이데미쓰 고산 가부시끼가이샤
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Publication of KR900014409A publication Critical patent/KR900014409A/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C07F5/068—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

내용 없음

Description

균일한 알루미녹산 용액의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 유기알루미늄 화합물과 물을 반응시킨 후, 고체잔유물을 여과해내어 얻어진 알킬알루미녹산 (가)를, 방향족계 탄화수소용매 (나)의 존재하에, 유기 알루미늄 화합물(다)와 반응시키는 것을 특징으로 하는 균일한 알루미녹산 용액의 제조 방법.
  2. 제 1항에 있어서, 알킬알루미녹산 (가)가, 벤젠의 응고점 강하법으로 구한 분자량 500~4,000을 갖는 메틸알루미녹산인 균일한 알루미녹산 용액의 제조방법.
  3. 제 1항에 있어서, 알킬알루미녹산 (가)의 제조에 사용된 유기 알루미늄 화합물이 트리알킬알루미늄인 균일한 알루미녹산 용액의 제조방법.
  4. 제 1항에 있어서, 방향족계 탄화수소용매 (나)가 벤젠, 톨루엔, 에틸벤젠, 크실렌 또는 쿠멘인 균일한 알루미녹산 용액의 제조방법.
  5. 제 1항에 있어서, 유기 알루미늄 화합물 (다)가 분지 알킬기를 갖는 유기 알루미늄 화합물인 균일한 알루미녹산 용액의 제조방법.
  6. 제 1항에 있어서, 반응되는 유기 알루미늄 화합물 (다)/알킬알루미녹산 (가)의 Aℓ 몰비가 0.01/1~1/1인 균일한 알루미녹산 용액의 제조방법.
  7. 제 1항에 있어서, 반응되는 유기 알루미늄 화합물 (다)/알킬알루미녹산 (가)의 Aℓ 몰비가 0.01/1~0.4/1인 균일한 알루미녹산 용액의 제조방법.
  8. 제 1항에 있어서, 반응되는 유기 알루미늄 화합물 (다)/알킬알루미녹산 (가)의 Aℓ 몰비가 0.01/1~0.09/1인 균일한 알루미녹산 용액의 제조방법.
  9. 제 1항에 있어서, 방향족게 탄화수소용매 중의 유기 알루미늄 화합물 (다)와 알킬알루미녹산 (가)의 농도는 0.01~5몰/ℓ(Aℓ 기준)인 균일한 알루미녹산 용액의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900003770A 1989-03-23 1990-03-21 균일한 알루미녹산 용액의 제조방법 KR950002859B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP1-69305 1989-03-23
JP6930589 1989-03-23
JP89-69305 1989-03-23

Publications (2)

Publication Number Publication Date
KR900014409A true KR900014409A (ko) 1990-10-23
KR950002859B1 KR950002859B1 (ko) 1995-03-27

Family

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KR1019900003770A KR950002859B1 (ko) 1989-03-23 1990-03-21 균일한 알루미녹산 용액의 제조방법

Country Status (8)

Country Link
US (1) US5093295A (ko)
EP (1) EP0393358B1 (ko)
KR (1) KR950002859B1 (ko)
AT (1) ATE149172T1 (ko)
AU (1) AU616836B2 (ko)
CA (1) CA2012637C (ko)
DE (1) DE69029973T2 (ko)
FI (1) FI99128C (ko)

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Publication number Priority date Publication date Assignee Title
ES2020484A6 (es) * 1990-06-29 1991-08-01 Repsol Quimica Sa Procedimiento de preparacion de homopolimeros de dienos conjugados y de copolimeros de dienos conjugados con otros dienos o compuestos vinil aromaticos.
US5066631A (en) * 1990-10-16 1991-11-19 Ethyl Corporation Hydrocarbon solutions of alkylaluminoxane compounds
US5411925A (en) * 1993-02-12 1995-05-02 Phillips Petroleum Company Organo-aluminoxy product and use
US5157137A (en) * 1991-07-26 1992-10-20 Ethyl Corporation Method of making gel free alkylaluminoxane solutions
US5235081A (en) * 1992-03-18 1993-08-10 Ethyl Corporation Method of removing gel forming materials from methylaluminoxanes
US5157008A (en) * 1991-08-01 1992-10-20 Ethyl Corporation Hydrocarbon solutions of alkylaluminoxane compounds
US5329032A (en) * 1992-03-18 1994-07-12 Akzo Chemicals Inc. Polymethylaluminoxane of enhanced solution stability
US5420220A (en) * 1993-03-25 1995-05-30 Mobil Oil Corporation LLDPE films
US5412131A (en) * 1993-07-09 1995-05-02 Albemarle Corporation Teritary amino-aluminoxane halides
DE69422462T2 (de) * 1993-09-20 2000-05-31 Albemarle Corp Aluminoxanen mit einer erhöhten katalytischen Aktivität
CN1149297A (zh) * 1994-01-11 1997-05-07 埃克森化学专利公司 不含凝胶的铝氧烷溶液的应用
US5436212A (en) * 1994-04-15 1995-07-25 Phillips Petroleum Company Organoaluminoxy product, preparation, and use
US5496781A (en) * 1994-05-16 1996-03-05 Phillips Petroleum Company Metallocene catalyst systems, preparation, and use
US5565395A (en) * 1995-05-26 1996-10-15 Albemarle Corporation Aluminoxanate compositions
US5693838A (en) * 1995-11-13 1997-12-02 Albemarle Corporation Aluminoxane process and product
ES2195030T3 (es) * 1995-12-21 2003-12-01 Idemitsu Petrochemical Co Compuestos alumino-oxi de metilo y catalizadores para la preparacion de polimeros que contienen estos compuestos.
US5599964A (en) * 1996-04-19 1997-02-04 Albemarle Corporation Continuous process for preparing hydrocarbylaluminoxanes
US6034024A (en) * 1996-05-10 2000-03-07 Albemarle Corporation Heat treated alumoxanes
US5847177A (en) * 1996-10-10 1998-12-08 Albemarle Corporation Production of hydrocarbon-soluble hydrocarbylaluminoxanes
US6153551A (en) 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
EP1352913B1 (en) * 2002-04-08 2016-06-01 Tosoh Finechem Corporation Preparation of modified methylaluminoxane olefin polymerisation catalyst component

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3240383A1 (de) * 1982-11-02 1984-05-03 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von oligomeren aluminoxanen
US4552859A (en) * 1984-08-06 1985-11-12 Stauffer Chemical Company Olefin polymerization catalyst and process
US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst

Also Published As

Publication number Publication date
FI99128B (fi) 1997-06-30
CA2012637A1 (en) 1990-09-23
KR950002859B1 (ko) 1995-03-27
EP0393358B1 (en) 1997-02-26
ATE149172T1 (de) 1997-03-15
EP0393358A3 (en) 1990-12-27
US5093295A (en) 1992-03-03
DE69029973D1 (de) 1997-04-03
CA2012637C (en) 1996-04-16
DE69029973T2 (de) 1997-06-12
EP0393358A2 (en) 1990-10-24
FI99128C (fi) 1997-10-10
AU5149890A (en) 1990-09-27
FI901354A0 (fi) 1990-03-19
AU616836B2 (en) 1991-11-07

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