ES2195030T3 - Compuestos alumino-oxi de metilo y catalizadores para la preparacion de polimeros que contienen estos compuestos. - Google Patents
Compuestos alumino-oxi de metilo y catalizadores para la preparacion de polimeros que contienen estos compuestos.Info
- Publication number
- ES2195030T3 ES2195030T3 ES96942572T ES96942572T ES2195030T3 ES 2195030 T3 ES2195030 T3 ES 2195030T3 ES 96942572 T ES96942572 T ES 96942572T ES 96942572 T ES96942572 T ES 96942572T ES 2195030 T3 ES2195030 T3 ES 2195030T3
- Authority
- ES
- Spain
- Prior art keywords
- previous
- compounds
- sub
- aluminoxi
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/10—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
- C07F5/06—Aluminium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
- C07F5/068—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Abstract
UN COMPUESTO ORGANICO DE ALUMINOXI, EL CUAL MUESTRA UN ESPECTRO DE RESONANCIA MAGNETICA DE {SUP,27}AL (ESPECTRO DE RMN DE {SUP,27}AL) QUE TIENE UN COCIENTE A{SUB,1}/A{SUB,2} DE UN MAXIMO DE 0,1, EN EL QUE A{SUB,1} ES EL AREA DE UNA REGION ENGLOBADA POR UN SEGMENTO DE UNA LINEA QUE CONECTA UN PUNTO MINIMO LOCAL EXISTENTE ENTRE UNA CURVA CONTINUA "A" QUE CONTIENE UN PICO QUE APARECE A APROXIMADAMENTE 150 PPM Y UNA CURVA CONTINUA "B" QUE CONTIENE UN PICO QUE APARECE A APROXIMADAMENTE 60 PPM HASTA EL PUNTO DONDE LA CURVA ANTERIOR "B" ENTRA EN CONTACTO CON LA LINEA BASE Y TAMBIEN POR LA ANTERIOR CURVA "B" Y A{SUB,2} FORMA PARTE DE UN REGION DELIMITADA POR LAS CURVAS ANTERIORES "A" Y "B" Y TAMBIEN POR LA LINEA BASE; UN COMPUESTO ALUMINOXI ORGANICO QUE CONTIENE AL MENOS EL 5 % EXPRESADO EN TERMINOS DE ATOMOS DE ALUMINIO, DE UNA PORCION INSOLUBLE EN UNA MEZCLA DE DISOLVENTES DE TOLUENO Y HEXANO EN UNA PROPORCION DE VOLUMEN DE 2 : 5 A 30 (GRADOS) C O MENOS Y UN CATALIZADOR PARA LA PRODUCCION DE UN POLIMERO QUE CONTIENE CUALQUIERA DE LOS COMPUESTOS ALUMINOXI ORGANICOS ANTERIORES Y UN COMPUESTO DE UN METAL DE TRANSICION. EL CATALIZADOR ANTERIOR ES UN CATALIZADOR HOMOGENEO QUE TIENE UNA ACTIVIDAD ALTA Y ES ESTABLE Y QUE SE USA PARA LA POLIMERIZACION DE OLEFINAS Y ESTIRENOS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP33333895 | 1995-12-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2195030T3 true ES2195030T3 (es) | 2003-12-01 |
Family
ID=18265001
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES96942572T Expired - Lifetime ES2195030T3 (es) | 1995-12-21 | 1996-12-19 | Compuestos alumino-oxi de metilo y catalizadores para la preparacion de polimeros que contienen estos compuestos. |
Country Status (9)
Country | Link |
---|---|
US (3) | US5917073A (es) |
EP (1) | EP0811628B1 (es) |
JP (1) | JP3756192B2 (es) |
KR (1) | KR100521932B1 (es) |
CA (1) | CA2211022A1 (es) |
DE (1) | DE69626499T2 (es) |
ES (1) | ES2195030T3 (es) |
TW (1) | TW363983B (es) |
WO (1) | WO1997023488A1 (es) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997023488A1 (fr) * | 1995-12-21 | 1997-07-03 | Idemitsu Petrochemical Co., Ltd. | Composes alumino-oxy organiques et catalyseurs pour la preparation de polymeres contenant ces composes |
US20030211933A1 (en) * | 1998-02-27 | 2003-11-13 | Idemitsu Kosan Co., Ltd. | Aluminum compound, method for producing the same, catalyst for producing olefinic polymers and method for producing olefinic polymers |
IT1301681B1 (it) * | 1998-06-11 | 2000-07-07 | Siac It Additivi Carburanti | Polimeri dell'etilene con alfa-olefine. |
JP4195138B2 (ja) * | 1998-12-10 | 2008-12-10 | 出光興産株式会社 | アルミニウムオキシ化合物、オレフィン重合用触媒成分及びポリオレフィンの製造方法 |
CN1139649C (zh) * | 2000-01-07 | 2004-02-25 | 清华大学 | 一种有机电致发光材料 |
JP2002179714A (ja) * | 2000-12-12 | 2002-06-26 | Idemitsu Petrochem Co Ltd | 重合体混合物の製造方法 |
US6518445B1 (en) | 2000-12-15 | 2003-02-11 | Albemarle Corporation | Methylaluminoxane compositions, enriched solutions of such compositions, and the preparation thereof |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
JP4972284B2 (ja) | 2002-10-15 | 2012-07-11 | エクソンモービル・ケミカル・パテンツ・インク | オレフィン重合のための複数触媒系及びそれらから生成されたポリマー |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4665208A (en) * | 1985-07-11 | 1987-05-12 | Exxon Chemical Patents Inc. | Process for the preparation of alumoxanes |
JP2693538B2 (ja) * | 1988-12-26 | 1997-12-24 | 三井石油化学工業株式会社 | ベンゼン不溶性の有機アルミニウムオキシ化合物 |
JP2777252B2 (ja) * | 1989-02-16 | 1998-07-16 | 出光興産株式会社 | アルミノキサンの製造方法 |
US5093295A (en) * | 1989-03-23 | 1992-03-03 | Idemitsu Kosan Company Limited | Process for producing homogeneous aluminoxane solution |
US4968827A (en) * | 1989-06-06 | 1990-11-06 | Ethyl Corporation | Alkylaluminoxane process |
JPH0449293A (ja) * | 1990-06-19 | 1992-02-18 | Idemitsu Kosan Co Ltd | アルミノキサン溶液およびこれを用いた重合用触媒 |
JP3091241B2 (ja) * | 1991-02-21 | 2000-09-25 | 三菱化学株式会社 | 新規なメチルイソブチルアルモキサン |
JPH0730091B2 (ja) * | 1991-09-06 | 1995-04-05 | 東ソー・アクゾ株式会社 | アルミノキサン類の製造方法 |
WO1997023488A1 (fr) * | 1995-12-21 | 1997-07-03 | Idemitsu Petrochemical Co., Ltd. | Composes alumino-oxy organiques et catalyseurs pour la preparation de polymeres contenant ces composes |
-
1996
- 1996-12-19 WO PCT/JP1996/003699 patent/WO1997023488A1/ja active IP Right Grant
- 1996-12-19 KR KR1019970705810A patent/KR100521932B1/ko not_active IP Right Cessation
- 1996-12-19 DE DE69626499T patent/DE69626499T2/de not_active Expired - Lifetime
- 1996-12-19 JP JP52193497A patent/JP3756192B2/ja not_active Expired - Fee Related
- 1996-12-19 EP EP96942572A patent/EP0811628B1/en not_active Expired - Lifetime
- 1996-12-19 US US08/875,606 patent/US5917073A/en not_active Expired - Fee Related
- 1996-12-19 CA CA002211022A patent/CA2211022A1/en not_active Abandoned
- 1996-12-19 ES ES96942572T patent/ES2195030T3/es not_active Expired - Lifetime
- 1996-12-24 TW TW085116012A patent/TW363983B/zh not_active IP Right Cessation
-
1998
- 1998-12-21 US US09/216,875 patent/US6034191A/en not_active Expired - Fee Related
-
1999
- 1999-10-13 US US09/416,956 patent/US6277934B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
KR19980702411A (ko) | 1998-07-15 |
DE69626499T2 (de) | 2003-10-09 |
KR100521932B1 (ko) | 2006-03-09 |
US6277934B1 (en) | 2001-08-21 |
TW363983B (en) | 1999-07-11 |
EP0811628A4 (en) | 1999-12-15 |
DE69626499D1 (de) | 2003-04-10 |
WO1997023488A1 (fr) | 1997-07-03 |
US5917073A (en) | 1999-06-29 |
EP0811628A1 (en) | 1997-12-10 |
CA2211022A1 (en) | 1997-07-03 |
EP0811628B1 (en) | 2003-03-05 |
JP3756192B2 (ja) | 2006-03-15 |
US6034191A (en) | 2000-03-07 |
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