ES2170312T3 - Procedimiento para la obtencion de un compuesto de bisciclopentadieno puenteado con metileno. - Google Patents
Procedimiento para la obtencion de un compuesto de bisciclopentadieno puenteado con metileno.Info
- Publication number
- ES2170312T3 ES2170312T3 ES97115504T ES97115504T ES2170312T3 ES 2170312 T3 ES2170312 T3 ES 2170312T3 ES 97115504 T ES97115504 T ES 97115504T ES 97115504 T ES97115504 T ES 97115504T ES 2170312 T3 ES2170312 T3 ES 2170312T3
- Authority
- ES
- Spain
- Prior art keywords
- methylene
- bisciclopentadien
- procedure
- obtaining
- compound bridged
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/20—Polycyclic condensed hydrocarbons
- C07C15/24—Polycyclic condensed hydrocarbons containing two rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/867—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an aldehyde or a ketone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
- C07C15/56—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals polycyclic condensed
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/49—Hafnium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/04—One of the condensed rings being a six-membered aromatic ring
- C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
- C07C2603/06—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
- C07C2603/10—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings
- C07C2603/12—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings only one five-membered ring
- C07C2603/18—Fluorenes; Hydrogenated fluorenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
LA PRESENTE INVENCION TRATA DE UNA COMPOSICION DE BISCICLOPENTADIENO CON PUENTES DE METILENO DE LA FORMULA GENERAL I, EN LA QUE L, INDEPENDIENTEMENTE UNA DE OTRA, ES IGUAL O DIFERENTE A UN GRUPO CICLOPENTADIENILO, MEDIANTE REACCION DE UNA O DOS COMPOSICIONES DE CICLOPENTADIENILO LH CON FORMALDEHIDO EN FORMA DE MONOMERO, OLIGOMERO O POLIMERO O REACTIVOS QUE GENERAN FORMALDEHIDO EN PRESENCIA DE UNA BASE COMO MINIMO Y DE UN CATALIZADOR DE TRANSFERENCIA DE FASES COMO MINIMO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19637669A DE19637669A1 (de) | 1996-09-16 | 1996-09-16 | Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2170312T3 true ES2170312T3 (es) | 2002-08-01 |
Family
ID=7805765
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES97115504T Expired - Lifetime ES2170312T3 (es) | 1996-09-16 | 1997-09-08 | Procedimiento para la obtencion de un compuesto de bisciclopentadieno puenteado con metileno. |
Country Status (9)
Country | Link |
---|---|
US (2) | US5945553A (es) |
EP (2) | EP0832866B1 (es) |
JP (1) | JP4116684B2 (es) |
KR (2) | KR100517390B1 (es) |
CN (3) | CN1100784C (es) |
AT (1) | ATE211721T1 (es) |
BR (1) | BR9704714A (es) |
DE (2) | DE19637669A1 (es) |
ES (1) | ES2170312T3 (es) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0920403B1 (en) * | 1997-03-29 | 2002-01-30 | Basell Technology Company B.V. | Process for preparing cyclopentadienyl compounds |
PL330222A1 (en) * | 1997-03-29 | 1999-05-10 | Montell Technology Company Bv | Metalocenes and catalysts for use in polymerisation of olefins |
KR20010101034A (ko) * | 1998-11-18 | 2001-11-14 | 간디 지오프레이 에이치. | 올레핀 중합 촉매 성분으로서 메틸렌 가교된 메탈로센 |
US6380447B1 (en) * | 2000-06-09 | 2002-04-30 | Wake Forest University | Diels-alder adducts of epoxybutene and epoxybutene derivatives |
US7868440B2 (en) * | 2006-08-25 | 2011-01-11 | Micron Technology, Inc. | Packaged microdevices and methods for manufacturing packaged microdevices |
Family Cites Families (58)
Publication number | Priority date | Publication date | Assignee | Title |
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US4015059A (en) | 1975-12-29 | 1977-03-29 | Union Carbide Corporation | Fused ring catalyst and ethylene polymerization process therewith |
DE3443087A1 (de) | 1984-11-27 | 1986-05-28 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinen |
PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
US4794096A (en) | 1987-04-03 | 1988-12-27 | Fina Technology, Inc. | Hafnium metallocene catalyst for the polymerization of olefins |
DE3808268A1 (de) | 1988-03-12 | 1989-09-21 | Hoechst Ag | Verfahren zur herstellung eines 1-olefinpolymers |
DE3808267A1 (de) | 1988-03-12 | 1989-09-21 | Hoechst Ag | Verfahren zur herstellung von 1-olefinpolymeren |
US5017714A (en) | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
US5120867A (en) | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
US5162278A (en) | 1988-07-15 | 1992-11-10 | Fina Technology, Inc. | Non-bridged syndiospecific metallocene catalysts and polymerization process |
US5158920A (en) | 1988-07-15 | 1992-10-27 | Fina Technology, Inc. | Process for producing stereospecific polymers |
US5304523A (en) | 1988-07-15 | 1994-04-19 | Fina Technology, Inc. | Process and catalyst for producing crystalline polyolefins |
US4892851A (en) | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
DE3840772A1 (de) | 1988-12-03 | 1990-06-07 | Hoechst Ag | Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente |
US5218071A (en) | 1988-12-26 | 1993-06-08 | Mitsui Petrochemical Industries, Ltd. | Ethylene random copolymers |
JP2685264B2 (ja) | 1988-12-27 | 1997-12-03 | 三井石油化学工業株式会社 | α―オレフィン系ランダム共重合体の製造方法 |
IT8919252A0 (it) | 1989-01-31 | 1989-01-31 | Ilano | Catalizzatori per la polimerizzazione di olefine. |
IT1228906B (it) | 1989-02-28 | 1991-07-09 | Giampiero Cislaghi | Chiusura per contenitori con sigillo di garanzia incorporato, particolarmente per vasetti di prodotti alimentari,cosmetici e simili. |
DE3907964A1 (de) | 1989-03-11 | 1990-09-13 | Hoechst Ag | Verfahren zur herstellung eines syndiotaktischen polyolefins |
US5441920A (en) | 1989-03-21 | 1995-08-15 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
DE3916555A1 (de) * | 1989-05-20 | 1990-11-22 | Hoechst Ag | Verfahren zur herstellung von ethylenpolymeren |
DE3916553A1 (de) | 1989-05-20 | 1990-11-22 | Hoechst Ag | Syndio- isoblockpolymer und verfahren zu seiner herstellung |
DE3922546A1 (de) | 1989-07-08 | 1991-01-17 | Hoechst Ag | Verfahren zur herstellung von cycloolefinpolymeren |
US5117020A (en) | 1989-10-30 | 1992-05-26 | Fina Research, S.A. | Process for the preparation of metallocenes |
DE3942366A1 (de) | 1989-12-21 | 1991-06-27 | Hoechst Ag | Verfahren zur herstellung eines syndiotaktischen propylen-copolymers |
ES2090209T3 (es) * | 1990-11-12 | 1996-10-16 | Hoechst Ag | Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores. |
US5252677A (en) | 1990-11-20 | 1993-10-12 | Mitsubishi Petrochemical Company Limited | Functionalized olefin polymers |
JP3048653B2 (ja) * | 1991-02-07 | 2000-06-05 | 三菱化学株式会社 | α‐オレフィン重合体の製造 |
JP3193066B2 (ja) | 1991-05-02 | 2001-07-30 | 三菱化学株式会社 | プロピレンランダム共重合体の製造法 |
US5436305A (en) * | 1991-05-09 | 1995-07-25 | Phillips Petroleum Company | Organometallic fluorenyl compounds, preparation, and use |
US5631335A (en) | 1991-05-09 | 1997-05-20 | Phillips Petroleum Company | Process of polymerizing olefins using diphenylsilyl or dimethyl tin bridged 1-methyl fluorenyl metallocenes |
US5393911A (en) | 1991-05-09 | 1995-02-28 | Phillips Petroleum Company | Cyclopentadiene type compounds and method for making |
US5191132A (en) | 1991-05-09 | 1993-03-02 | Phillips Petroleum Company | Cyclopentadiene type compounds and method for making |
US5451649A (en) | 1991-05-09 | 1995-09-19 | Phillips Petroleum Company | Organometallic fluorenyl compounds, preparation, and use |
US5627247A (en) | 1991-05-09 | 1997-05-06 | Phillips Petroleum Company | Organometallic fluorenyl compounds and use thereof in olefin polymerization |
US5571880A (en) | 1991-05-09 | 1996-11-05 | Phillips Petroleum Company | Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process |
US5401817A (en) | 1991-05-09 | 1995-03-28 | Phillips Petroleum Company | Olefin polymerization using silyl-bridged metallocenes |
US5668230A (en) | 1991-07-23 | 1997-09-16 | Phillips Petroleum Company | Olefin polymerization |
US5610247A (en) | 1991-07-23 | 1997-03-11 | Phillips Petroleum Company | Unbridged metallocenes of 9-substituted fluorenyl compounds and use thereof |
US5594078A (en) | 1991-07-23 | 1997-01-14 | Phillips Petroleum Company | Process for producing broad molecular weight polyolefin |
US5391789A (en) | 1991-08-08 | 1995-02-21 | Hoechst Aktiengesellschaft | Bridged, chiral metallocenes, processes for their preparation and their use as catalysts |
TW300901B (es) * | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
US5416228A (en) | 1991-10-07 | 1995-05-16 | Fina Technology, Inc. | Process and catalyst for producing isotactic polyolefins |
AU651915B2 (en) * | 1991-11-30 | 1994-08-04 | Basell Polyolefine Gmbh | Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts |
US5308817A (en) | 1992-05-18 | 1994-05-03 | Fina Technology, Inc. | Metallocene catalyst component with good catalyst efficiency after aging |
EP0582194B1 (de) * | 1992-08-03 | 1998-05-06 | TARGOR GmbH | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden |
ES2128371T3 (es) * | 1992-08-15 | 1999-05-16 | Targor Gmbh | Procedimiento para la obtencion de poliolefinas. |
US5461127A (en) | 1992-09-22 | 1995-10-24 | Idemitsu Kosan Co., Ltd. | Polymerization catalysts and process for producing polymers |
US5631202A (en) | 1993-09-24 | 1997-05-20 | Montell Technology Company B.V. | Stereospecific metallocene catalysts with stereolocking α-CP substituents |
DE4344688A1 (de) | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
DE4434640C1 (de) | 1994-09-28 | 1996-02-01 | Hoechst Ag | Verfahren zur Herstellung verbrückter Metallocene |
DE69500763T2 (de) | 1994-10-13 | 1998-03-26 | Japan Polyolefins Co Ltd | Katalysatorkomponent zur Olefinpolymerisation, dieses enthaltenden Katalysator und Verfahren zur Olefinpolymerisation in Gegenwart dieses Katalysators |
IT1275856B1 (it) | 1995-03-03 | 1997-10-24 | Spherilene Srl | Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione |
DE19519884A1 (de) | 1995-05-31 | 1996-12-05 | Basf Ag | Verfahren zur Herstellung von verbrückten Metallocenkomplexen |
DE19523595A1 (de) * | 1995-06-30 | 1997-01-02 | Hoechst Ag | Verfahren zur Herstellung einer kohlenstoffverbrückten Biscyclopentadienverbindung |
IT1275777B1 (it) | 1995-07-06 | 1997-10-17 | Enichem Spa | Catalizzatore metallocenico per la (co)polimerizzazione delle olefine |
US5780659A (en) | 1996-03-29 | 1998-07-14 | Phillips Petroleum Company | Substituted indenyl unbridged metallocenes |
US5886202A (en) | 1997-01-08 | 1999-03-23 | Jung; Michael | Bridged fluorenyl/indenyl metallocenes and the use thereof |
PL330222A1 (en) * | 1997-03-29 | 1999-05-10 | Montell Technology Company Bv | Metalocenes and catalysts for use in polymerisation of olefins |
-
1996
- 1996-09-16 DE DE19637669A patent/DE19637669A1/de not_active Withdrawn
-
1997
- 1997-09-08 EP EP97115504A patent/EP0832866B1/de not_active Expired - Lifetime
- 1997-09-08 AT AT97115504T patent/ATE211721T1/de not_active IP Right Cessation
- 1997-09-08 DE DE59705959T patent/DE59705959D1/de not_active Expired - Lifetime
- 1997-09-08 EP EP01113772A patent/EP1134227A3/de not_active Ceased
- 1997-09-08 ES ES97115504T patent/ES2170312T3/es not_active Expired - Lifetime
- 1997-09-12 US US08/928,208 patent/US5945553A/en not_active Expired - Fee Related
- 1997-09-13 KR KR1019970047279A patent/KR100517390B1/ko not_active IP Right Cessation
- 1997-09-15 BR BR9704714A patent/BR9704714A/pt not_active Application Discontinuation
- 1997-09-15 CN CN97118455A patent/CN1100784C/zh not_active Expired - Lifetime
- 1997-09-16 JP JP25073797A patent/JP4116684B2/ja not_active Expired - Fee Related
-
1999
- 1999-06-23 US US09/338,057 patent/US6255508B1/en not_active Expired - Fee Related
-
2001
- 2001-03-28 CN CN011117885A patent/CN1217950C/zh not_active Expired - Fee Related
- 2001-03-28 CN CN011117877A patent/CN1217891C/zh not_active Expired - Fee Related
-
2005
- 2005-04-14 KR KR1020050030904A patent/KR20070087704A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
ATE211721T1 (de) | 2002-01-15 |
EP1134227A2 (de) | 2001-09-19 |
CN1217950C (zh) | 2005-09-07 |
KR19980024646A (ko) | 1998-07-06 |
US6255508B1 (en) | 2001-07-03 |
EP1134227A3 (de) | 2001-09-26 |
CN1176955A (zh) | 1998-03-25 |
CN1320588A (zh) | 2001-11-07 |
BR9704714A (pt) | 1999-01-12 |
EP0832866B1 (de) | 2002-01-09 |
US5945553A (en) | 1999-08-31 |
CN1317470A (zh) | 2001-10-17 |
CN1100784C (zh) | 2003-02-05 |
EP0832866A3 (de) | 1998-07-08 |
JPH10101589A (ja) | 1998-04-21 |
KR20070087704A (ko) | 2007-08-29 |
DE19637669A1 (de) | 1998-03-19 |
DE59705959D1 (de) | 2002-02-14 |
CN1217891C (zh) | 2005-09-07 |
KR100517390B1 (ko) | 2006-01-12 |
EP0832866A2 (de) | 1998-04-01 |
JP4116684B2 (ja) | 2008-07-09 |
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