BR9006840A - Compostos heterociclicos - Google Patents
Compostos heterociclicosInfo
- Publication number
- BR9006840A BR9006840A BR909006840A BR9006840A BR9006840A BR 9006840 A BR9006840 A BR 9006840A BR 909006840 A BR909006840 A BR 909006840A BR 9006840 A BR9006840 A BR 9006840A BR 9006840 A BR9006840 A BR 9006840A
- Authority
- BR
- Brazil
- Prior art keywords
- compounds
- heterocyclic compounds
- concerned
- substances
- compositions
- Prior art date
Links
- 150000002391 heterocyclic compounds Chemical class 0.000 title 1
- 241000196324 Embryophyta Species 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 239000004480 active ingredient Substances 0.000 abstract 1
- 150000002084 enol ethers Chemical class 0.000 abstract 1
- 230000002363 herbicidal effect Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
- C07D239/52—Two oxygen atoms
- C07D239/54—Two oxygen atoms as doubly bound oxygen atoms or as unsubstituted hydroxy radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/70—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings condensed with carbocyclic rings or ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/70—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings condensed with carbocyclic rings or ring systems
- C07D239/72—Quinazolines; Hydrogenated quinazolines
- C07D239/95—Quinazolines; Hydrogenated quinazolines with hetero atoms directly attached in positions 2 and 4
- C07D239/96—Two oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
- C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1896—Compounds having one or more Si-O-acyl linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH245089 | 1989-06-29 | ||
PCT/CH1990/000153 WO1991000278A1 (de) | 1989-06-29 | 1990-06-27 | Heterocyclische verbindungen |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9006840A true BR9006840A (pt) | 1991-08-06 |
Family
ID=4234106
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR909006840A BR9006840A (pt) | 1989-06-29 | 1990-06-27 | Compostos heterociclicos |
Country Status (13)
Country | Link |
---|---|
US (1) | US5183492A (pt) |
EP (1) | EP0436680B1 (pt) |
JP (1) | JP2811121B2 (pt) |
KR (1) | KR0150221B1 (pt) |
AT (1) | ATE111085T1 (pt) |
AU (1) | AU630980B2 (pt) |
BR (1) | BR9006840A (pt) |
CA (1) | CA2033990C (pt) |
DE (1) | DE59007059D1 (pt) |
DK (1) | DK0436680T3 (pt) |
ES (1) | ES2060175T3 (pt) |
HU (1) | HU219159B (pt) |
WO (1) | WO1991000278A1 (pt) |
Families Citing this family (67)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6207830B1 (en) | 1987-09-23 | 2001-03-27 | Syngenta Crop Protection, Inc. | Process for the production of 3-aryl-uracils |
US5176735A (en) * | 1990-06-28 | 1993-01-05 | Uniroyal Chemical Company, Inc. | Method of desiccating plants employing 3-carbonylphenyl uracil derivatives |
JP3089621B2 (ja) * | 1990-12-17 | 2000-09-18 | 日産化学工業株式会社 | ウラシル誘導体 |
US5169430A (en) * | 1991-08-09 | 1992-12-08 | Uniroyal Chemical Company, Inc. | Benzenesulfonamide derivatives and methods for their production |
DE4131038A1 (de) * | 1991-09-20 | 1993-04-01 | Basf Ag | Substituierte 3-phenylurazile |
US5336663A (en) * | 1991-11-13 | 1994-08-09 | Ciba-Geigy Corporation | 3-aryluracil derivatives and their use for weed control |
WO1994010155A1 (en) * | 1992-10-23 | 1994-05-11 | Ciba-Geigy Ag | 3-aryluracil derivatives and the use thereof for weed control |
BR9405209A (pt) * | 1993-04-21 | 1999-08-31 | Ciba Geigy Ag | Derivados de 3-ariluracila e seu uso como herbicidas |
US5346881A (en) * | 1993-08-13 | 1994-09-13 | Fmc Corporation | 2-(bicyclic heterocyclyl)-6-fluoroalkyluracils |
CA2179292A1 (en) * | 1993-12-20 | 1995-06-29 | Roland Andree | N-cyanoaryl nitrogen heterocycles with sulphur-containing groupings |
WO1995017096A1 (en) * | 1993-12-22 | 1995-06-29 | Fmc Corporation | Herbicidal haloalkyluracils |
CA2181583A1 (en) * | 1994-02-04 | 1995-08-10 | Georg Pissiotas | Phenylimino-thiadiazabicycloalkane derivatives, processes and intermediates for their preparation and their use as herbicides |
US6783006B1 (en) | 1994-02-24 | 2004-08-31 | Syngenta Investment Corp. | Container for chemicals |
WO1999010417A1 (fr) * | 1996-02-23 | 1999-03-04 | Toray Industries, Inc. | Film polyester pour isolation electrique |
US6159899A (en) * | 1996-03-15 | 2000-12-12 | Novartis Crop Protection, Inc. | Herbicidal composition and method of weed control |
MY117294A (en) * | 1996-03-15 | 2004-06-30 | Novartis Ag | Herbicidal composition and method of weed control |
DE19621311A1 (de) | 1996-05-28 | 1997-12-04 | Bayer Ag | Substituierte Phenyluracile |
US6586367B2 (en) * | 1996-09-05 | 2003-07-01 | Syngenta Crop Protection, Inc. | Process for the control of weeds |
DE19649094A1 (de) * | 1996-11-27 | 1998-05-28 | Bayer Ag | Phenyl-uracil-Derivate |
AU708918B2 (en) | 1997-01-28 | 1999-08-19 | Syngenta Participations Ag | Herbicidal synergistic composition and method of weed control |
CA2283672A1 (en) | 1997-03-25 | 1998-10-01 | Basf Aktiengesellschaft | Novel herbicidal hydroximic acid derivatives |
EP1030843A4 (en) | 1997-10-27 | 2002-11-06 | Isk Americas Inc | SUBSTITUTED BENZENE COMPOUNDS, METHOD FOR THE PRODUCTION THEREOF AND HERBICIDES AND LEAVING COMPOSITIONS THAT CONTAIN THEM |
BR9911587A (pt) | 1998-06-26 | 2001-03-20 | Novartis Ag | Composições herbicidas |
CN1314894A (zh) | 1998-07-09 | 2001-09-26 | 拜尔公司 | 取代的苯基尿嘧啶类化合物 |
DE19836659A1 (de) | 1998-08-13 | 2000-02-17 | Hoechst Schering Agrevo Gmbh | Herbizide Mittel für tolerante oder resistente Baumwollkulturen |
DE19836660A1 (de) | 1998-08-13 | 2000-02-17 | Hoechst Schering Agrevo Gmbh | Herbizide Mittel für tolerante oder resistente Sojakulturen |
PL215314B1 (pl) | 1998-08-13 | 2013-11-29 | Bayer Cropscience Ag | Zastosowanie kompozycji zawierajacej glifosat i pendimetaline oraz sposób zwalczania szkodliwych roslin w uprawach kukurydzy |
ES2166681B1 (es) * | 1998-12-25 | 2003-06-16 | Sumitomo Chemical Co | Compuestos de uracilo opticamente activos. |
AR023523A1 (es) | 1999-04-19 | 2002-09-04 | Syngenta Participations Ag | Tratamiento herbicida para semillas |
DE19927612A1 (de) * | 1999-06-17 | 2000-12-21 | Bayer Ag | Substituierte Phenyluracile |
DE19932813A1 (de) | 1999-07-14 | 2001-01-18 | Bayer Ag | Substituierte Phenyluracile |
DE19954312A1 (de) | 1999-11-11 | 2001-05-17 | Bayer Ag | Substituierte Phenyluracile |
US6339155B1 (en) | 1999-11-15 | 2002-01-15 | Sumitomo Chemical Company, Limited | Process for producing 3-phenyluracil compounds |
DE19958381A1 (de) * | 1999-12-03 | 2001-06-07 | Bayer Ag | Herbizide auf Basis von N-Aryl-uracilen |
PT1250047E (pt) | 2000-01-25 | 2005-08-31 | Syngenta Participations Ag | Composicao herbicida |
DE10016893A1 (de) | 2000-04-05 | 2001-10-18 | Bayer Ag | Substituierte Phenyluracile |
DE10051981A1 (de) | 2000-10-20 | 2002-05-02 | Bayer Ag | Substituierte Phenyluracile |
US6846890B2 (en) | 2001-10-10 | 2005-01-25 | Jsr Corporation | Norbornene derivative and norbornene polymer obtained therefrom through ring opening polymerization |
KR101291006B1 (ko) | 2001-10-19 | 2013-07-30 | 스미또모 가가꾸 가부시키가이샤 | 잡초 방제제 대사 단백질, 그의 유전자 및 그의 용도 |
US7767624B2 (en) * | 2002-07-23 | 2010-08-03 | Basf Aktiengesellschaft | 3-Heterocyclyl substituted benzoic acid derivatives |
US20050288188A1 (en) * | 2004-06-28 | 2005-12-29 | Helena Holding Company | Manufacture and use of a plant growth regulating compound |
CN100360509C (zh) * | 2005-04-15 | 2008-01-09 | 南开大学 | 用作除草剂的1-嘧啶酮基-4-氯-5-苯甲酸酯类化合物及其制备方法 |
US8426341B2 (en) * | 2005-05-27 | 2013-04-23 | Helena Holding Company | Herbicide formulation |
US7671254B2 (en) * | 2005-08-25 | 2010-03-02 | The Board Of Trustees Of The University Of Illinois | Herbicide resistance gene, compositions and methods |
US7842856B2 (en) | 2005-08-25 | 2010-11-30 | The Board Of Trustees Of The University Of Illinois | Herbicide resistance gene, compositions and methods |
EP2052608A1 (de) | 2007-10-24 | 2009-04-29 | Bayer CropScience AG | Herbizid-Kombination |
DE102008037631A1 (de) | 2008-08-14 | 2010-02-18 | Bayer Cropscience Ag | Herbizid-Kombination mit Dimethoxytriazinyl-substituierten Difluormethansulfonylaniliden |
CN104094944B (zh) * | 2014-06-13 | 2016-08-24 | 广东中迅农科股份有限公司 | 一种含有氟丙嘧草酯和五氟磺草胺的除草组合物 |
AU2017311447B2 (en) | 2016-08-09 | 2022-03-31 | Basf Se | Method for controlling PPO resistant weeds |
WO2019121547A1 (de) | 2017-12-19 | 2019-06-27 | Bayer Aktiengesellschaft | Substituierte thiophenyluracile sowie deren salze und ihre verwendung als herbizide wirkstoffe |
ES2911000T3 (es) | 2017-12-19 | 2022-05-17 | Syngenta Crop Protection Ag | Tiofeniluracilos sustituidos, sales de los mismos y el uso de los mismos como agentes herbicidas |
EP3728237B1 (de) | 2017-12-19 | 2022-02-09 | Syngenta Crop Protection AG | Substituierte thiophenyluracile sowie deren salze und ihre verwendung als herbizide wirkstoffe |
US20210400954A1 (en) | 2018-11-19 | 2021-12-30 | Syngenta Crop Protection Ag | Paraquat formulation |
CN110078673B (zh) * | 2019-05-31 | 2020-04-24 | 深圳大学 | 一种芳基尿嘧啶类化合物及其制备方法和农药组合物 |
JP2022542068A (ja) | 2019-07-22 | 2022-09-29 | バイエル、アクチエンゲゼルシャフト | 置換n-フェニルウラシル、その塩および除草剤としてのこれらの使用 |
AU2020318682A1 (en) | 2019-07-22 | 2022-03-03 | Bayer Aktiengesellschaft | Substituted N-phenyl-N-aminouarcils and salts thereof and use thereof as herbicidal agents |
AU2021334085A1 (en) | 2020-08-24 | 2023-03-23 | Bayer Aktiengesellschaft | Substituted N-phenyluracils and salts thereof, and use thereof as herbicidal active substances |
CN115151531B (zh) * | 2021-02-07 | 2023-09-12 | 江苏中旗科技股份有限公司 | 一种含羧酸酯片段的尿嘧啶类化合物、其制备方法、除草组合物和用途 |
EP4230620A1 (de) | 2022-02-22 | 2023-08-23 | Bayer Aktiengesellschaft | Substituierte n-amino-n´-benzoesäureuracile sowie deren salze und ihre verwendung als herbizide wirkstoffe |
WO2023161172A1 (de) | 2022-02-22 | 2023-08-31 | Bayer Aktiengesellschaft | Substituierte n-benzoesäureuracile sowie deren salze und ihre verwendung als herbizide wirkstoffe |
EP4230621A1 (de) | 2022-02-22 | 2023-08-23 | Bayer AG | Substituierte n-benzoesäureuracile sowie deren salze und ihre verwendung als herbizide wirkstoffe |
WO2023222831A1 (en) | 2022-05-20 | 2023-11-23 | Syngenta Crop Protection Ag | Herbicidal compositions |
CN117546851A (zh) * | 2022-08-04 | 2024-02-13 | 江苏中旗科技股份有限公司 | 包含羧酸酯片段的尿嘧啶类化合物的除草组合物及其应用 |
WO2024078906A1 (de) | 2022-10-10 | 2024-04-18 | Bayer Aktiengesellschaft | Substituierte n-phenyluracile sowie deren salze und ihre verwendung als herbizide wirkstoffe |
WO2024104954A1 (de) | 2022-11-16 | 2024-05-23 | Bayer Aktiengesellschaft | Substituierte cycloalkyloxyphenyluracile sowie deren salze und ihre verwendung als herbizide wirkstoffe |
WO2024104952A1 (de) | 2022-11-16 | 2024-05-23 | Bayer Aktiengesellschaft | Substituierte cyclopropyloxyphenyluracile sowie deren salze und ihre verwendung als herbizide wirkstoffe |
WO2024104956A1 (de) | 2022-11-16 | 2024-05-23 | Bayer Aktiengesellschaft | Substituierte cycloalkylsulfanylphenyluracile sowie deren salze und ihre verwendung als herbizide wirkstoffe |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1035094A (en) * | 1959-08-14 | 1966-07-06 | Du Pont | Improvements relating to herbicides and novel 3-substituted uracils |
DK106253A (pt) * | 1959-08-14 | 1900-01-01 | ||
GB968666A (en) * | 1960-08-15 | 1964-09-02 | Du Pont | Herbicidal compositions containing 3-substituted uracils |
GB1035098A (en) * | 1962-12-07 | 1966-07-06 | Du Pont | Improvements relating to herbicides |
GB1035097A (en) * | 1962-12-07 | 1966-07-06 | Du Pont | Improvements relating to herbicides |
US3291592A (en) * | 1964-04-20 | 1966-12-13 | Du Pont | Method for increasing sugar cane yield |
US3360520A (en) * | 1964-05-01 | 1967-12-26 | Du Pont | 1, 3, 5, 6-tetrasurbstituted uracils |
US3235363A (en) * | 1964-05-01 | 1966-02-15 | Du Pont | Method for the control of undesirable vegetation |
IL32113A (en) * | 1968-05-13 | 1973-10-25 | Du Pont | 1-alkoxycarbonyl uracils,their preparation and herbicidal compositions containing them |
DK167280B1 (da) * | 1985-03-20 | 1993-10-04 | Ciba Geigy Ag | 3-aryluracilderivater, fremgangsmaade til fremstilling deraf, ukrudtsbekaempelsesmidler indeholdende disse derivater samt anvendelsen af derivaterne til ukrudtsbekaempelse |
DK366887A (da) * | 1986-07-31 | 1988-05-13 | Hoffmann La Roche | Pyrimidinderivater |
EP0260621A3 (de) * | 1986-09-18 | 1989-03-15 | F. HOFFMANN-LA ROCHE & CO. Aktiengesellschaft | 3-Aryluracil-enoläther und deren Verwendung zur Unkrautbekämpfung |
US4941909A (en) * | 1987-06-19 | 1990-07-17 | Hoffmann-La Roche Inc. | Heterocyclic compounds |
US4927451A (en) * | 1988-12-30 | 1990-05-22 | Uniroyal Chemical Company, Inc. | 3-aryldihydrouracils |
US5084084A (en) * | 1989-07-14 | 1992-01-28 | Nissan Chemical Industries Ltd. | Uracil derivatives and herbicides containing the same as active ingredient |
-
1990
- 1990-06-27 DE DE59007059T patent/DE59007059D1/de not_active Expired - Fee Related
- 1990-06-27 ES ES90909122T patent/ES2060175T3/es not_active Expired - Lifetime
- 1990-06-27 HU HU806/90A patent/HU219159B/hu not_active IP Right Cessation
- 1990-06-27 CA CA002033990A patent/CA2033990C/en not_active Expired - Fee Related
- 1990-06-27 KR KR1019910700215A patent/KR0150221B1/ko not_active IP Right Cessation
- 1990-06-27 EP EP90909122A patent/EP0436680B1/de not_active Expired - Lifetime
- 1990-06-27 WO PCT/CH1990/000153 patent/WO1991000278A1/de active IP Right Grant
- 1990-06-27 AT AT90909122T patent/ATE111085T1/de not_active IP Right Cessation
- 1990-06-27 BR BR909006840A patent/BR9006840A/pt not_active IP Right Cessation
- 1990-06-27 AU AU58183/90A patent/AU630980B2/en not_active Ceased
- 1990-06-27 JP JP2508597A patent/JP2811121B2/ja not_active Expired - Fee Related
- 1990-06-27 DK DK90909122.5T patent/DK0436680T3/da active
-
1991
- 1991-02-27 US US07/656,133 patent/US5183492A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
KR0150221B1 (ko) | 1998-10-15 |
US5183492A (en) | 1993-02-02 |
KR920701172A (ko) | 1992-08-11 |
EP0436680A1 (de) | 1991-07-17 |
AU5818390A (en) | 1991-01-17 |
ATE111085T1 (de) | 1994-09-15 |
HU219159B (hu) | 2001-02-28 |
HU904806D0 (en) | 1991-10-28 |
ES2060175T3 (es) | 1994-11-16 |
JPH04502473A (ja) | 1992-05-07 |
CA2033990C (en) | 2000-12-12 |
AU630980B2 (en) | 1992-11-12 |
CA2033990A1 (en) | 1990-12-30 |
EP0436680B1 (de) | 1994-09-07 |
DK0436680T3 (da) | 1994-10-10 |
JP2811121B2 (ja) | 1998-10-15 |
WO1991000278A1 (de) | 1991-01-10 |
HUT57008A (en) | 1991-11-28 |
DE59007059D1 (de) | 1994-10-13 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FB36 | Technical and formal requirements: requirement - article 36 of industrial property law | ||
FF | Decision: intention to grant | ||
PC | Transfer | ||
FG9A | Patent or certificate of addition granted | ||
B21A | Patent or certificate of addition expired [chapter 21.1 patent gazette] |
Free format text: PATENTE EXTINTA EM 27/06/2010 |