BR112021024566A2 - Compostos para separação cromatográfica de elementos de terras raras e metais s, p, d, método de separação e uso dos mesmos - Google Patents

Compostos para separação cromatográfica de elementos de terras raras e metais s, p, d, método de separação e uso dos mesmos

Info

Publication number
BR112021024566A2
BR112021024566A2 BR112021024566A BR112021024566A BR112021024566A2 BR 112021024566 A2 BR112021024566 A2 BR 112021024566A2 BR 112021024566 A BR112021024566 A BR 112021024566A BR 112021024566 A BR112021024566 A BR 112021024566A BR 112021024566 A2 BR112021024566 A2 BR 112021024566A2
Authority
BR
Brazil
Prior art keywords
alkyl
rare earth
separation
earth elements
amino
Prior art date
Application number
BR112021024566A
Other languages
English (en)
Inventor
Miloslav Polasek
Original Assignee
Ustav Organicke Chemie A Biochemie Av Cr V V I
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ustav Organicke Chemie A Biochemie Av Cr V V I filed Critical Ustav Organicke Chemie A Biochemie Av Cr V V I
Publication of BR112021024566A2 publication Critical patent/BR112021024566A2/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B59/00—Introduction of isotopes of elements into organic compounds ; Labelled organic compounds per se
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B59/00—Introduction of isotopes of elements into organic compounds ; Labelled organic compounds per se
    • C07B59/002—Heterocyclic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B01D15/42—Selective adsorption, e.g. chromatography characterised by the development mode, e.g. by displacement or by elution
    • B01D15/424—Elution mode
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B59/00—Introduction of isotopes of elements into organic compounds ; Labelled organic compounds per se
    • C07B59/004—Acyclic, carbocyclic or heterocyclic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur, selenium or tellurium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/06—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6524—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having four or more nitrogen atoms as the only ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6558—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom containing at least two different or differently substituted hetero rings neither condensed among themselves nor condensed with a common carbocyclic ring or ring system
    • C07F9/65583—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom containing at least two different or differently substituted hetero rings neither condensed among themselves nor condensed with a common carbocyclic ring or ring system each of the hetero rings containing nitrogen as ring hetero atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/05—Isotopically modified compounds, e.g. labelled

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

compostos para separação cromatográfica de elementos de terras raras e metais s, p, d, método de separação e uso dos mesmos. a presente invenção se refere a compostos da fórmula geral (i), em que - x é selecionado a partir de um grupo que consiste em h; alquila c1 a c6; halogênio (f, cl, br ou i); y é selecionado a partir de um grupo que consiste em nitrogênio; n-óxido; z1, z2, zm, em que m é 1 ou 2, são independentemente selecionados a partir do grupo que consiste em -ch2-ch2- e -ch2-ch2-ch2-; a, am, em que m é 1 ou 2, são independentemente selecionados a partir de h; -ch2cooh; -ch2c(o)nh2; -ch2p(o)(oh)2, e - n é 1 ou 2; r1, r2, r3 são independentemente h; alquila c1 a c6; alquilóxi c1 a c6; arilóxi c6 a c10; benzilóxi; alquiltio c1 a c6; ariltio c6 a c10; f; cl; br; i; oh; sh; nh2; alquilamino c1 a c6; di(alquila c1 a c6)amino; acilamino c1 a c6; di(acila c1 a c6)amino; arilamino c6 a c10; di(arila c6 a c10)amino; cn; oh; nitro; coorn, c(o)nhrn, c(o)n(rn)2, em que rn é independentemente h ou alquila c1 a c10 ou arila c6 a c10; e/ou dois vizinhos de r1, r2, r3 juntamente com dois átomos de carbono vizinhos do ciclo aromático formam um anel de seis membros, opcionalmente substituído com um ou mais substituintes independentemente selecionados a partir do grupo que consiste em oh, sh, cf3, f, cl, br, i, alquila c1 a c6, alquilóxi c1 a c6, alquiltio c1 a c6, nh2, alquilamino c1 a c6, di(alquila c1 a c6)amino, no2, cooh, coorn, c(o)nhrn, c(o)n(rn)2, em que rn é independentemente h ou alquila c1 a c10 ou arila c6 a c10; com a condição de que quando n é 2 e todos os z1, z2, zm são -ch2-ch2-, então a não é -ch2cooh; para separação cromatográfica de elementos de terras raras e/ou metais do bloco s, p e d, assim como para o método da separação dos elementos de terras raras.
BR112021024566A 2019-06-05 2020-05-28 Compostos para separação cromatográfica de elementos de terras raras e metais s, p, d, método de separação e uso dos mesmos BR112021024566A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP19178492.5A EP3747852B1 (en) 2019-06-05 2019-06-05 Compounds for chromatographic separation of rare earth elements and s-, p-, d- metals, method of separation, and use thereof
PCT/CZ2020/050035 WO2020244686A1 (en) 2019-06-05 2020-05-28 Compounds for chromatographic separation of rare earth elements and s-, p-, d- metals, method of separation, and use thereof

Publications (1)

Publication Number Publication Date
BR112021024566A2 true BR112021024566A2 (pt) 2022-01-18

Family

ID=66770383

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112021024566A BR112021024566A2 (pt) 2019-06-05 2020-05-28 Compostos para separação cromatográfica de elementos de terras raras e metais s, p, d, método de separação e uso dos mesmos

Country Status (11)

Country Link
US (1) US20220259119A1 (pt)
EP (1) EP3747852B1 (pt)
KR (1) KR20220018551A (pt)
CN (1) CN113966318B (pt)
AU (1) AU2020287193A1 (pt)
BR (1) BR112021024566A2 (pt)
CA (1) CA3142204A1 (pt)
HK (1) HK40042003B (pt)
IL (1) IL288434A (pt)
MX (1) MX2021014796A (pt)
WO (1) WO2020244686A1 (pt)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CZ309827B6 (cs) * 2020-11-13 2023-11-15 Ústav organické chemie a biochemie AV ČR, v. v. i. Použití sloučenin na bázi cyklenu pro separaci prvků vzácných zemin a způsob této separace

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6056939A (en) * 1998-08-28 2000-05-02 Desreux; Jean F. Self-assembling heteropolymetallic chelates as imaging agents and radiopharmaceuticals
WO2012155076A2 (en) * 2011-05-11 2012-11-15 The Research Foundation Of State University Of New York Imaging contrast agents and uses thereof
WO2015051362A1 (en) * 2013-10-04 2015-04-09 Illinois Institute Of Technology Multifunctional chelators, complexes, and compositions thereof, and methods of using same
EP3492460A1 (en) * 2017-12-01 2019-06-05 Ustav Organicke Chemie A Biochemie Av Cr, V.v.i. Compounds for separation of rare earth elements, method of separation, and use thereof

Also Published As

Publication number Publication date
AU2020287193A1 (en) 2022-01-06
IL288434A (en) 2022-01-01
CN113966318A (zh) 2022-01-21
EP3747852A1 (en) 2020-12-09
CN113966318B (zh) 2024-06-18
MX2021014796A (es) 2022-03-25
JP2022536278A (ja) 2022-08-15
KR20220018551A (ko) 2022-02-15
EP3747852B1 (en) 2022-10-26
CA3142204A1 (en) 2020-12-10
HK40042003B (pt) 2023-05-19
WO2020244686A1 (en) 2020-12-10
US20220259119A1 (en) 2022-08-18

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