BR112021000789A8 - injeção de biomassa em reator de pirólise catalítica de leito fluido - Google Patents
injeção de biomassa em reator de pirólise catalítica de leito fluidoInfo
- Publication number
- BR112021000789A8 BR112021000789A8 BR112021000789A BR112021000789A BR112021000789A8 BR 112021000789 A8 BR112021000789 A8 BR 112021000789A8 BR 112021000789 A BR112021000789 A BR 112021000789A BR 112021000789 A BR112021000789 A BR 112021000789A BR 112021000789 A8 BR112021000789 A8 BR 112021000789A8
- Authority
- BR
- Brazil
- Prior art keywords
- biomass
- catalytic pyrolysis
- pyrolysis reactor
- injection
- catalyst
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
- C10B49/02—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
- C10B49/04—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated
- C10B49/08—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated in dispersed form
- C10B49/10—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated in dispersed form according to the "fluidised bed" technique
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
- B01J8/0025—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor by an ascending fluid
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
- C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
- C10B49/20—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form
- C10B49/22—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
- C10B57/06—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/463—Gasification of granular or pulverulent flues in suspension in stationary fluidised beds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
- C10J3/60—Processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/78—High-pressure apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
- B01J2208/00292—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00938—Flow distribution elements
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/15—Details of feeding means
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
- C10J2300/092—Wood, cellulose
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Processing Of Solid Wastes (AREA)
- Catalysts (AREA)
Abstract
injeção de biomassa em reator de pirólise catalítica de leito fluido. um processo aperfeiçoado é provido para pirólise catalítica de biomassa, compreendendo injetar pneumaticamente uma alimentação de biomassa através de uma linha de injeção pneumática em um meio de calor fluidizado, por exemplo, catalisador quente, com um gás carreador a uma velocidade de 5 a 40 m/s em pelo menos uma zona de mistura em comunicação com um reator de pirólise no qual ocorre pirólise catalítica, e manter uma razão de taxa de fluxo de mistura de catalisador/biomassa (c/b) de 4 a 40 a jusante do ponto de injeção de catalisador através de uma linha de injeção de catalisador na pelo menos uma zona de mistura
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201862698347P | 2018-07-16 | 2018-07-16 | |
US62/698,347 | 2018-07-16 | ||
PCT/US2019/041974 WO2020018517A1 (en) | 2018-07-16 | 2019-07-16 | Biomass injection into fluid bed catalytic pyrolysis reactor |
Publications (3)
Publication Number | Publication Date |
---|---|
BR112021000789A2 BR112021000789A2 (pt) | 2021-04-13 |
BR112021000789A8 true BR112021000789A8 (pt) | 2021-05-04 |
BR112021000789B1 BR112021000789B1 (pt) | 2023-01-17 |
Family
ID=67660792
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112021000789-0A BR112021000789B1 (pt) | 2018-07-16 | 2019-07-16 | Injeção de biomassa em reator de pirólise catalítica de leito fluido |
Country Status (11)
Country | Link |
---|---|
US (1) | US11479725B2 (pt) |
EP (1) | EP3824043B1 (pt) |
JP (1) | JP7350023B2 (pt) |
KR (1) | KR20210031911A (pt) |
CN (1) | CN112469802B (pt) |
AU (1) | AU2019306525A1 (pt) |
BR (1) | BR112021000789B1 (pt) |
CA (1) | CA3102616A1 (pt) |
ES (1) | ES2946936T3 (pt) |
MX (1) | MX2021000082A (pt) |
WO (1) | WO2020018517A1 (pt) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT524123B1 (de) * | 2021-01-19 | 2022-03-15 | Radmat Ag | Vorrichtung zum Verwerten von Prozessgas unter Umsetzung von Altstoffen und Bildung von Synthesegas |
AT525654B1 (de) * | 2022-07-26 | 2023-06-15 | Alfred Edlinger Dipl Ing | Verfahren zur Gewinnung von Methan aus heißem Prozessgas unter Umsetzung von kohlenstoffhaltigen Altstoffen |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
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US4029716A (en) | 1975-12-08 | 1977-06-14 | Mobil Oil Corporation | Selective production of para-xylene |
US4115929A (en) | 1976-10-27 | 1978-09-26 | Electric Power Research Institute, Inc. | Gas distributor for fluidizing beds |
US4108730A (en) * | 1977-03-14 | 1978-08-22 | Mobil Oil Corporation | Method for treatment of rubber and plastic wastes |
US4470931A (en) | 1978-10-24 | 1984-09-11 | The Standard Oil Company | Combination fixed-fluid bed reactor |
US5175943A (en) | 1990-05-23 | 1993-01-05 | E. I. Du Pont De Nemours And Company | Solids feed system and method for feeding fluidized beds |
US5968460A (en) * | 1996-03-28 | 1999-10-19 | E. I. Du Pont De Nemours And Company | Process for injecting particulate material into a fluidized bed reactor |
JP4660874B2 (ja) | 1999-03-11 | 2011-03-30 | 宇部興産株式会社 | 廃棄物の二段ガス化システムの運転制御方法 |
US20100162625A1 (en) | 2008-12-31 | 2010-07-01 | Innovative Energy Global Limited | Biomass fast pyrolysis system utilizing non-circulating riser reactor |
US9120980B2 (en) | 2009-05-05 | 2015-09-01 | Kior, Inc. | Catalyst/biomass mixing in transport reactor |
CA2759954A1 (en) * | 2009-05-22 | 2010-11-25 | Robert Bartek | Processing biomass with a hydrogen source |
US8523496B2 (en) | 2010-02-10 | 2013-09-03 | Kior, Inc. | Biomass feed system/process |
US8499702B2 (en) * | 2010-07-15 | 2013-08-06 | Ensyn Renewables, Inc. | Char-handling processes in a pyrolysis system |
US9017428B2 (en) * | 2010-11-16 | 2015-04-28 | Kior, Inc. | Two-stage reactor and process for conversion of solid biomass material |
US9441887B2 (en) | 2011-02-22 | 2016-09-13 | Ensyn Renewables, Inc. | Heat removal and recovery in biomass pyrolysis |
EP2699647A1 (en) | 2011-04-21 | 2014-02-26 | Shell Internationale Research Maatschappij B.V. | Process for converting a solid biomass material |
AU2013230978B2 (en) * | 2012-03-07 | 2015-12-24 | Research Triangle Institute | Catalytic biomass pyrolysis process |
US20130324772A1 (en) | 2012-06-05 | 2013-12-05 | University Of Massachusetts | Method for converting a hydrocarbonaceous material to a fluid hydrocarbon product comprising p-xylene |
US9035116B2 (en) | 2012-08-07 | 2015-05-19 | Kior, Inc. | Biomass feed system including gas assist |
US10093863B2 (en) | 2013-01-22 | 2018-10-09 | Anellotech, Inc. | Gas jet injector reactor for catalytic fast pyrolysis process |
US9428695B2 (en) | 2013-02-12 | 2016-08-30 | Saudi Basic Industries Corporation | Conversion of plastics to olefin and aromatic products with product recycle |
FR3006607B1 (fr) | 2013-06-11 | 2016-10-07 | Axens | Dispositif de distribution d'un fluide |
AU2014318759B2 (en) * | 2013-09-11 | 2018-04-26 | Research Triangle Institute | Reactive catalytic fast pyrolysis process and system |
US20150240167A1 (en) | 2014-02-25 | 2015-08-27 | Uop Llc | Green fluid catalytic cracking process |
FR3051801B1 (fr) * | 2016-05-31 | 2018-06-15 | IFP Energies Nouvelles | Procede de production de btx et d'alcools par pyrolyse catalytique de biomasse et fermentation de l'effluent gazeux de pyrolyse |
CN107597026B (zh) * | 2016-07-11 | 2019-10-25 | 中国石油化工股份有限公司 | 一种催化裂解的工艺和系统 |
EP3741828A1 (en) * | 2019-05-23 | 2020-11-25 | Vertoro B.V. | Fluid catalytic cracking process of crude lignin oil (clo) |
-
2019
- 2019-07-16 CN CN201980041510.4A patent/CN112469802B/zh active Active
- 2019-07-16 ES ES19755711T patent/ES2946936T3/es active Active
- 2019-07-16 EP EP19755711.9A patent/EP3824043B1/en active Active
- 2019-07-16 KR KR1020217001504A patent/KR20210031911A/ko not_active Application Discontinuation
- 2019-07-16 JP JP2020573179A patent/JP7350023B2/ja active Active
- 2019-07-16 CA CA3102616A patent/CA3102616A1/en active Pending
- 2019-07-16 WO PCT/US2019/041974 patent/WO2020018517A1/en unknown
- 2019-07-16 AU AU2019306525A patent/AU2019306525A1/en active Pending
- 2019-07-16 US US16/512,981 patent/US11479725B2/en active Active
- 2019-07-16 BR BR112021000789-0A patent/BR112021000789B1/pt active IP Right Grant
- 2019-07-16 MX MX2021000082A patent/MX2021000082A/es unknown
Also Published As
Publication number | Publication date |
---|---|
JP7350023B2 (ja) | 2023-09-25 |
KR20210031911A (ko) | 2021-03-23 |
CN112469802B (zh) | 2022-12-30 |
EP3824043B1 (en) | 2023-04-05 |
JP2021532206A (ja) | 2021-11-25 |
BR112021000789B1 (pt) | 2023-01-17 |
CA3102616A1 (en) | 2020-01-23 |
EP3824043A1 (en) | 2021-05-26 |
US20200017770A1 (en) | 2020-01-16 |
US11479725B2 (en) | 2022-10-25 |
CN112469802A (zh) | 2021-03-09 |
BR112021000789A2 (pt) | 2021-04-13 |
WO2020018517A1 (en) | 2020-01-23 |
ES2946936T3 (es) | 2023-07-28 |
AU2019306525A1 (en) | 2021-01-07 |
MX2021000082A (es) | 2021-03-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 16/07/2019, OBSERVADAS AS CONDICOES LEGAIS |