FR3051801B1 - Procede de production de btx et d'alcools par pyrolyse catalytique de biomasse et fermentation de l'effluent gazeux de pyrolyse - Google Patents
Procede de production de btx et d'alcools par pyrolyse catalytique de biomasse et fermentation de l'effluent gazeux de pyrolyse Download PDFInfo
- Publication number
- FR3051801B1 FR3051801B1 FR1654895A FR1654895A FR3051801B1 FR 3051801 B1 FR3051801 B1 FR 3051801B1 FR 1654895 A FR1654895 A FR 1654895A FR 1654895 A FR1654895 A FR 1654895A FR 3051801 B1 FR3051801 B1 FR 3051801B1
- Authority
- FR
- France
- Prior art keywords
- biomass
- fermentation
- alcohols
- gaseous effluent
- catalytic pyrolysis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002028 Biomass Substances 0.000 title 1
- 150000001298 alcohols Chemical class 0.000 title 1
- 238000007233 catalytic pyrolysis Methods 0.000 title 1
- 238000000855 fermentation Methods 0.000 title 1
- 230000004151 fermentation Effects 0.000 title 1
- 238000000034 method Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
- C10B57/06—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
- C10G1/086—Characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P5/00—Preparation of hydrocarbons or halogenated hydrocarbons
- C12P5/002—Preparation of hydrocarbons or halogenated hydrocarbons cyclic
- C12P5/005—Preparation of hydrocarbons or halogenated hydrocarbons cyclic aromatic
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
- C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
- C12P7/06—Ethanol, i.e. non-beverage
- C12P7/065—Ethanol, i.e. non-beverage with microorganisms other than yeasts
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
- C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
- C12P7/16—Butanols
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
- C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
- C12P7/18—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic polyhydric
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/24—Preparation of oxygen-containing organic compounds containing a carbonyl group
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/24—Preparation of oxygen-containing organic compounds containing a carbonyl group
- C12P7/26—Ketones
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
- C12P7/52—Propionic acid; Butyric acids
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
- C12P7/54—Acetic acid
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
- C12P7/56—Lactic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Zoology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Microbiology (AREA)
- Biotechnology (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1654895A FR3051801B1 (fr) | 2016-05-31 | 2016-05-31 | Procede de production de btx et d'alcools par pyrolyse catalytique de biomasse et fermentation de l'effluent gazeux de pyrolyse |
PCT/EP2017/060547 WO2017207200A1 (fr) | 2016-05-31 | 2017-05-03 | Procede de production de btx et d'alcools par pyrolyse catalytique de biomasse et fermentation de l'effluent gazeux de pyrolyse |
US16/306,086 US10570337B2 (en) | 2016-05-31 | 2017-05-03 | Process for producing BTX and alcohols by catalytic pyrolysis of biomass and fermentation of the gaseous pyrolysis effluent |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1654895 | 2016-05-31 | ||
FR1654895A FR3051801B1 (fr) | 2016-05-31 | 2016-05-31 | Procede de production de btx et d'alcools par pyrolyse catalytique de biomasse et fermentation de l'effluent gazeux de pyrolyse |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3051801A1 FR3051801A1 (fr) | 2017-12-01 |
FR3051801B1 true FR3051801B1 (fr) | 2018-06-15 |
Family
ID=56511770
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR1654895A Active FR3051801B1 (fr) | 2016-05-31 | 2016-05-31 | Procede de production de btx et d'alcools par pyrolyse catalytique de biomasse et fermentation de l'effluent gazeux de pyrolyse |
Country Status (3)
Country | Link |
---|---|
US (1) | US10570337B2 (fr) |
FR (1) | FR3051801B1 (fr) |
WO (1) | WO2017207200A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20210031911A (ko) * | 2018-07-16 | 2021-03-23 | 아넬로테크, 인코퍼레이티드 | 유동층 촉매성 열분해 반응기 내로의 바이오매스 주입 |
US11667857B2 (en) * | 2020-03-16 | 2023-06-06 | Lanzatech, Inc. | Use of fermentation tail gas in integrated gasification and gas fermentation system |
CN113528164A (zh) * | 2021-06-29 | 2021-10-22 | 清华大学 | 一种煤分质利用联产乙醇和蛋白质的系统及工艺 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9249080B2 (en) * | 2012-10-17 | 2016-02-02 | Anellotech, Inc. | Chemical intermediates by catalytic fast pyrolysis process |
JP6353457B2 (ja) * | 2012-11-12 | 2018-07-04 | ランザテク・ニュージーランド・リミテッド | ガス発酵を介するバイオマスの液化 |
US9873836B2 (en) * | 2013-05-22 | 2018-01-23 | Virent, Inc. | Process for converting biomass to aromatic hydrocarbons |
-
2016
- 2016-05-31 FR FR1654895A patent/FR3051801B1/fr active Active
-
2017
- 2017-05-03 US US16/306,086 patent/US10570337B2/en active Active
- 2017-05-03 WO PCT/EP2017/060547 patent/WO2017207200A1/fr active Application Filing
Also Published As
Publication number | Publication date |
---|---|
US20190136138A1 (en) | 2019-05-09 |
WO2017207200A1 (fr) | 2017-12-07 |
FR3051801A1 (fr) | 2017-12-01 |
US10570337B2 (en) | 2020-02-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
MX2019000007A (es) | Planta y proceso para la pirolisis de desechos plasticos mixtos. | |
HRP20190577T1 (hr) | Postupak proizvodnje polihidroksialkanoata iz prekursora dobivenih anaerobnom fermentacijom fermentabilne biomase | |
PL3165609T3 (pl) | Kaseta ekspresyjna do transformacji komórki eukariotycznej, sposób transformacji komórki eukariotycznej, organizm modyfikowany genetycznie i sposób wytwarzania biopaliw i/iub substancji biochemicznych oraz wytwarzane w ten sposób biopaliwa | |
EP3088529A4 (fr) | Procédé de production d'une solution saccharifiée utilisant une biomasse en tant que matière première, dispositif de production de solution saccharifiée, et réacteur continu | |
FR3051801B1 (fr) | Procede de production de btx et d'alcools par pyrolyse catalytique de biomasse et fermentation de l'effluent gazeux de pyrolyse | |
ZA201208223B (en) | Process including hydrogenolysis of biomass followed by dehydrogenation and aldol condensation for producing alkanes | |
IT201700067289A1 (it) | Processo e impianto combinato per la produzione di biogas da reflui organici, il recupero dei nutrienti e la pulizia del biogas prodotto | |
FR3030561B1 (fr) | Procede de transformation de biomasse lignocellulosique en molecules oxygenees et en hydrocarbures sans etape de pretraitement | |
FR3007625B1 (fr) | Procede de production de biomasse de microalgues de qualite sensorielle optimisee | |
EP3587431A4 (fr) | Procédé de préparation de lévoglucosénone par pyrolyse catalytique de biomasse | |
FR3024159B1 (fr) | Procede de production de molecules a partir de biomasse fermentescible | |
EP3476933A4 (fr) | Feuille de peau de culture tridimensionnelle, cuve de culture de cellules utilisée pour la production de celle-ci, et procédé de production de feuille de peau de culture tridimensionnelle | |
MA43226A (fr) | Procédé de fermentation de litière de volaille et production de biogaz | |
WO2016081527A3 (fr) | Procédés de manipulation de produit de carbonisation dans un procédé de pyrolyse catalytique rapide et compositions de produit de carbonisation | |
LT3262024T (lt) | Aminorūgščių gamybos būdas iš pirmtakų, gautų anaerobine fermentacija iš fermentuojamos biomasės | |
PL3464511T3 (pl) | Sposób wytwarzania btx za pomocą pirolizy katalitycznej z biomasy bez recyrkulacji związków utlenionych | |
TWI800515B (zh) | 具有待處理的製程流的徑向流的固定床或移動床反應器,包含改進的內部 | |
PH12017501088A1 (en) | Reactor for producing a product gas from a fuel | |
FI20136161A (fi) | Menetelmä biokaasun valmistamiseksi biomassasta anaerobisella hajottamisella ja vastaava reaktori | |
FR3014451B1 (fr) | Procede de production de gaz de synthese par coelectrolyse | |
FR3041336B1 (fr) | Procede et appareil de production d'un melange de monoxyde de carbone et d'hydrogene | |
EP3029136A4 (fr) | Installation pour l'obtention de biomasse par la culture d'algues et pour l'obtention de bioraffinat pour la production de biohuile et de bioproduits et procédé d'obtention correspondant | |
FR3011556B1 (fr) | Procede de purification d'un gaz de synthese brut issu d'une pyrolyse et/ou gazeification d'une charge de matiere carbonee par destruction de goudrons contenus dans le gaz | |
DE112016004355A5 (de) | Umweltfreundliche selbstständig regelbare Anlage zur kontinuierlichen Erzeugung von Pflanzenkohle mit großer Ausbeute, gleichbleibend hoher Güte aus Biomasse und Verfahren zur Erzeugung derselben | |
MY178964A (en) | Method for producing chemical substance by continuous fermentation |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PLFP | Fee payment |
Year of fee payment: 2 |
|
PLSC | Publication of the preliminary search report |
Effective date: 20171201 |
|
PLFP | Fee payment |
Year of fee payment: 3 |
|
PLFP | Fee payment |
Year of fee payment: 4 |
|
PLFP | Fee payment |
Year of fee payment: 5 |
|
PLFP | Fee payment |
Year of fee payment: 6 |
|
PLFP | Fee payment |
Year of fee payment: 7 |
|
PLFP | Fee payment |
Year of fee payment: 8 |
|
PLFP | Fee payment |
Year of fee payment: 9 |