BR112018014322A2 - componente catalisador sólido, catalisador para polimerização de olefinas, e, método para produzir um polímero de olefina - Google Patents

componente catalisador sólido, catalisador para polimerização de olefinas, e, método para produzir um polímero de olefina

Info

Publication number
BR112018014322A2
BR112018014322A2 BR112018014322A BR112018014322A BR112018014322A2 BR 112018014322 A2 BR112018014322 A2 BR 112018014322A2 BR 112018014322 A BR112018014322 A BR 112018014322A BR 112018014322 A BR112018014322 A BR 112018014322A BR 112018014322 A2 BR112018014322 A2 BR 112018014322A2
Authority
BR
Brazil
Prior art keywords
catalyst component
solid catalyst
olefin polymerization
compound
olefin
Prior art date
Application number
BR112018014322A
Other languages
English (en)
Other versions
BR112018014322B1 (pt
Inventor
Uzawa Chika
Kono Hiroyuki
Marui Shinta
Uozumi Toshiya
Original Assignee
Toho Titanium Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toho Titanium Co Ltd filed Critical Toho Titanium Co Ltd
Publication of BR112018014322A2 publication Critical patent/BR112018014322A2/pt
Publication of BR112018014322B1 publication Critical patent/BR112018014322B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/612—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety
    • C07C69/618—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety having unsaturation outside the six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
    • C07C69/708—Ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6491—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
    • C08F4/6492—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon containing aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

é provido um componente catalisador sólido para polimerização de olefinas, o qual contém um composto doador de elétrons diferente de ésteres de ftalato, em que a atividade de polimerização de olefinas do componente catalisador sólido, e as propriedades físicas primárias tais como estereorregularidade, distribuição de peso molecular, etc., dos polímeros obtidos usando o componente catalisador sólido, são as mesmas que quando ésteres de ftalato são usados como um composto doador de elétrons. o componente catalisador sólido para polimerização de olefinas é distinguido por incluir um átomo de magnésio, um átomo de titânio, um átomo de halogênio, um composto éster (a) representado pela fórmula geral (1), e um composto diéster (b) representado pela fórmula geral (2), e em que a razão representada por uma fórmula (teor (% em massa) de composto éster (a)/ teor (% em massa) de composto diéster (b)) é 0,05-50.
BR112018014322A 2016-01-14 2016-12-26 Componente catalisador sólido, catalisador para polimerização de olefinas, e, método para produzir um polímero de olefina BR112018014322B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2016005186A JP6546536B2 (ja) 2016-01-14 2016-01-14 オレフィン類重合用固体触媒成分、オレフィン類重合用触媒およびオレフィン類重合体の製造方法
PCT/JP2016/088680 WO2017122521A1 (ja) 2016-01-14 2016-12-26 オレフィン類重合用固体触媒成分、オレフィン類重合用触媒およびオレフィン類重合体の製造方法

Publications (2)

Publication Number Publication Date
BR112018014322A2 true BR112018014322A2 (pt) 2018-12-11
BR112018014322B1 BR112018014322B1 (pt) 2022-05-17

Family

ID=59311029

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018014322A BR112018014322B1 (pt) 2016-01-14 2016-12-26 Componente catalisador sólido, catalisador para polimerização de olefinas, e, método para produzir um polímero de olefina

Country Status (10)

Country Link
US (1) US11192965B2 (pt)
EP (1) EP3404046B1 (pt)
JP (1) JP6546536B2 (pt)
KR (1) KR102587481B1 (pt)
CN (1) CN108473612B (pt)
BR (1) BR112018014322B1 (pt)
ES (1) ES2820473T3 (pt)
SG (1) SG11201805860VA (pt)
TW (1) TWI711638B (pt)
WO (1) WO2017122521A1 (pt)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116063590B (zh) * 2021-10-29 2024-06-04 中国石油化工股份有限公司 一种用于烯烃聚合的含环硅氧烷催化剂组分及其制备方法和应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1209255B (it) 1980-08-13 1989-07-16 Montedison Spa Catalizzatori per la polimerizzazione di olefine.
JPH0768443B2 (ja) * 1990-03-28 1995-07-26 義治 土肥 生分解性樹脂組成物
US7244549B2 (en) * 2001-08-24 2007-07-17 Jsr Corporation Pattern forming method and bilayer film
CN101486776B (zh) * 2008-01-17 2010-12-22 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其催化剂
JP6188252B2 (ja) * 2012-03-30 2017-08-30 シラス・インコーポレイテッド 重合性組成物の活性化方法、重合系およびこれにより形成される製品
JP6137463B2 (ja) * 2013-04-01 2017-05-31 東邦チタニウム株式会社 オレフィン類重合用固体触媒成分、オレフィン類重合触媒及びこれを用いたオレフィン類重合体の製造方法
CN103554312B (zh) 2013-10-18 2016-08-17 营口市向阳催化剂有限责任公司 一种用于制备α-烯烃聚合催化剂组分的内给电子体复配物
BR112016010938B1 (pt) * 2014-01-20 2021-08-03 Toho Titanium Co., Ltd Componente de catalisador sólido para polimerização de olefinas, métodos para produzir um componente de catalisador sólido para polimerização de olefinas e um polímero de olefina, e, catalisador de polimerização de olefinas

Also Published As

Publication number Publication date
ES2820473T3 (es) 2021-04-21
KR102587481B1 (ko) 2023-10-11
KR20180100658A (ko) 2018-09-11
JP2017125129A (ja) 2017-07-20
CN108473612A (zh) 2018-08-31
SG11201805860VA (en) 2018-08-30
EP3404046A1 (en) 2018-11-21
WO2017122521A1 (ja) 2017-07-20
US11192965B2 (en) 2021-12-07
BR112018014322B1 (pt) 2022-05-17
EP3404046B1 (en) 2020-08-19
JP6546536B2 (ja) 2019-07-17
TWI711638B (zh) 2020-12-01
CN108473612B (zh) 2021-02-05
EP3404046A4 (en) 2019-10-23
US20210040247A1 (en) 2021-02-11
TW201736407A (zh) 2017-10-16

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Legal Events

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B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B350 Update of information on the portal [chapter 15.35 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 26/12/2016, OBSERVADAS AS CONDICOES LEGAIS