BR112018013479B1 - Material de revestimento multifuncional, estrutura compósita, e, método para formar uma estrutura compósita - Google Patents
Material de revestimento multifuncional, estrutura compósita, e, método para formar uma estrutura compósita Download PDFInfo
- Publication number
- BR112018013479B1 BR112018013479B1 BR112018013479-1A BR112018013479A BR112018013479B1 BR 112018013479 B1 BR112018013479 B1 BR 112018013479B1 BR 112018013479 A BR112018013479 A BR 112018013479A BR 112018013479 B1 BR112018013479 B1 BR 112018013479B1
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- Brazil
- Prior art keywords
- resin
- layer
- coating material
- multifunctional
- epoxy
- Prior art date
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- 239000000463 material Substances 0.000 title claims abstract description 72
- 239000002131 composite material Substances 0.000 title claims abstract description 63
- 238000000034 method Methods 0.000 title claims abstract description 17
- 229920005989 resin Polymers 0.000 claims abstract description 75
- 239000011347 resin Substances 0.000 claims abstract description 75
- 239000011248 coating agent Substances 0.000 claims abstract description 53
- 238000000576 coating method Methods 0.000 claims abstract description 53
- 239000000758 substrate Substances 0.000 claims abstract description 24
- 150000001875 compounds Chemical class 0.000 claims abstract description 22
- 239000003063 flame retardant Substances 0.000 claims abstract description 20
- 238000000465 moulding Methods 0.000 claims abstract description 16
- 239000011159 matrix material Substances 0.000 claims abstract description 11
- 239000010410 layer Substances 0.000 claims description 115
- 229920000647 polyepoxide Polymers 0.000 claims description 48
- 239000003822 epoxy resin Substances 0.000 claims description 47
- 229920001296 polysiloxane Polymers 0.000 claims description 32
- 239000002245 particle Substances 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 26
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 229920001971 elastomer Polymers 0.000 claims description 20
- 239000004593 Epoxy Substances 0.000 claims description 19
- -1 polydimethylsiloxane Polymers 0.000 claims description 19
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 15
- 239000004005 microsphere Substances 0.000 claims description 15
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- 238000006243 chemical reaction Methods 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 13
- 239000012783 reinforcing fiber Substances 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 12
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 11
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- 239000011574 phosphorus Substances 0.000 claims description 10
- 229910052698 phosphorus Inorganic materials 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 9
- 229920001568 phenolic resin Polymers 0.000 claims description 9
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 8
- 239000004695 Polyether sulfone Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 239000000806 elastomer Substances 0.000 claims description 8
- 239000005011 phenolic resin Substances 0.000 claims description 8
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- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 7
- 229930185605 Bisphenol Natural products 0.000 claims description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 6
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 6
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 6
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 239000011256 inorganic filler Substances 0.000 claims description 5
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 5
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
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- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 229920012266 Poly(ether sulfone) PES Polymers 0.000 claims description 3
- 229920002627 poly(phosphazenes) Polymers 0.000 claims description 3
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
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- 229910010272 inorganic material Inorganic materials 0.000 claims description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 2
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 claims description 2
- 150000002894 organic compounds Chemical class 0.000 claims description 2
- 125000004437 phosphorous atom Chemical group 0.000 claims description 2
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 claims description 2
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- 238000005728 strengthening Methods 0.000 claims description 2
- 150000004684 trihydrates Chemical class 0.000 claims description 2
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 claims description 2
- 239000011253 protective coating Substances 0.000 claims 2
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- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
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- 229910052782 aluminium Inorganic materials 0.000 description 5
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- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 239000011889 copper foil Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
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- 229920001187 thermosetting polymer Polymers 0.000 description 5
- 239000012963 UV stabilizer Substances 0.000 description 4
- 238000005253 cladding Methods 0.000 description 4
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
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- 238000004519 manufacturing process Methods 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
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- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 4
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 3
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- 239000004952 Polyamide Substances 0.000 description 3
- 229920000388 Polyphosphate Polymers 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
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- 238000004132 cross linking Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
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- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000004843 novolac epoxy resin Substances 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
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- 238000010998 test method Methods 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- JLZIIHMTTRXXIN-UHFFFAOYSA-N 2-(2-hydroxy-4-methoxybenzoyl)benzoic acid Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1C(O)=O JLZIIHMTTRXXIN-UHFFFAOYSA-N 0.000 description 2
- ZMWRRFHBXARRRT-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-methylbutan-2-yl)phenol Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(N2N=C3C=CC=CC3=N2)=C1O ZMWRRFHBXARRRT-UHFFFAOYSA-N 0.000 description 2
- ZSSVCEUEVMALRD-UHFFFAOYSA-N 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(octyloxy)phenol Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C1=NC(C=2C(=CC(C)=CC=2)C)=NC(C=2C(=CC(C)=CC=2)C)=N1 ZSSVCEUEVMALRD-UHFFFAOYSA-N 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 2
- ODJUOZPKKHIEOZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3,5-dimethylphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=C(C)C=2)=C1 ODJUOZPKKHIEOZ-UHFFFAOYSA-N 0.000 description 2
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- 239000004322 Butylated hydroxytoluene Substances 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
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- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
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- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 2
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- BSYJHYLAMMJNRC-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-ol Chemical compound CC(C)(C)CC(C)(C)O BSYJHYLAMMJNRC-UHFFFAOYSA-N 0.000 description 1
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- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- LIAWCKFOFPPVGF-UHFFFAOYSA-N 2-ethyladamantane Chemical compound C1C(C2)CC3CC1C(CC)C2C3 LIAWCKFOFPPVGF-UHFFFAOYSA-N 0.000 description 1
- YEXOWHQZWLCHHD-UHFFFAOYSA-N 3,5-ditert-butyl-4-hydroxybenzoic acid Chemical compound CC(C)(C)C1=CC(C(O)=O)=CC(C(C)(C)C)=C1O YEXOWHQZWLCHHD-UHFFFAOYSA-N 0.000 description 1
- WPMYUUITDBHVQZ-UHFFFAOYSA-M 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=CC(CCC([O-])=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-M 0.000 description 1
- LJGHYPLBDBRCRZ-UHFFFAOYSA-N 3-(3-aminophenyl)sulfonylaniline Chemical compound NC1=CC=CC(S(=O)(=O)C=2C=C(N)C=CC=2)=C1 LJGHYPLBDBRCRZ-UHFFFAOYSA-N 0.000 description 1
- ZRYCRPNCXLQHPN-UHFFFAOYSA-N 3-hydroxy-2-methylbenzaldehyde Chemical compound CC1=C(O)C=CC=C1C=O ZRYCRPNCXLQHPN-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
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| FR3061145B1 (fr) * | 2016-12-27 | 2021-12-17 | Zodiac Aerosafety Systems | Dispositif de degivrage de type pneumatique pour briser et retirer un depot de glace accumulee sur la surface exterieure d'un aeronef |
| GB2568727B (en) * | 2017-11-24 | 2020-06-24 | Gurit Uk Ltd | Fire-retardant composite materials |
| KR102281565B1 (ko) * | 2018-03-13 | 2021-07-26 | 스미또모 덴꼬 쇼오께쯔 고오낑 가부시끼가이샤 | 사이징 장치 |
| WO2020197561A1 (en) * | 2019-03-28 | 2020-10-01 | Safran Cabin Inc. | Fire retardant epoxy resin |
| WO2020205488A1 (en) * | 2019-03-29 | 2020-10-08 | Cytec Industries Inc. | Permeable materials capable of lightning strike protection and use thereof in resin infusion processing |
| IT201900016847A1 (it) * | 2019-09-20 | 2021-03-20 | Londonart Srl | Guaina decorativa per pareti di ambienti umidi e/o soggetti ad acqua battente e relativo procedimento di applicazione |
| EP4045575A4 (en) * | 2019-10-18 | 2023-11-08 | Toray Industries, Inc. | FLAME-RESISTANT EXPOXY RESIN COMPOSITION |
| WO2021074685A1 (en) * | 2019-10-18 | 2021-04-22 | Toray Industries, Inc. | Flame retardant composition, prepreg, and fiber reinforced composite material |
| US12275227B2 (en) | 2020-02-11 | 2025-04-15 | Helicoid Industries, Inc. | Composite materials and structures |
| US11376812B2 (en) | 2020-02-11 | 2022-07-05 | Helicoid Industries Inc. | Shock and impact resistant structures |
| EP3926024A1 (de) | 2020-06-17 | 2021-12-22 | Clariant International Ltd | Phosphorhaltige flammschutzmittelmischungen, ein verfahren zu ihrer herstellung und ihre verwendung sowie epoxidharzformulierungen, die diese flammschutzmittelmischungen enthalten |
| KR102391715B1 (ko) * | 2020-08-27 | 2022-05-02 | 경상국립대학교산학협력단 | 낙뢰 보호 기능 및 전자기파 흡수 기능을 구비하는 항공기용 날개 |
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| US11346499B1 (en) | 2021-06-01 | 2022-05-31 | Helicoid Industries Inc. | Containers and methods for protecting pressure vessels |
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| US20030236318A1 (en) * | 2002-04-18 | 2003-12-25 | Kuraray Co., Ltd. | Curable resin composition, method for manufacture of laminate using the composition, transfer material, method for manufacture thereof and transferred product |
| DE10300462A1 (de) * | 2003-01-07 | 2004-07-15 | Bakelite Ag | Phosphormodifiziertes Epoxidharz |
| JP4270926B2 (ja) | 2003-04-07 | 2009-06-03 | 三菱レイヨン株式会社 | エポキシ樹脂組成物及びプリプレグ |
| EP1673218B1 (en) | 2003-09-30 | 2013-06-19 | The Boeing Company | Protective applique coating and use thereof |
| CN103992464B (zh) | 2004-02-27 | 2017-07-21 | 东丽株式会社 | 碳纤维增强复合材料用环氧树脂组合物、预浸料坯及纤维增强复合材料板 |
| EP1616924A1 (en) * | 2004-07-13 | 2006-01-18 | Huntsman Advanced Materials (Switzerland) GmbH | Fire retardant composition |
| DE602005017509D1 (de) * | 2004-11-26 | 2009-12-17 | Lg Chemical Ltd | Nicht-halogene flammenhemmende epoxidharzzusammensetzung und prepreg sowie kupferkaschiertes laminat damit |
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| JP2009535530A (ja) * | 2006-05-02 | 2009-10-01 | ロール インコーポレイテッド | ナノ補強材を用いた複合材料中に用いられる補強繊維トウの修飾 |
| US8206823B2 (en) * | 2008-04-14 | 2012-06-26 | The Boeing Company | System and method for fabrication of integrated lightning strike protection material |
| RU2402862C2 (ru) | 2008-09-30 | 2010-10-27 | Игорь Владиславович Захаров | Преобразователь переменного сигнала |
| WO2010109957A1 (ja) | 2009-03-25 | 2010-09-30 | 東レ株式会社 | エポキシ樹脂組成物、プリプレグ、炭素繊維強化複合材料および電子電気部品筐体 |
| JP5659806B2 (ja) | 2011-01-14 | 2015-01-28 | 三菱レイヨン株式会社 | エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料 |
| EP2705090A1 (en) | 2011-05-02 | 2014-03-12 | Dow Global Technologies LLC | Trimethyl borate in epoxy resins |
| IN2014CN04162A (enExample) * | 2011-12-09 | 2015-07-17 | Cytec Tech Corp | |
| MY176165A (en) | 2012-12-05 | 2020-07-24 | Cytec Ind Inc | Conductive surfacing material for composite structures |
| GB2510835A (en) | 2013-02-13 | 2014-08-20 | Hexcel Composites Ltd | Fire retardant epoxy resin formulations and their use |
-
2016
- 2016-12-29 BR BR112018013479-1A patent/BR112018013479B1/pt active IP Right Grant
- 2016-12-29 CA CA3010201A patent/CA3010201A1/en not_active Abandoned
- 2016-12-29 AU AU2016380284A patent/AU2016380284B2/en not_active Ceased
- 2016-12-29 KR KR1020187021661A patent/KR20180100348A/ko not_active Withdrawn
- 2016-12-29 US US16/067,407 patent/US11108220B2/en active Active
- 2016-12-29 CN CN201680077325.7A patent/CN108430874B/zh active Active
- 2016-12-29 EP EP16834159.2A patent/EP3397556B1/en active Active
- 2016-12-29 WO PCT/US2016/069192 patent/WO2017117383A1/en not_active Ceased
- 2016-12-29 ES ES16834159T patent/ES2929619T3/es active Active
- 2016-12-29 JP JP2018534714A patent/JP7007274B2/ja active Active
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2019
- 2019-12-26 JP JP2019236131A patent/JP7100010B2/ja active Active
-
2021
- 2021-07-21 US US17/381,496 patent/US11664647B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2020090099A (ja) | 2020-06-11 |
| US11108220B2 (en) | 2021-08-31 |
| EP3397556A1 (en) | 2018-11-07 |
| ES2929619T3 (es) | 2022-11-30 |
| CN108430874B (zh) | 2022-02-18 |
| CA3010201A1 (en) | 2017-07-06 |
| US20220102957A1 (en) | 2022-03-31 |
| JP7007274B2 (ja) | 2022-01-24 |
| WO2017117383A1 (en) | 2017-07-06 |
| JP7100010B2 (ja) | 2022-07-12 |
| AU2016380284A1 (en) | 2018-07-05 |
| US11664647B2 (en) | 2023-05-30 |
| CN108430874A (zh) | 2018-08-21 |
| EP3397556B1 (en) | 2022-08-10 |
| AU2016380284B2 (en) | 2021-10-28 |
| US20190027913A1 (en) | 2019-01-24 |
| JP2019505412A (ja) | 2019-02-28 |
| KR20180100348A (ko) | 2018-09-10 |
| BR112018013479A2 (pt) | 2018-12-04 |
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Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 29/12/2016, OBSERVADAS AS CONDICOES LEGAIS |