BR112018006502A2 - método de conversão de um álcool a uma cetona, catalisador, e método de produzir um catalisador - Google Patents

método de conversão de um álcool a uma cetona, catalisador, e método de produzir um catalisador

Info

Publication number
BR112018006502A2
BR112018006502A2 BR112018006502-1A BR112018006502A BR112018006502A2 BR 112018006502 A2 BR112018006502 A2 BR 112018006502A2 BR 112018006502 A BR112018006502 A BR 112018006502A BR 112018006502 A2 BR112018006502 A2 BR 112018006502A2
Authority
BR
Brazil
Prior art keywords
catalyst
ketone
alcohol
converting
producing
Prior art date
Application number
BR112018006502-1A
Other languages
English (en)
Other versions
BR112018006502B1 (pt
Inventor
B. Levy Alan
R. Keenan Scott
Raja Robert
M. Gill Arran
E. Potter Matthew
A. Van Aswegen Sivan
Original Assignee
Advansix Resins & Chemicals Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Advansix Resins & Chemicals Llc filed Critical Advansix Resins & Chemicals Llc
Publication of BR112018006502A2 publication Critical patent/BR112018006502A2/pt
Publication of BR112018006502B1 publication Critical patent/BR112018006502B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/86—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B01J27/1817—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with copper, silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1856—Phosphorus; Compounds thereof with iron group metals or platinum group metals with platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/005—Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/341—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
    • B01J37/343—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of ultrasonic wave energy
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
    • C07C35/08—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/39—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/385—Saturated compounds containing a keto group being part of a ring
    • C07C49/403—Saturated compounds containing a keto group being part of a ring of a six-membered ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

métodos para a conversão de um álcool, tal como ciclo-hexanol a uma cetona, tal como ciclo-hexanona, incluem a reação do álcool na presença de um catalisador e oxigênio para produzir a cetona. em uma modalidade representativa, o catalisador inclui uma estrutura microporosa de cloropirofosfato de cobre compreendendo uma pluralidade de nanopartículas de metais nobres. em uma modalidade representativa, as nanopartículas de metais nobres incluem pelo menos um metal selecionado a partir do grupo que compreende platina, paládio, e ouro.
BR112018006502-1A 2015-10-01 2016-09-29 Método de conversão de um álcool a uma cetona, catalisador, e método de produzir um catalisador BR112018006502B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562235684P 2015-10-01 2015-10-01
US62/235,684 2015-10-01
PCT/US2016/054334 WO2017059010A1 (en) 2015-10-01 2016-09-29 Nanoparticle catalysts for conversion of cyclohexanol to cyclohexanone

Publications (2)

Publication Number Publication Date
BR112018006502A2 true BR112018006502A2 (pt) 2018-10-09
BR112018006502B1 BR112018006502B1 (pt) 2022-01-11

Family

ID=58427914

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018006502-1A BR112018006502B1 (pt) 2015-10-01 2016-09-29 Método de conversão de um álcool a uma cetona, catalisador, e método de produzir um catalisador

Country Status (10)

Country Link
US (2) US9822052B2 (pt)
EP (1) EP3356319B1 (pt)
JP (1) JP6771549B2 (pt)
KR (1) KR102663114B1 (pt)
CN (1) CN108473407B (pt)
BR (1) BR112018006502B1 (pt)
ES (1) ES2821103T3 (pt)
MX (1) MX2018003813A (pt)
RU (1) RU2717342C1 (pt)
WO (1) WO2017059010A1 (pt)

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4918239A (en) * 1988-12-27 1990-04-17 National Science Council Method of producing cyclohexanone from cyclohexanol through oxidative dehydrogenation
DE19757297A1 (de) * 1997-12-22 1999-06-24 Basf Ag Verfahren zur Herstellung oxidischer Katalysatoren, die Kupfer in einer Oxidationsstufe > 0 enthalten
EP1101753A4 (en) 1998-07-30 2002-09-11 Sumitomo Chemical Co PROCESS FOR THE PRODUCTION OF ADIPIC ACID
JP4451939B2 (ja) 1999-02-19 2010-04-14 ダイセル化学工業株式会社 シクロアルカノンの製造方法
JP2002292282A (ja) * 2001-03-29 2002-10-08 Sud-Chemie Catalysts Inc シクロヘキサノール脱水素触媒及びその製造方法
US6703529B1 (en) 2002-09-12 2004-03-09 E. I. Du Pont De Nemours And Company Process for oxidation of cyclohexane
US7081552B2 (en) 2004-08-17 2006-07-25 Solutia Inc. Catalysts for cycloalkanes oxidation and decomposition of cycloalkyl hydroperoxide
CN100445255C (zh) 2007-04-21 2008-12-24 中国科学院新疆理化技术研究所 席夫碱-卟啉金属化合物催化氧化六碳环化合物的方法
US8981157B2 (en) 2011-05-13 2015-03-17 Ever Nu Technology, LLC Gas phase heterogeneous catalytic oxidation of alkanes to aliphatic ketones and/or other oxygenates
CN102850198B (zh) * 2011-06-30 2015-01-14 中国石油化工股份有限公司 一种环己醇氧化的方法
JP6103583B2 (ja) * 2012-03-13 2017-03-29 国立大学法人北陸先端科学技術大学院大学 金及びパラジウムを含む高分子保護ナノ粒子担持ハイドロタルサイト触媒、並びにその製造方法及び使用
US9382195B2 (en) 2013-03-14 2016-07-05 Honeywell International Inc. Oximation of KA oil by-product
CN104478701B (zh) 2014-11-24 2016-08-24 常州大学 连续流微通道反应器中醇酮油硝酸氧化合成己二酸的方法

Also Published As

Publication number Publication date
EP3356319A1 (en) 2018-08-08
EP3356319A4 (en) 2019-05-29
US20170096380A1 (en) 2017-04-06
ES2821103T3 (es) 2021-04-23
BR112018006502B1 (pt) 2022-01-11
CN108473407A (zh) 2018-08-31
JP6771549B2 (ja) 2020-10-21
RU2717342C1 (ru) 2020-03-23
EP3356319B1 (en) 2020-06-24
US20180065910A1 (en) 2018-03-08
JP2018535938A (ja) 2018-12-06
KR102663114B1 (ko) 2024-05-02
CN108473407B (zh) 2022-04-19
WO2017059010A1 (en) 2017-04-06
US9822052B2 (en) 2017-11-21
MX2018003813A (es) 2018-08-01
KR20180050757A (ko) 2018-05-15

Similar Documents

Publication Publication Date Title
BR112015030481A2 (pt) sistema e método para monitorar um processo
MX2016017355A (es) Lipido que comprende acido docosapentaenoico.
MX346356B (es) Procedimiento de obtencion de alcoholes superiores.
BR112017003956A2 (pt) adsorvente para ligação de metais e produção do mesmo
BR112018001226A2 (pt) goma arábica a partir de acacia seyal
BR112018006520A2 (pt) processo para hidrogenação catalítica de halonitroaromáticos
WO2015161468A8 (en) Methods and systems for producing isosorbide from biomass
BR112017023955A2 (pt) catalisador para a produção de 1,3-butadieno a partir de etanol
BR112018010229A2 (pt) sistema catalisador e processo para a produção de glicóis
MY183026A (en) Method for producing conjugated diene
BR112019006226A2 (pt) método para condicionamento de tratamento com ácido de um catalisador na produção de glicóis
MY169083A (en) Method for the catalytic aldol condensation of aldehydes
BR112017005344A2 (pt) método para a produção de um álcool alifático tendo 8 ou mais e 22 ou menos átomos de carbono por meio de hidrogenação de um ácido graxo ou um éster de ácido graxo usando um catalisador
MY174683A (en) Process for producing polyhydric alcohol
BR112018006502A2 (pt) método de conversão de um álcool a uma cetona, catalisador, e método de produzir um catalisador
BR112014031919A2 (pt) processo para produção de ácido acético
BR112017012993A2 (pt) processo catalítico para produzir propileno glicol pela redução seletiva de glicerol, catalisador e processo para produzir o catalisador
HK1248648A1 (zh) 製造鉑膠體的方法和通過該方法製造的鉑膠體
EA201590131A1 (ru) Способ производства зеркала без медного слоя
BR112017005358A2 (pt) método para produção de um composto, e, sal de um composto.
BR112014032024A2 (pt) processo para preparo de uma composição de etanol; composição de etanol formada termoquimicamente; e processo para controle do teor de isopropanol em um processo de produção de etanol
FR3000737B1 (fr) Procede de production d'hydrogene.
Kim A Study on Le Corbusier's Plan Libre in Terms of Void
Bellardita et al. H2 and value added chemicals from photocatalytic conversion of glucose
BR112015021778A2 (pt) produto de reação de retro-aldol, e, método para a produção de um produto de reação de retro-aldol

Legal Events

Date Code Title Description
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 29/09/2016, OBSERVADAS AS CONDICOES LEGAIS.