BR112017022524A2 - material polimérico poroso, composição, métodos para purificar uma amostra de fluido, para determinar a presença ou ausência de compostos em uma amostra de fluido, para remover compostos de uma amostra de fluido, para preparar um material polimérico poroso e uma composição, e, artigo de fabricação. - Google Patents

material polimérico poroso, composição, métodos para purificar uma amostra de fluido, para determinar a presença ou ausência de compostos em uma amostra de fluido, para remover compostos de uma amostra de fluido, para preparar um material polimérico poroso e uma composição, e, artigo de fabricação.

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Publication number
BR112017022524A2
BR112017022524A2 BR112017022524A BR112017022524A BR112017022524A2 BR 112017022524 A2 BR112017022524 A2 BR 112017022524A2 BR 112017022524 A BR112017022524 A BR 112017022524A BR 112017022524 A BR112017022524 A BR 112017022524A BR 112017022524 A2 BR112017022524 A2 BR 112017022524A2
Authority
BR
Brazil
Prior art keywords
fluid sample
composition
polymeric material
porous polymeric
compounds
Prior art date
Application number
BR112017022524A
Other languages
English (en)
Other versions
BR112017022524B1 (pt
Inventor
Alsbaiee Alaaeddin
j smith Brian
Helbling Damian
Alzate-Sanchez Diego
Hinestroza Juan
Xiao Leilei
R Dichtel William
Ling Yuhan
Original Assignee
Univ Cornell
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Cornell filed Critical Univ Cornell
Publication of BR112017022524A2 publication Critical patent/BR112017022524A2/pt
Publication of BR112017022524B1 publication Critical patent/BR112017022524B1/pt

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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
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    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
    • B01D15/40—Selective adsorption, e.g. chromatography characterised by the separation mechanism using supercritical fluid as mobile phase or eluent
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    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/025—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with wetted adsorbents; Chromatography
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  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

uma reação de substituição necleofílica para reticular polímero de ciclodextrina (cd) com grupos aromáticos rígidos, provendo uma área superficial elevada, polímeros contendo cd mesoporosos (p-cdps). os p-cdps podem ser usados para remover contaminantes orgânicos da água. através da encapsulação de poluentes para formar complexos hospedeiro-hóspede bem definidos com seletividades complementares sorventes de carbono ativado (ac). os p-cdps podem rapidamente sequestrar farmacêuticos, pesticidas, e outros micropoluentes orgânicos, alcançando capacidade de ligação de equilíbrio em segundos com constantes de taxa de adsorção 15-200 vezes maior que sorventes de cd não porosos e acs. o polímero cd pode ser regenerado várias vezes, através de um procedimento de lavagem em temperatura ambiente, sem nenhuma perda de desempenho.
BR112017022524-7A 2015-04-20 2016-04-19 Material polimérico mesoporoso, composição, métodos para purificar uma amostra de fluido, para determinar a presença ou ausência de compostos em uma amostra de fluido, para remover compostos de uma amostra de fluido, para preparar um material polimérico poroso e uma composição, e, artigo de fabricação BR112017022524B1 (pt)

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