BR112016013709A2 - Combinação de inibidor para processo de transesterificação catalisada por sal de lítio e método para remoção de sal de lítio - Google Patents

Combinação de inibidor para processo de transesterificação catalisada por sal de lítio e método para remoção de sal de lítio

Info

Publication number
BR112016013709A2
BR112016013709A2 BR112016013709A BR112016013709A BR112016013709A2 BR 112016013709 A2 BR112016013709 A2 BR 112016013709A2 BR 112016013709 A BR112016013709 A BR 112016013709A BR 112016013709 A BR112016013709 A BR 112016013709A BR 112016013709 A2 BR112016013709 A2 BR 112016013709A2
Authority
BR
Brazil
Prior art keywords
lithium salt
substituted alkyl
polyene
beta
alpha
Prior art date
Application number
BR112016013709A
Other languages
English (en)
Inventor
Wilczynski Robert
R Eddy Christopher
O Osby John
T P Hoang Nguyen Lan
Original Assignee
Dow Global Technologies Llc
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc, Rohm & Haas filed Critical Dow Global Technologies Llc
Publication of BR112016013709A2 publication Critical patent/BR112016013709A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/02—Preparation of carboxylic acid esters by interreacting ester groups, i.e. transesterification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/587—Monocarboxylic acid esters having at least two carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
    • C08F220/68—Esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/08—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkali metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1818—C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/285—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety
    • C08F220/287—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety and containing polypropylene oxide in the alcohol moiety

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

COMBINAÇÃO DE INIBIDOR PARA PROCESSO DE TRANSESTERIFICAÇÃO CATALISADA POR SAL DE LÍTIO E MÉTODO PARA REMOÇÃO DE SAL DE LÍTIO. Um processo para formar uma composição compreendendo um polieno assimétrico, o polieno assimétrico compreendendo uma "extremidade carbonil (Alfa),(Beta) insaturada" e uma "extremidade de ligação dupla C-C", o processo compreendendo: reagir um álcool contendo alqueno ou polieno com um alquil éster de um ácido carboxílico (Alfa),(Beta) insaturado na presença de, pelo menos, os seguintes componentes A) a C) para formar uma solução compreendendo um polieno assimétrico: A)um sal de lítio; B) um componente selecionado a partir do grupo que consiste em hidroquinona, um alquil-fenol substituído, um alquil-substituído-fenol substituído, um alquil-hidroquinona substituída, um alquil-substituído-hidroquinona substituída, e combinações dos mesmos; e C)um Composto contendo N-oxil; em que, a "extremidade carbonil (Alfa),(Beta) insaturada" do polieno assimétrico é selecionada a partir do grupo que consiste em estruturas A) a C), como aqui descrito, e em que, a "extremidade de ligação dupla C-C" do polieno assimétrico é selecionada a partir do grupo que consiste em estruturas 1) a 17), como aqui descrito.
BR112016013709A 2013-12-26 2014-11-21 Combinação de inibidor para processo de transesterificação catalisada por sal de lítio e método para remoção de sal de lítio BR112016013709A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361920939P 2013-12-26 2013-12-26
PCT/US2014/066745 WO2015099915A1 (en) 2013-12-26 2014-11-21 Inhibitor combination for lithium salt-catalyzed transesterification process and method for removing lithium salt

Publications (1)

Publication Number Publication Date
BR112016013709A2 true BR112016013709A2 (pt) 2017-08-08

Family

ID=52021458

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112016013709A BR112016013709A2 (pt) 2013-12-26 2014-11-21 Combinação de inibidor para processo de transesterificação catalisada por sal de lítio e método para remoção de sal de lítio

Country Status (8)

Country Link
US (2) US9796650B2 (pt)
EP (1) EP3087049A1 (pt)
JP (1) JP6678105B2 (pt)
KR (1) KR20160107181A (pt)
CN (1) CN106170472B (pt)
BR (1) BR112016013709A2 (pt)
SG (1) SG11201605119WA (pt)
WO (1) WO2015099915A1 (pt)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2768552T3 (es) 2013-12-26 2020-06-23 Dow Global Technologies Llc Polímeros basados en etileno formados usando polienos asimétricos
JP7050630B2 (ja) * 2018-08-30 2022-04-08 信越化学工業株式会社 （メタ）アクリロイル化合物及びその製造方法

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3264275A (en) * 1961-06-27 1966-08-02 Du Pont Elastomeric interpolymers comprising ethylene and acrylonitrile
GB1094998A (en) 1966-04-19 1967-12-13 Vergier Chemical Company Ltd D Process for the production of esters
US3542749A (en) 1968-03-07 1970-11-24 Gulf Research Development Co Novel ethylene copolymers and selfsupporting film prepared therefrom
DE3423443A1 (de) 1984-06-26 1986-01-02 Röhm GmbH, 6100 Darmstadt Verfahren zur herstellung von estern der acryl- und methacrylsaeure durch umesterung
JPH0613604B2 (ja) * 1985-03-22 1994-02-23 鐘淵化学工業株式会社 分子末端に不飽和基を含有するポリアルキレンオキシドの製造法
JPH0717577B2 (ja) * 1987-10-23 1995-03-01 日立化成工業株式会社 エーテル基含有アルコールのメタクリル酸エステルの製造法
US4916255A (en) * 1987-05-19 1990-04-10 Hitachi, Ltd. Method for production of methacrylate ester
US5072027A (en) * 1988-10-06 1991-12-10 Hitachi Chemical Company, Ltd. Process for producing methacrylic acid esters
JPH03106847A (ja) * 1989-09-20 1991-05-07 Hitachi Chem Co Ltd メタクリル酸エステルの製造法
JPH03109350A (ja) 1989-09-22 1991-05-09 Hitachi Chem Co Ltd メタクリル酸エステルの製造法
JP2725593B2 (ja) * 1993-04-15 1998-03-11 株式会社日本触媒 （メタ）アクリル酸およびそのエステルの重合防止方法
KR100247527B1 (ko) 1996-04-03 2000-03-15 겐지 아이다 시멘트분산방법및시멘트조성물
US6391463B1 (en) * 1996-12-23 2002-05-21 Sartomer Technology Co., Inc. Silicon-containing alkoxylated (meth)acrylate monomers
AU743962B2 (en) * 1997-08-29 2002-02-14 Rohm And Haas Company Transesterification process
US7321051B2 (en) * 2000-10-23 2008-01-22 Nippon Shokubai Co., Ltd. Composition of vinyl ether group-containing (meth) acrylic ester and production method thereof
JP4065676B2 (ja) * 2000-11-01 2008-03-26 三菱レイヨン株式会社 （メタ）アクリル酸エステルの製造方法および（メタ）アクリル酸エステル製造用触媒
JP2004010551A (ja) * 2002-06-07 2004-01-15 Nippon Shokubai Co Ltd ビニルエーテル基含有（メタ）アクリル酸エステル類の製造方法
US20060173191A1 (en) * 2005-01-28 2006-08-03 Curtis Michael A Transesterification process for production of (meth)acrylate ester monomers
JP4628219B2 (ja) 2005-08-22 2011-02-09 株式会社日本触媒 ポリアルキレンオキサイド骨格を有する（メタ）アクリル酸エステル化合物及びその製造方法
DE102005044250A1 (de) * 2005-09-15 2007-03-29 Röhm Gmbh Verfahren zur Herstellung von Methacrylaten mit reaktiven Doppelbindungen
CN101088990B (zh) * 2006-06-13 2011-08-03 罗门哈斯公司 用来制备(甲基)丙烯酸酯单体的酯交换法
US8920885B2 (en) * 2006-11-21 2014-12-30 Dr. Ben Curatolo, Inc. Corrosion-resistant, chromium-free, self-priming coatings curable by ultraviolet light
DE102007031473A1 (de) * 2007-07-05 2009-01-08 Evonik Röhm Gmbh Verfahren zur Herstellung von Ethylenglycoldimethacrylat
DE102007031468A1 (de) * 2007-07-05 2009-01-08 Evonik Röhm Gmbh Verfahren zur Herstellung von Allylmethacrylat
JP2009185169A (ja) * 2008-02-06 2009-08-20 Chugoku Marine Paints Ltd 新規ポリオルガノシロキサン及びそれを架橋剤として含有する室温硬化性シリコーン組成物
GB201009969D0 (en) * 2010-06-15 2010-07-21 Ecosynth Bvba Transesterification process using mixed salt acetylacetonates catalysts
SG190030A1 (en) 2010-10-29 2013-06-28 Dow Global Technologies Llc Ethylene-based polymers and processes for the same
JP6054153B2 (ja) * 2011-11-30 2016-12-27 三洋化成工業株式会社 活性エネルギー線硬化型ハードコート用組成物
WO2013095969A1 (en) 2011-12-22 2013-06-27 Dow Global Technologies Llc Ethylene-based polymers with improved melt strength and processes for the same
US10442878B2 (en) * 2012-06-27 2019-10-15 Dow Global Technologies Llc Ethylene-based polymers and processes for the same

Also Published As

Publication number Publication date
CN106170472B (zh) 2020-04-14
US9796650B2 (en) 2017-10-24
US20160297736A1 (en) 2016-10-13
US20180037531A1 (en) 2018-02-08
CN106170472A (zh) 2016-11-30
JP2017502001A (ja) 2017-01-19
WO2015099915A1 (en) 2015-07-02
EP3087049A1 (en) 2016-11-02
KR20160107181A (ko) 2016-09-13
SG11201605119WA (en) 2016-07-28
JP6678105B2 (ja) 2020-04-08

Similar Documents

Publication Publication Date Title
BR112015017869A2 (pt) hidroalquilação aromtática de alquilo para a produção de plastificantes
BR112014026109A2 (pt) composição para tratamento dos cabelos que compreende ésteres insaturados de poliol metatetizados
WO2014206554A3 (de) Verwendung von speziellen n-methyl-n-acylglucaminen in hautreinigungsmitteln und handgeschirrspülmitteln
BR112016006926A8 (pt) uso de um conjugado de ácido quínico com pelo menos uma molécula de ácido cafeico na preparação de uma composição para a prevenção e/ou a melhora da senescência de célula ou tecido
AR089482A1 (es) Composicion antimicrobiana y metodo para prolongar la vida util del agua, alimentos/piensos o ingredientes de alimentos/piensos
CL2015001726A1 (es) Biorefinación de aceite de resina crudo
CR20120268A (es) Método para reducir el estrés por temperatura de plantas
CL2013002166A1 (es) Compuesto correspondiente a la sal de magnesio del acido (s)-alfa-etoxi-4-[2-metil-5-[4-metiltiofenil-1h-pirrol-1-il]etoxi]bencenpropanoico; composicion farmaceutica que lo comprende; y uso para el tratamiento de lipodistrofia.
BR112014013098A2 (pt) composições compreendendo ácidos graxos que têm 20 carbonos e métodos de produção e uso dos mesmos
AR105494A1 (es) Método para preparar derivados de ácido 3-(2-anilino-1-ciclohexil-1h-bencimidazol-5-il)propanoico sustituido
BR112014032741A2 (pt) lipase em esterificação de ácidos graxos de cadeia curta
BR112015020497A2 (pt) processo para remover o formaldeído de uma composição compreendendo glicolaldeído
BRPI0613981A8 (pt) processo para a produção de ésteres alquílicos de ácidos carboxílicos
BR112013030145A2 (pt) processo para preparação de ácido metacrílico
AR087254A1 (es) Gliceratos de metales alcalinos y alcalinoterreos para la desacidificacion y secado de esteres de acidos grasos
BR112014014060A2 (pt) processo para a preparação de travoprosta
BR112015021332A2 (pt) sal de sódio de ácido (2s, 5r)-6-benzilóxi-7-oxo-1,6-diaza-biciclo [3.2.1] octano-2-carboxílico e sua preparação
BR112013001942A2 (pt) ester de ácidos carboxílicos hidróxi o-substituído, processo para produzir pelo menos um éster de ácidos hidróxi carboxílicos o-substituídos, e, composição cosmética
BR112017010968A2 (pt) formulação aquosa, processo para preparação de uma solução aquosa, e, uso de soluções aquosas.
BR112013001010A2 (pt) processo para o pós-tratamento de ésteres de poliol
BR112016013709A2 (pt) Combinação de inibidor para processo de transesterificação catalisada por sal de lítio e método para remoção de sal de lítio
BR112014017587A2 (pt) métodos e formulações para o tratamento de deficiências de ácido siálico
BR112017021960A2 (pt) processo para produção de um composto, composto, e, uso de um sal de metal base.
BR112014009266A2 (pt) processo para a preparação de ácidos isoxazolil-metóxi-nicotínicos
BR112015015083A2 (pt) método para produzir olefina

Legal Events

Date Code Title Description
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B11D Dismissal acc. art. 38, par 2 of ipl - failure to pay fee after grant in time