GB1094998A - Process for the production of esters - Google Patents

Process for the production of esters

Info

Publication number
GB1094998A
GB1094998A GB2796365A GB2796365A GB1094998A GB 1094998 A GB1094998 A GB 1094998A GB 2796365 A GB2796365 A GB 2796365A GB 2796365 A GB2796365 A GB 2796365A GB 1094998 A GB1094998 A GB 1094998A
Authority
GB
United Kingdom
Prior art keywords
alcohol
catalyst
ethylene glycol
glycol
methacrylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2796365A
Inventor
Denis Anthony Kinsley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
VERGIER CHEMICAL Co Ltd D
Original Assignee
VERGIER CHEMICAL Co Ltd D
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by VERGIER CHEMICAL Co Ltd D filed Critical VERGIER CHEMICAL Co Ltd D
Publication of GB1094998A publication Critical patent/GB1094998A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

An ester of acrylic or methacrylic acid is transesterified with an alcohol at elevated temperature in the presence, as a catalyst of an alkali metal salt of mercaptobenzthiazole, or phthalimide or lithium hydroxide. The reaction may be at the boiling point of the mixture and the alcohol displaced is distilled off. The catalyst may be added or formed in situ and a polymerization inhibitors may be present. Butanol, octanol, lauryl alcohol, ethoxyethanol, ethylene glycol, 1,3-propylene glycol, diethylene glycol, cyclohexanol, glycerol, pentaerythritol, and dimethyl aminoethanol are mentioned and examples describe the preparation of ethylene glycol di- and mono-methacrylate and butyl methacrylate.
GB2796365A 1966-04-19 1965-07-01 Process for the production of esters Expired GB1094998A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1714966 1966-04-19

Publications (1)

Publication Number Publication Date
GB1094998A true GB1094998A (en) 1967-12-13

Family

ID=10090144

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2796365A Expired GB1094998A (en) 1966-04-19 1965-07-01 Process for the production of esters

Country Status (1)

Country Link
GB (1) GB1094998A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2566394A1 (en) * 1984-06-26 1985-12-27 Roehm Gmbh PROCESS FOR THE PREPARATION OF ESTERS OF ACRYLIC AND METHACRYLIC ACIDS BY TRANS-ESTERIFICATION
US5072027A (en) * 1988-10-06 1991-12-10 Hitachi Chemical Company, Ltd. Process for producing methacrylic acid esters
WO2009003744A1 (en) * 2007-07-05 2009-01-08 Evonik Röhm Gmbh Method for producing (meth)acrylates
WO2010003709A2 (en) * 2008-07-07 2010-01-14 Evonik Röhm Gmbh Method for the production of (meth)acrylic esters
US9796650B2 (en) 2013-12-26 2017-10-24 Dow Global Technologies Llc Inhibitor combination for lithium salt-catalyzed transesterification process and method for removing lithium salt

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2566394A1 (en) * 1984-06-26 1985-12-27 Roehm Gmbh PROCESS FOR THE PREPARATION OF ESTERS OF ACRYLIC AND METHACRYLIC ACIDS BY TRANS-ESTERIFICATION
DE3423443A1 (en) * 1984-06-26 1986-01-02 Röhm GmbH, 6100 Darmstadt METHOD FOR THE PRODUCTION OF ESTERS OF ACRYLIC AND METHACRYLIC ACID BY TRANSESTERATION
US5072027A (en) * 1988-10-06 1991-12-10 Hitachi Chemical Company, Ltd. Process for producing methacrylic acid esters
WO2009003744A1 (en) * 2007-07-05 2009-01-08 Evonik Röhm Gmbh Method for producing (meth)acrylates
US8049030B2 (en) 2007-07-05 2011-11-01 Evonik Röhm Gmbh Method for producing (meth)acrylates
WO2010003709A2 (en) * 2008-07-07 2010-01-14 Evonik Röhm Gmbh Method for the production of (meth)acrylic esters
WO2010003709A3 (en) * 2008-07-07 2010-04-15 Evonik Röhm Gmbh Method for the production of (meth)acrylic esters
CN102046581A (en) * 2008-07-07 2011-05-04 赢创罗姆有限公司 Method for the production of (meth)acrylic esters
RU2515985C2 (en) * 2008-07-07 2014-05-20 Эвоник Рем ГмбХ Method of obtaining (met)acrylic acid ethers
US8916724B2 (en) 2008-07-07 2014-12-23 Evonik Roehm Gmbh Method for the production of (meth)acrylic esters
TWI488837B (en) * 2008-07-07 2015-06-21 Evonik Roehm Gmbh Process for preparing (meth) acrylic esters
US9796650B2 (en) 2013-12-26 2017-10-24 Dow Global Technologies Llc Inhibitor combination for lithium salt-catalyzed transesterification process and method for removing lithium salt

Similar Documents

Publication Publication Date Title
ZA826087B (en) Copolymers of alpha-beta-unsaturated dicarboxylic acid esters,methods for their production and their use as lubricants for processing plastics
GB2005252A (en) A process for the production of esters of methacrylic acid
GB1341623A (en) Production of esters of epoyidised stearic acid
GB1094998A (en) Process for the production of esters
GB1367591A (en) Transesterification process
GB1292383A (en) Process for production of acrylates and methacrylates of higher alcohols
GB1174148A (en) Method of producing Acrylic and Methacrylic Esters
GB894639A (en) Improvements relating to the preparation of esters
GB938217A (en) Self-adhesive tapes and adhesives therefor
GB1155897A (en) Process for the production of Esters of Acrylic Acid
ES304883A1 (en) A procedure for the preparation of esters. (Machine-translation by Google Translate, not legally binding)
ES476885A1 (en) Process for the preparation of ethylesters.
DK132023B (en) Process for the preparation of 2-hydroxyethyl esters of 2-quinoxaline carboxylic acid 1,4-dioxides by transesterification of a corresponding 2-alkyl ester with ethylene glycol in the presence of a basic catalyst.
GB707005A (en) An improved process for the alcoholysis of glycerides
GB1053574A (en)
GB936373A (en) Improvements in or relating to the production of esters of boron-containing acids
GB767780A (en) Improvements in trans n-carbamylamic esters
GB1058387A (en) Process for the manufacture of film-and fibre-forming polyesters
JPS53144523A (en) Production of acrylic or methacrylic ester
ES418130A1 (en) O,o-dialkyl-o-(1,2-dibromo-2,2-dichloroethyl)-thionophosphoric acid ester
JPS5217447A (en) Process for preparation of trans-4- aminomethylcyclohexane-carboxylic acid ester
ES2088609T3 (en) PROCEDURE FOR OBTAINING ESTERS OF HYDROXIPIVALIC ACID.
GB856857A (en) Method of producing boron trialkyls
GB1177227A (en) Improvements relating to Esters of alpha,beta-Unsaturated Acids
GB999805A (en) Process for the production of spinnable polyesters