BR112015020458B1 - Processo para preparar uma composição de pelotas adsorventes de carbono e composição de pelotas adsorventes de carbono - Google Patents
Processo para preparar uma composição de pelotas adsorventes de carbono e composição de pelotas adsorventes de carbono Download PDFInfo
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- BR112015020458B1 BR112015020458B1 BR112015020458-9A BR112015020458A BR112015020458B1 BR 112015020458 B1 BR112015020458 B1 BR 112015020458B1 BR 112015020458 A BR112015020458 A BR 112015020458A BR 112015020458 B1 BR112015020458 B1 BR 112015020458B1
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- pellets
- carbon
- carbon adsorbent
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- 239000008188 pellet Substances 0.000 title claims abstract description 84
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 43
- 239000003463 adsorbent Substances 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 27
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- 239000002243 precursor Substances 0.000 claims abstract description 21
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 20
- 150000001336 alkenes Chemical class 0.000 claims abstract description 18
- 239000011230 binding agent Substances 0.000 claims abstract description 18
- 229920001467 poly(styrenesulfonates) Polymers 0.000 claims abstract description 18
- 239000011148 porous material Substances 0.000 claims abstract description 12
- 238000002844 melting Methods 0.000 claims abstract description 6
- 230000008018 melting Effects 0.000 claims abstract description 6
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052753 mercury Inorganic materials 0.000 claims abstract description 6
- 238000002459 porosimetry Methods 0.000 claims abstract description 6
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 13
- 239000003456 ion exchange resin Substances 0.000 claims description 12
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 12
- 238000000197 pyrolysis Methods 0.000 claims description 11
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 8
- 239000004793 Polystyrene Substances 0.000 claims description 8
- 229920002223 polystyrene Polymers 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 5
- 239000003431 cross linking reagent Substances 0.000 claims description 4
- 229920003086 cellulose ether Polymers 0.000 claims description 2
- 238000001179 sorption measurement Methods 0.000 abstract description 39
- 239000002808 molecular sieve Substances 0.000 abstract description 6
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract description 6
- 239000003446 ligand Substances 0.000 abstract description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 42
- 239000007789 gas Substances 0.000 description 25
- 238000000926 separation method Methods 0.000 description 25
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 24
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 24
- 239000001294 propane Substances 0.000 description 21
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 230000008929 regeneration Effects 0.000 description 9
- 238000011069 regeneration method Methods 0.000 description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 8
- 239000005977 Ethylene Substances 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 238000003795 desorption Methods 0.000 description 5
- 239000011324 bead Substances 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000011261 inert gas Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000002336 sorption--desorption measurement Methods 0.000 description 4
- 239000011800 void material Substances 0.000 description 4
- 238000010926 purge Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- -1 H + Chemical class 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910021398 atomic carbon Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000000542 sulfonic acid group Chemical group 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- CVSVTCORWBXHQV-UHFFFAOYSA-N creatine Chemical compound NC(=[NH2+])N(C)CC([O-])=O CVSVTCORWBXHQV-UHFFFAOYSA-N 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000002082 metal nanoparticle Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical compound COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28042—Shaped bodies; Monolithic structures
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
- B01J20/28085—Pore diameter being more than 50 nm, i.e. macropores
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28088—Pore-size distribution
- B01J20/28092—Bimodal, polymodal, different types of pores or different pore size distributions in different parts of the sorbent
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J20/3042—Use of binding agents; addition of materials ameliorating the mechanical properties of the produced sorbent
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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- B01D2253/10—Inorganic adsorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D2253/10—Inorganic adsorbents
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- B01D2253/302—Dimensions
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D2257/702—Hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0462—Temperature swing adsorption
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/54—Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
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- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
- C01P2006/17—Pore diameter distribution
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Carbon And Carbon Compounds (AREA)
- Separation Of Gases By Adsorption (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361805656P | 2013-03-27 | 2013-03-27 | |
| US61/805,656 | 2013-03-27 | ||
| PCT/US2014/031537 WO2014160624A1 (en) | 2013-03-27 | 2014-03-24 | Novel carbon molecular sieve and pellet compositions useful for c2-c3 alkane/alkene separations |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112015020458A2 BR112015020458A2 (pt) | 2017-07-18 |
| BR112015020458B1 true BR112015020458B1 (pt) | 2020-10-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112015020458-9A BR112015020458B1 (pt) | 2013-03-27 | 2014-03-24 | Processo para preparar uma composição de pelotas adsorventes de carbono e composição de pelotas adsorventes de carbono |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9579627B2 (enExample) |
| EP (1) | EP2978524A1 (enExample) |
| JP (2) | JP6400077B2 (enExample) |
| CN (1) | CN105283245B (enExample) |
| BR (1) | BR112015020458B1 (enExample) |
| WO (1) | WO2014160624A1 (enExample) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014160624A1 (en) * | 2013-03-27 | 2014-10-02 | Dow Global Technologies Llc | Novel carbon molecular sieve and pellet compositions useful for c2-c3 alkane/alkene separations |
| KR102263688B1 (ko) * | 2014-10-07 | 2021-06-10 | 삼성전자주식회사 | 무선 통신 시스템에서 다른 무선 접속 기술을 이용한 다중 연결을 제공하기 위한 장치 및 방법 |
| EA201791685A1 (ru) | 2015-01-27 | 2018-01-31 | Дау Глоубл Текнолоджиз Ллк | Отделение азота от газообразного углеводорода с использованием пиролизованной сульфированной макропористой ионообменной смолы |
| CN107206305A (zh) | 2015-01-27 | 2017-09-26 | 陶氏环球技术有限责任公司 | 使用亚烷基桥接的可再生大孔吸附剂在填充移动床中利用微波再生将c2+链烷烃与甲烷分离 |
| CN105597709A (zh) * | 2016-03-08 | 2016-05-25 | 湖南凯美特气体股份有限公司 | 一种吸附co2的碳材料的制备与改性方法 |
| EP3548172B1 (en) * | 2016-11-30 | 2020-12-09 | Solvay SA | Advanced porous carbonaceous materials and methods to prepare them |
| WO2020101972A1 (en) | 2018-11-12 | 2020-05-22 | Dow Global Technologies Llc | Catalyst support comprising mesoporous carbon |
| JP2022553921A (ja) * | 2019-10-11 | 2022-12-27 | ユニバーサル マター インコーポレイテッド | グラフェンを合成するための装置、方法、およびカーボンピル |
| CN113019318B (zh) * | 2021-02-26 | 2022-06-14 | 华南理工大学 | 一种分离烯烃烷烃的碳分子筛制备方法及应用 |
| WO2024262401A1 (ja) * | 2023-06-23 | 2024-12-26 | 株式会社クラレ | 分子篩炭の再生方法 |
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|---|---|---|---|---|
| FR2216227B1 (enExample) | 1973-02-01 | 1976-11-26 | Sumitomo Chemical Co | |
| JPS5230799A (en) | 1975-09-04 | 1977-03-08 | Sumitomo Chem Co Ltd | Method for production of porous carbon |
| US4526887A (en) * | 1983-03-16 | 1985-07-02 | Calgon Carbon Corporation | Carbon molecular sieves and a process for their preparation and use |
| CA1291110C (en) | 1985-11-18 | 1991-10-22 | Christopher John Carruthers Edwards | Porous carbon structures and methods for their preparation |
| JPH0620546B2 (ja) * | 1987-03-10 | 1994-03-23 | 鐘紡株式会社 | 分子ふるい炭素及びその製造法 |
| US4933314A (en) * | 1987-03-10 | 1990-06-12 | Kanebo Ltd. | Molecular sieving carbon |
| US4839331A (en) * | 1988-01-29 | 1989-06-13 | Rohm And Haas Company | Carbonaceous adsorbents from pyrolyzed polysulfonated polymers |
| US5094754A (en) | 1988-01-29 | 1992-03-10 | Rohm And Haas Company | Carbonaceous adsorbents from pyrolyzed polysulfonated polymers |
| US6503295B1 (en) | 2000-09-20 | 2003-01-07 | Chevron U.S.A. Inc. | Gas separations using mixed matrix membranes |
| JP6076255B2 (ja) * | 2011-08-17 | 2017-02-08 | 株式会社クラレ | 金属錯体、並びにそれからなる吸着材、吸蔵材及び分離材 |
| WO2014160624A1 (en) | 2013-03-27 | 2014-10-02 | Dow Global Technologies Llc | Novel carbon molecular sieve and pellet compositions useful for c2-c3 alkane/alkene separations |
-
2014
- 2014-03-24 WO PCT/US2014/031537 patent/WO2014160624A1/en not_active Ceased
- 2014-03-24 JP JP2016505518A patent/JP6400077B2/ja not_active Expired - Fee Related
- 2014-03-24 US US14/763,855 patent/US9579627B2/en not_active Expired - Fee Related
- 2014-03-24 CN CN201480027657.5A patent/CN105283245B/zh not_active Expired - Fee Related
- 2014-03-24 BR BR112015020458-9A patent/BR112015020458B1/pt not_active IP Right Cessation
- 2014-03-24 EP EP14722478.6A patent/EP2978524A1/en not_active Withdrawn
-
2018
- 2018-04-05 JP JP2018073461A patent/JP6545314B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20160008787A1 (en) | 2016-01-14 |
| CN105283245B (zh) | 2019-04-19 |
| WO2014160624A1 (en) | 2014-10-02 |
| US9579627B2 (en) | 2017-02-28 |
| JP6400077B2 (ja) | 2018-10-03 |
| JP2016518972A (ja) | 2016-06-30 |
| JP6545314B2 (ja) | 2019-07-17 |
| EP2978524A1 (en) | 2016-02-03 |
| JP2018122301A (ja) | 2018-08-09 |
| BR112015020458A2 (pt) | 2017-07-18 |
| CN105283245A (zh) | 2016-01-27 |
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