BR112014032145B1 - composição adsorvente tratada termicamente, e usada em processos de adsorção e separação de gás, processo de adsorção para separar n2 de uma mistura de gás contendo n2, e, método para fabricar uma composição adsorvente aglomerada - Google Patents

composição adsorvente tratada termicamente, e usada em processos de adsorção e separação de gás, processo de adsorção para separar n2 de uma mistura de gás contendo n2, e, método para fabricar uma composição adsorvente aglomerada Download PDF

Info

Publication number
BR112014032145B1
BR112014032145B1 BR112014032145-0A BR112014032145A BR112014032145B1 BR 112014032145 B1 BR112014032145 B1 BR 112014032145B1 BR 112014032145 A BR112014032145 A BR 112014032145A BR 112014032145 B1 BR112014032145 B1 BR 112014032145B1
Authority
BR
Brazil
Prior art keywords
adsorbent
agglomerated
particles
adsorption
silicone
Prior art date
Application number
BR112014032145-0A
Other languages
English (en)
Portuguese (pt)
Other versions
BR112014032145A2 (pt
Inventor
Philip Alexander Barrett
Steven John Pontonio
Persefoni Kechagia
Neil Andrew Stephenson
Kerry C. Weston
Original Assignee
Praxair Technology, Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/530,236 external-priority patent/US20130340614A1/en
Application filed by Praxair Technology, Inc filed Critical Praxair Technology, Inc
Publication of BR112014032145A2 publication Critical patent/BR112014032145A2/pt
Publication of BR112014032145B1 publication Critical patent/BR112014032145B1/pt

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B01D53/0476—Vacuum pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/183—Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28011—Other properties, e.g. density, crush strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/28085—Pore diameter being more than 50 nm, i.e. macropores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B01D2253/1085—Zeolites characterized by a silicon-aluminium ratio
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/11—Clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/102—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0462—Temperature swing adsorption
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
BR112014032145-0A 2012-06-22 2013-06-20 composição adsorvente tratada termicamente, e usada em processos de adsorção e separação de gás, processo de adsorção para separar n2 de uma mistura de gás contendo n2, e, método para fabricar uma composição adsorvente aglomerada BR112014032145B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US13/530,236 2012-06-22
US13/530,236 US20130340614A1 (en) 2012-06-22 2012-06-22 Novel adsorbent compositions
US13/923,096 2013-06-20
PCT/US2013/046862 WO2013192435A1 (en) 2012-06-22 2013-06-20 Novel adsorbent compositions
US13/923,096 US9050582B2 (en) 2012-06-22 2013-06-20 Adsorbent compositions

Publications (2)

Publication Number Publication Date
BR112014032145A2 BR112014032145A2 (pt) 2017-06-27
BR112014032145B1 true BR112014032145B1 (pt) 2021-02-23

Family

ID=48877513

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014032145-0A BR112014032145B1 (pt) 2012-06-22 2013-06-20 composição adsorvente tratada termicamente, e usada em processos de adsorção e separação de gás, processo de adsorção para separar n2 de uma mistura de gás contendo n2, e, método para fabricar uma composição adsorvente aglomerada

Country Status (8)

Country Link
US (2) US9050582B2 (enExample)
KR (1) KR102141723B1 (enExample)
CN (1) CN104364008B (enExample)
BR (1) BR112014032145B1 (enExample)
CA (1) CA2875103C (enExample)
IN (1) IN2014DN09620A (enExample)
MX (1) MX376182B (enExample)
WO (1) WO2013192435A1 (enExample)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9555401B2 (en) * 2011-01-25 2017-01-31 Zeochem Llc Molecular sieve adsorbent blends and uses thereof
TWI659778B (zh) 2014-04-09 2019-05-21 美商Ｗ Ｒ 康格雷氏公司 經改良之氣體或液體吸附和／或脫附用之沸石粒子及其應用與製造方法
US9764313B2 (en) * 2014-06-18 2017-09-19 Basf Corporation Molecular sieve catalyst compositions, catalyst composites, systems, and methods
US10850265B2 (en) 2014-06-18 2020-12-01 Basf Corporation Molecular sieve catalyst compositions, catalytic composites, systems, and methods
CN104368307A (zh) * 2014-11-04 2015-02-25 东北林业大学 一种氨吸附专用活性炭的制备方法
FR3045411B1 (fr) * 2015-12-18 2021-06-04 Air Liquide Adsorbant structure monolithique autosupporte comprenant de l'halloysite comme liant
FR3059571B1 (fr) * 2016-12-02 2018-11-16 Arkema France Materiau adsorbant zeolithique, procede de preparation et utilisation pour la separation non-cryogenique des gaz industriels
US10315184B2 (en) * 2017-04-17 2019-06-11 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Adsorbent-loaded beads for high temperature adsorption processes
US10717035B2 (en) 2017-02-13 2020-07-21 Praxair Technology, Inc. Tunable adsorbents
US10792610B2 (en) 2017-04-07 2020-10-06 Praxair Technology, Inc. Process for generating higher VPSA product pressure
US10525399B2 (en) 2017-04-17 2020-01-07 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Sorbent-loaded fibers for high temperature adsorption processes
US10525400B2 (en) 2017-04-17 2020-01-07 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Sorbent-loaded beads for high temperature adsorption processes
KR101896274B1 (ko) 2017-05-29 2018-09-10 (주)스마트코리아 산가스 제거효율이 우수한 기능성 흡착제 조성물
US12076707B2 (en) 2018-07-02 2024-09-03 Praxair Technology, Inc. Large crystal tunable adsorbents
CN108854947B (zh) * 2018-07-04 2021-08-17 洛阳建龙微纳新材料股份有限公司 一种混合阳离子AgCa-LSX分子筛及其制备方法和应用
CN109701484A (zh) * 2019-02-28 2019-05-03 西安工程大学 一种铝掺杂型二氧化硅复合吸附材料的制备方法
CN109701486A (zh) * 2019-02-28 2019-05-03 西安工程大学 一种疏水性三氧化二铝/二氧化硅吸附材料的制备方法
CN109718632A (zh) * 2019-03-05 2019-05-07 四川一脉科技有限公司 一种收集合成驰放气中氢气和一氧化碳的方法
CN110252261A (zh) * 2019-06-21 2019-09-20 南京信息工程大学 一种树脂基纳米羟基磷灰石复合材料、制备方法及在氟污染水体处理中的应用
WO2023250300A1 (en) 2022-06-20 2023-12-28 Zeochem Llc Adsorbent for separation of a gaseous stream
US20250033023A1 (en) * 2021-12-06 2025-01-30 Susteon Inc. Materials, systems, and processes for production of high purity oxygen
CN118804892A (zh) * 2022-03-29 2024-10-18 旭化成株式会社 沸石成型体、吸附装置、精制气体的制造方法以及沸石成型体的制造方法
DE102024107287A1 (de) * 2024-03-14 2025-09-18 Volkswagen Aktiengesellschaft Zeolithisches Granulat, Verfahren zu dessen Herstellung und dessen Verwendung als Adsorptionsmittel

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB827043A (en) 1956-11-05 1960-02-03 Union Carbide Corp Improvements in and relating to bonded molecular sieves
DE2025893B2 (de) 1970-05-27 1979-12-06 Bayer Ag, 5090 Leverkusen Glasfaserverstärkte Zeolith-Granulate
US5633217A (en) 1994-09-12 1997-05-27 Corning Incorporated Method of making a high strength catalyst, catalyst support or adsorber
FR2743507B1 (fr) 1996-01-16 1998-03-06 Air Liquide Procede pour la separation de melanges d'oxygene et d'azote utilisant un adsorbant a porosite amelioree
FR2766476B1 (fr) 1997-07-22 1999-09-03 Ceca Sa Adsorbant zeolitique ameliore pour la separation des gaz de l'air et son procede d'obtention
US6500234B1 (en) 1998-02-27 2002-12-31 Praxair Technology, Inc. Rate-enhanced gas separation
AU2792899A (en) 1998-02-27 1999-09-15 Praxair Technology, Inc. Advanced adsorbent for psa
US6171370B1 (en) 1998-03-04 2001-01-09 Tosoh Corporation Adsorbent for separating gases
DE19826209A1 (de) 1998-06-08 1999-12-09 Grace Gmbh Formkörper aus Zeolith, Verfahren zu seiner Herstellung und dessen Verwendung
ES2284246T3 (es) 1998-03-31 2007-11-01 GRACE GMBH & CO. KG Zeolitas de estructura compacta, un proceso para su produccion y uso.
FR2792850B1 (fr) 1999-04-29 2001-07-13 Air Liquide Adsorbant a macroporosite elevee utilisable dans un procede d'adsorption de gaz, notamment un procede psa
KR20020080357A (ko) * 1999-12-29 2002-10-23 코닝 인코포레이티드 고강도 및 고표면적 촉매, 촉매 지지체 또는 흡착제조성물
US6790260B2 (en) 2000-12-20 2004-09-14 Praxair Technology, Inc. Enhanced rate PSA process
AU2002246964A1 (en) 2001-01-05 2002-09-04 Questair Technologies, Inc. Adsorbent coating compositions, laminates and adsorber elements comprising such compositions and methods for their manufacture and use
US20050119112A1 (en) 2002-01-22 2005-06-02 Zeochem, Llc Process for production of molecular sieve adsorbent blends
DE10219879A1 (de) 2002-05-03 2003-11-20 Basf Ag Katalysatorträger und Verfahren zu seiner Herstellung
FR2850963B1 (fr) 2003-02-11 2005-03-25 Ceca Sa Adsorbants agglomeres, leur procede de preparation et leur utilisation pour le sechage de composes organiques
DE102004029544A1 (de) 2004-06-18 2006-01-05 Basf Ag Formkörper enthaltend ein mikroporöses Material und mindestens ein siliciumhaltiges Bindemittel, Verfahren zu seiner Herstellung und seine Verwendung als Katalysator, insbesondere in einem Verfahren zur Herstellung von Triethylendiamin (TEDA)
ATE490232T1 (de) * 2004-06-18 2010-12-15 Basf Se Verfahren zur kontinuierlichen synthese von methylaminen
US7572749B2 (en) * 2004-08-31 2009-08-11 Exxonmobil Research And Engineering Company Structured bodies with siliceous binder
ES2761656T3 (es) 2007-03-08 2020-05-20 Praxair Technology Inc Adsorbentes de alta velocidad y alta resistencia al aplastamiento
US20120118160A1 (en) 2007-06-27 2012-05-17 Heffes Ruth G Attrition resistant hardened zeolite materials for air filtration media
DE102008046155B4 (de) 2008-03-03 2017-01-26 Chemiewerk Bad Köstritz GmbH Verfahren zur Herstellung eines Adsorptionsmittelgranulates
US8680344B2 (en) * 2011-01-25 2014-03-25 Zeochem Llc Molecular sieve adsorbent blends and uses thereof
US8728218B2 (en) * 2011-09-15 2014-05-20 Corning Incorporated Sorbent substrates for CO2 capture and methods for forming the same
US9533280B2 (en) * 2012-06-22 2017-01-03 Praxair Technology, Inc. High rate compositions

Also Published As

Publication number Publication date
CN104364008A (zh) 2015-02-18
US9486732B2 (en) 2016-11-08
BR112014032145A2 (pt) 2017-06-27
KR20150028240A (ko) 2015-03-13
MX376182B (es) 2025-03-07
IN2014DN09620A (enExample) 2015-07-31
US9050582B2 (en) 2015-06-09
KR102141723B1 (ko) 2020-08-05
MX2014016112A (es) 2015-09-21
CA2875103A1 (en) 2013-12-27
CA2875103C (en) 2021-06-22
US20130340615A1 (en) 2013-12-26
CN104364008B (zh) 2017-11-17
WO2013192435A1 (en) 2013-12-27
US20150231553A1 (en) 2015-08-20

Similar Documents

Publication Publication Date Title
BR112014032145B1 (pt) composição adsorvente tratada termicamente, e usada em processos de adsorção e separação de gás, processo de adsorção para separar n2 de uma mistura de gás contendo n2, e, método para fabricar uma composição adsorvente aglomerada
JP6615898B2 (ja) 大きな外部表面積を有するゼオライト吸着剤および当該ゼオライト吸着剤の使用
US8123835B2 (en) High rate and high crush-strength adsorbents
BR112020015541B1 (pt) Adsorvente compósito de núcleo-cápsula para uso na separação de gases de batelada, e processo de separação de gás cíclico
US9555401B2 (en) Molecular sieve adsorbent blends and uses thereof
WO2012103055A2 (en) Molecular sieve adsorbent blends and uses thereof
TW201438807A (zh) 具有穩定吸附活性的ｄｄｒ型沸石
CN110267739B (zh) 可调吸附剂
EP2864040A1 (en) Novel adsorbent compositions
EP3010638B1 (en) Molecular sieve adsorbent blends and uses thereof
CN117164869A (zh) 一种多孔锰基金属有机框架材料的制备方法、应用
TW524718B (en) Method for the separation of molecules in the gas phase by adsorption by means of agglomerated solid inorganic adsorbents with a narrow and calibrated mesopore distribution
JP2022529646A (ja) アルミニウム置換型ｃｉｔ－１５、その合成及び使用
WO2014176002A1 (en) Zeolitic adsorbents for use in adsorptive separation processes and methods for manufacturing the same
CN115991487B (zh) Zsm-5分子筛及其制备方法和应用
JP2000210557A (ja) Ｘ型ゼオライト含有成形体及びその製造方法並びにその用途
Khongkliang et al. Development of Zeolite Adsorbent Efficiency Using Amine Solution for Carbon Dioxide Capture Technology
BR112019016419B1 (pt) Método para reduzir o tamanho da abertura de poro de um adsorvente inorgânico cristalino, adsorvente de zeólita, e, processo de adsorção para adsorção ou separação de um primeiro componente adsorvível de uma mistura gasosa

Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 20/06/2013, OBSERVADAS AS CONDICOES LEGAIS.