BR112013026816A2 - processo de hidropirólise catalítica de leito borbulhante que utiliza partículas maiores de catalisador e partículas menores de biomassa que apresenta um reator antifluidização - Google Patents

processo de hidropirólise catalítica de leito borbulhante que utiliza partículas maiores de catalisador e partículas menores de biomassa que apresenta um reator antifluidização

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Publication number
BR112013026816A2
BR112013026816A2 BR112013026816A BR112013026816A BR112013026816A2 BR 112013026816 A2 BR112013026816 A2 BR 112013026816A2 BR 112013026816 A BR112013026816 A BR 112013026816A BR 112013026816 A BR112013026816 A BR 112013026816A BR 112013026816 A2 BR112013026816 A2 BR 112013026816A2
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Brazil
Prior art keywords
reactor
bed
particles
catalyst particles
antifluidization
Prior art date
Application number
BR112013026816A
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English (en)
Other versions
BR112013026816B1 (pt
Inventor
Larry G Felix
Martin B Linck
Michael J Roberts
Terry L Marker
Original Assignee
Gas Technology Inst
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Publication date
Application filed by Gas Technology Inst filed Critical Gas Technology Inst
Publication of BR112013026816A2 publication Critical patent/BR112013026816A2/pt
Publication of BR112013026816B1 publication Critical patent/BR112013026816B1/pt

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    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
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    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/34—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with stationary packing material in the fluidised bed, e.g. bricks, wire rings, baffles
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    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
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    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
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    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/02—Combustion or pyrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
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Abstract

processo de hidropirólise catalítica de leito borbulhante que utiliza partículas maiores de catalisador e partículas menores de biomassa que apresenta um reator antifluidização trata-se de um processo para transformar de forma termoquímica a biomassa ou outras matérias-primas oxigenadas em combustíveis de hidrocarbonetos líquidos de alta qualidade. em particular, um reator de hidropirólise catalítica, que contém um leito profundo de partículas de catalisador fluidizdo é utilizado para aceitar as partículas de biomassa ou outras mátérias-primas oxigenadas que são significativamente menores que as partículas de catalisador no leito fluidizado. o reator dispõe de um elemento de inserção ou outra estrutura disposta no interior do recipiente de reator que inibe a fluidização do leito e, consequentemente, minimiza o atrito do catalisador. dentro do leito, a matéria-prima de biomassa é convertida em um produto de fase em vapor que contém as moléculas de hdirocarboneto e outros vapores de processo, e um produto de carvão vegetal sólido arrastado, que é separado do fluxo de vapor depois que o fluxo de vapor foi esgotado a partir do topo do reator. quando o fluxo de vapor do produto é resfriado para as temperaturas ambiente, uma proporção significativa dos hidrocarbonetos no fluxo de vapor do produto pode ser recuperada como um fluxo de líquido de hidrocarbonetos hidrofóbicos com as proprieddes consistentes àquelas de gasolina, querosene e combustível diesel. a separação dos fluxos de gasolina, querosene e combustível diesel também pode ser obtida ou através da condensação seletiva de cada tipo de combustível, ou através da destilação do líquido de hidrocarboneto combinado.
BR112013026816-6A 2011-04-18 2012-03-23 método para hidropirolisar uma matéria-prima orgânica oxigenada BR112013026816B1 (pt)

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US13/089,010 US8841495B2 (en) 2011-04-18 2011-04-18 Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor
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