BR112013015532B1 - ácido 2-(alcóxi ou ariloxicarbonil)-4-metil-6-(2,6,6-trimetilcicloex-1-enil)-hex-2-enoico, metódo para sua preparação e seus usos - Google Patents

ácido 2-(alcóxi ou ariloxicarbonil)-4-metil-6-(2,6,6-trimetilcicloex-1-enil)-hex-2-enoico, metódo para sua preparação e seus usos Download PDF

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Publication number
BR112013015532B1
BR112013015532B1 BR112013015532A BR112013015532A BR112013015532B1 BR 112013015532 B1 BR112013015532 B1 BR 112013015532B1 BR 112013015532 A BR112013015532 A BR 112013015532A BR 112013015532 A BR112013015532 A BR 112013015532A BR 112013015532 B1 BR112013015532 B1 BR 112013015532B1
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BR
Brazil
Prior art keywords
trimethylcycloex
aryloxycarbonyl
enyl
hex
alkoxy
Prior art date
Application number
BR112013015532A
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English (en)
Other versions
BR112013015532A2 (pt
Inventor
Jof Schröder Fridt
Daniel Oetiker Jürg
Mueller Urs
Original Assignee
Givaudan Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Givaudan Sa filed Critical Givaudan Sa
Publication of BR112013015532A2 publication Critical patent/BR112013015532A2/pt
Publication of BR112013015532B1 publication Critical patent/BR112013015532B1/pt

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D307/92—Naphthofurans; Hydrogenated naphthofurans
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/20—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by carboxyl groups or halides, anhydrides, or (thio)esters thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C07C51/38—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by decarboxylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/26—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C07C67/32—Decarboxylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/475—Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/608—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a ring other than a six-membered aromatic ring in the acid moiety
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
    • C07C2602/48—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing ten carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Furan Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Fats And Perfumes (AREA)

Abstract

ácido 2-(alcóxi ou ariloxicarbonil)- 4-metil-6-(2,6,6-trimetilcicloex-1-enil)-hex-2-enoico, metódo para sua preparação e seus usos a presente invenção se refere a compostos de fórmula (1) na qual r é hidrogênio, alquila ou alquila substituída, arila ou arila substituída, compostos estes que são intermediários úteis na síntese de ingredientes de fragrâncias, tal como ambrox (2).
BR112013015532A 2010-12-21 2011-12-21 ácido 2-(alcóxi ou ariloxicarbonil)-4-metil-6-(2,6,6-trimetilcicloex-1-enil)-hex-2-enoico, metódo para sua preparação e seus usos BR112013015532B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB201021584A GB201021584D0 (en) 2010-12-21 2010-12-21 Organic compounds
PCT/EP2011/073550 WO2012085056A1 (en) 2010-12-21 2011-12-21 2-(alkoxy or aryloxy carbonyl)-4-methyl-6-(2,6,6-trimethylcyclohex-1-enyl)hex-2-enoic acid compounds, its preparation and use

Publications (2)

Publication Number Publication Date
BR112013015532A2 BR112013015532A2 (pt) 2016-09-20
BR112013015532B1 true BR112013015532B1 (pt) 2020-04-28

Family

ID=43598678

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013015532A BR112013015532B1 (pt) 2010-12-21 2011-12-21 ácido 2-(alcóxi ou ariloxicarbonil)-4-metil-6-(2,6,6-trimetilcicloex-1-enil)-hex-2-enoico, metódo para sua preparação e seus usos

Country Status (10)

Country Link
US (4) US8933253B2 (pt)
EP (1) EP2655325B1 (pt)
JP (1) JP6000277B2 (pt)
CN (1) CN103298783B (pt)
BR (1) BR112013015532B1 (pt)
ES (1) ES2676368T3 (pt)
GB (1) GB201021584D0 (pt)
MX (1) MX338663B (pt)
SG (1) SG190846A1 (pt)
WO (1) WO2012085056A1 (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201021584D0 (en) * 2010-12-21 2011-02-02 Givaudan Sa Organic compounds
CN104557543B (zh) 2013-10-21 2017-04-12 芬芳香精香料有限公司 制备不饱和酯的方法
TWI527805B (zh) 2014-08-12 2016-04-01 國立臺灣大學 由紅果椌木半日花烷製備降龍涎香醚及由紅果椌木製備新穎二萜類化合物
CN107428662B (zh) * 2015-03-11 2021-04-23 国际香料和香精公司 用于制备不饱和丙二酸酯的方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3240054A1 (de) 1982-10-28 1984-05-03 Consortium für elektrochemische Industrie GmbH, 8000 München Verfahren zur herstellung von 8.12-epoxy-13.14.15.16-tetranorlabdan
JPS60239481A (ja) 1984-05-14 1985-11-28 T Hasegawa Co Ltd （±）−アンブロツクスの製法及びその利用
DE59203733D1 (de) 1991-08-02 1995-10-26 Givaudan Roure Int Verfahren zur Herstellung von substituierten Hexensäuren.
US5290955A (en) 1991-12-29 1994-03-01 Kuraray Co., Ltd. Process for producing L-ambrox
GB0417063D0 (en) 2004-07-30 2004-09-01 Givaudan Sa Process for the preparation of optically-active compounds
WO2007096791A1 (en) 2006-02-23 2007-08-30 Firmenich Sa Process for the preparation of beta-gamma ene carbonyl derivatives
CN101490027B (zh) * 2006-07-31 2011-08-03 花王株式会社 (±)-3a,6,6,9a-四甲基十氢萘并[2,1-b]呋喃-2(1H)-酮类的制造方法
CN101827835B (zh) * 2007-10-23 2013-07-17 弗门尼舍有限公司 去四甲基赖百当烷衍生物的制备方法
GB0922204D0 (en) * 2009-12-18 2010-02-03 Givaudan Sa Organic Compounds
GB201021584D0 (en) * 2010-12-21 2011-02-02 Givaudan Sa Organic compounds

Also Published As

Publication number Publication date
JP6000277B2 (ja) 2016-09-28
US20140275578A1 (en) 2014-09-18
SG190846A1 (en) 2013-07-31
JP2014502964A (ja) 2014-02-06
CN103298783B (zh) 2016-05-11
US10081613B2 (en) 2018-09-25
US20160002192A1 (en) 2016-01-07
CN103298783A (zh) 2013-09-11
US20170305875A1 (en) 2017-10-26
GB201021584D0 (en) 2011-02-02
BR112013015532A2 (pt) 2016-09-20
US20150094476A1 (en) 2015-04-02
MX338663B (es) 2016-04-27
WO2012085056A1 (en) 2012-06-28
ES2676368T3 (es) 2018-07-19
US8933253B2 (en) 2015-01-13
EP2655325A1 (en) 2013-10-30
US9163000B2 (en) 2015-10-20
US9732056B2 (en) 2017-08-15
EP2655325B1 (en) 2018-04-18
MX2013006035A (es) 2013-08-01

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B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

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B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

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