BR112012005692B1 - Polímero compreendendo um siloxano, composição e artigo - Google Patents
Polímero compreendendo um siloxano, composição e artigo Download PDFInfo
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- BR112012005692B1 BR112012005692B1 BR112012005692-1A BR112012005692A BR112012005692B1 BR 112012005692 B1 BR112012005692 B1 BR 112012005692B1 BR 112012005692 A BR112012005692 A BR 112012005692A BR 112012005692 B1 BR112012005692 B1 BR 112012005692B1
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- Prior art keywords
- polymer
- ethylene
- siloxane
- polymers
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- 229920000642 polymer Polymers 0.000 title claims abstract description 248
- 239000000203 mixture Substances 0.000 title claims abstract description 68
- -1 SILOXAN Chemical class 0.000 title claims description 104
- 239000005977 Ethylene Substances 0.000 claims abstract description 117
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 116
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims abstract description 58
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 17
- 238000005481 NMR spectroscopy Methods 0.000 claims abstract description 16
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims abstract description 11
- 229920000573 polyethylene Polymers 0.000 claims description 33
- 239000004698 Polyethylene Substances 0.000 claims description 31
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 230000004927 fusion Effects 0.000 claims description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- 238000000638 solvent extraction Methods 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 2
- 238000000034 method Methods 0.000 description 78
- 230000008569 process Effects 0.000 description 53
- 238000006243 chemical reaction Methods 0.000 description 50
- 229920001684 low density polyethylene Polymers 0.000 description 42
- 229920001296 polysiloxane Polymers 0.000 description 42
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- 239000004702 low-density polyethylene Substances 0.000 description 39
- 239000000523 sample Substances 0.000 description 38
- 150000003254 radicals Chemical class 0.000 description 33
- 239000004205 dimethyl polysiloxane Substances 0.000 description 32
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 32
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- 239000003054 catalyst Substances 0.000 description 24
- 230000000052 comparative effect Effects 0.000 description 22
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- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 16
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- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 10
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
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- 238000010526 radical polymerization reaction Methods 0.000 description 7
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- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
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- NALFRYPTRXKZPN-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane Chemical compound CC1CC(C)(C)CC(OOC(C)(C)C)(OOC(C)(C)C)C1 NALFRYPTRXKZPN-UHFFFAOYSA-N 0.000 description 3
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical group ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
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- HSLFISVKRDQEBY-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)cyclohexane Chemical compound CC(C)(C)OOC1(OOC(C)(C)C)CCCCC1 HSLFISVKRDQEBY-UHFFFAOYSA-N 0.000 description 2
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- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- HTCRKQHJUYBQTK-UHFFFAOYSA-N 2-ethylhexyl 2-methylbutan-2-yloxy carbonate Chemical compound CCCCC(CC)COC(=O)OOC(C)(C)CC HTCRKQHJUYBQTK-UHFFFAOYSA-N 0.000 description 2
- RFSCGDQQLKVJEJ-UHFFFAOYSA-N 2-methylbutan-2-yl benzenecarboperoxoate Chemical compound CCC(C)(C)OOC(=O)C1=CC=CC=C1 RFSCGDQQLKVJEJ-UHFFFAOYSA-N 0.000 description 2
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- 210000003411 telomere Anatomy 0.000 description 1
- 102000055501 telomere Human genes 0.000 description 1
- 108091035539 telomere Proteins 0.000 description 1
- KQYLUTYUZIVHND-UHFFFAOYSA-N tert-butyl 2,2-dimethyloctaneperoxoate Chemical compound CCCCCCC(C)(C)C(=O)OOC(C)(C)C KQYLUTYUZIVHND-UHFFFAOYSA-N 0.000 description 1
- WYKYCHHWIJXDAO-UHFFFAOYSA-N tert-butyl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)C WYKYCHHWIJXDAO-UHFFFAOYSA-N 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- VSJBBIJIXZVVLQ-UHFFFAOYSA-N tert-butyl 3,5,5-trimethylhexaneperoxoate Chemical compound CC(C)(C)CC(C)CC(=O)OOC(C)(C)C VSJBBIJIXZVVLQ-UHFFFAOYSA-N 0.000 description 1
- NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 1
- 229940124543 ultraviolet light absorber Drugs 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000004260 weight control Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
- C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2351/08—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Graft Or Block Polymers (AREA)
- Silicon Polymers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US24212709P | 2009-09-14 | 2009-09-14 | |
| US61/242,127 | 2009-09-14 | ||
| PCT/US2010/048818 WO2011032172A1 (en) | 2009-09-14 | 2010-09-14 | Polymers comprising units derived from ethylene and siloxane |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112012005692A2 BR112012005692A2 (pt) | 2020-10-13 |
| BR112012005692B1 true BR112012005692B1 (pt) | 2021-07-27 |
Family
ID=42985625
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112012005692-1A BR112012005692B1 (pt) | 2009-09-14 | 2010-09-14 | Polímero compreendendo um siloxano, composição e artigo |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8691923B2 (OSRAM) |
| EP (1) | EP2478025B1 (OSRAM) |
| JP (1) | JP5764561B2 (OSRAM) |
| KR (1) | KR101715435B1 (OSRAM) |
| CN (1) | CN102695735B (OSRAM) |
| BR (1) | BR112012005692B1 (OSRAM) |
| CA (1) | CA2773325A1 (OSRAM) |
| ES (1) | ES2711958T3 (OSRAM) |
| SG (1) | SG179053A1 (OSRAM) |
| WO (1) | WO2011032172A1 (OSRAM) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9243087B2 (en) | 2009-06-11 | 2016-01-26 | Dow Global Technologies Llc | LDPE enabling high output and good optics when blended with other polymers |
| KR101869997B1 (ko) | 2010-12-03 | 2018-06-22 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌-기재 중합체 조성물의 제조 방법 |
| WO2013038426A1 (en) * | 2011-09-13 | 2013-03-21 | V.K.A. Polymers Private Limited | Insecticides incorporated controlled release polymer fabrics for pest control |
| EP3412455A1 (en) | 2017-06-09 | 2018-12-12 | Dow Global Technologies Llc | Low coefficient of friction ethylene-based compositions |
| WO2019023008A1 (en) | 2017-07-25 | 2019-01-31 | Dow Silicones Corporation | PROCESS FOR THE PREPARATION OF A GRAFT COPOLYMER HAVING A POLYOLEFIN SKELETON AND POLYORGANOSILOXANE PENDANT GROUPS |
| US12037462B2 (en) | 2018-03-19 | 2024-07-16 | Dow Global Technologies Llc | Polyolefin-polydiorganosiloxane block copolymer and method for the synthesis thereof |
| JP2021518460A (ja) * | 2018-03-19 | 2021-08-02 | ダウ シリコーンズ コーポレーション | ポリオレフィン−ポリジオルガノシロキサンコポリマーを含有するホットメルト接着剤組成物ならびにその調製方法および使用方法 |
| JP7263381B2 (ja) | 2018-03-19 | 2023-04-24 | ダウ シリコーンズ コーポレーション | ポリオレフィン－ポリジオルガノオシロキサン（ｐｏｌｙｄｉｏｒｇａｎｏｏｓｉｌｏｘａｎｅ）コポリマーを含有するポリオルガノシロキサンホットメルト接着剤組成物ならびにそれを調製および使用するための方法 |
| WO2019182721A1 (en) | 2018-03-19 | 2019-09-26 | Dow Silicones Corporation | Polyolefin-polydiorganosiloxane block copolymer and hydrosilylaton reaction method for the synthesis thereof |
| US11702512B2 (en) | 2018-07-17 | 2023-07-18 | Dow Silicones Corporation | Polysiloxane resin-polyolefin copolymer and methods for the preparation and use thereof |
| KR20220162144A (ko) * | 2020-03-31 | 2022-12-07 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리올레핀 제조를 위한 사슬 이동제로서의 치환된 실란 |
| EP3970760B1 (en) | 2020-09-16 | 2024-05-29 | Dow Global Technologies LLC | Feminine hygiene articles and films suitable for use in such |
| WO2022060988A1 (en) | 2020-09-16 | 2022-03-24 | Dow Global Technologies Llc | Copolymers of ethylene with (meth) acrylic ester functionalized polysiloxane |
| BR112023004616A2 (pt) * | 2020-09-16 | 2023-04-11 | Dow Global Technologies Llc | Espuma extrudada |
| CN116323771A (zh) | 2020-10-30 | 2023-06-23 | 陶氏环球技术有限责任公司 | 包含硅氧烷官能化聚乙烯和低密度聚乙烯的共混物的泡沫 |
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| US3573334A (en) * | 1964-04-02 | 1971-03-30 | Union Carbide Corp | Olefinic silicone-organic polymer graft copolymers |
| US3462249A (en) | 1967-03-31 | 1969-08-19 | Exxon Research Engineering Co | Fuel oil compositions containing grafted polymers |
| US3485706A (en) | 1968-01-18 | 1969-12-23 | Du Pont | Textile-like patterned nonwoven fabrics and their production |
| JPS5410590B1 (OSRAM) | 1970-04-18 | 1979-05-08 | ||
| US4178951A (en) | 1978-10-10 | 1979-12-18 | Texaco Inc. | Low pour point crude oil compositions |
| US4340563A (en) | 1980-05-05 | 1982-07-20 | Kimberly-Clark Corporation | Method for forming nonwoven webs |
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| US4413110A (en) | 1981-04-30 | 1983-11-01 | Allied Corporation | High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore |
| DE3240383A1 (de) | 1982-11-02 | 1984-05-03 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von oligomeren aluminoxanen |
| US4599392A (en) | 1983-06-13 | 1986-07-08 | The Dow Chemical Company | Interpolymers of ethylene and unsaturated carboxylic acids |
| US4663220A (en) | 1985-07-30 | 1987-05-05 | Kimberly-Clark Corporation | Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers |
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| JPH0491217A (ja) | 1990-07-27 | 1992-03-24 | Mitsui Toatsu Chem Inc | ポリオレフィン製モノフィラメント |
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| DE60335459D1 (de) | 2002-04-24 | 2011-02-03 | Symyx Solutions Inc | Verbrückte bi-aromatische liganden, komplexe, katalysatoren, verfahren zur polymerisierung und entstehende polymere |
| US6797779B1 (en) | 2003-03-28 | 2004-09-28 | The Goodyear Tire & Rubber Company | Thermoplastic composition |
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| JP5133050B2 (ja) | 2004-03-17 | 2013-01-30 | ダウ グローバル テクノロジーズ エルエルシー | エチレンマルチブロックコポリマーを形成するためのシャトリング剤を含む触媒組成物 |
| US7728094B2 (en) * | 2005-05-03 | 2010-06-01 | Imec | Selfassembled grafted polymeric layer for use in biosensor technology |
| CN101472952B (zh) | 2006-05-17 | 2012-10-03 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃/二烯溶液聚合法 |
| WO2009114661A1 (en) | 2008-03-13 | 2009-09-17 | Dow Global Technologies Inc. | Long chain branched (lcb), block or interconnected copolymers of ethylene in combination with one other polymer |
| US8722817B2 (en) | 2009-06-05 | 2014-05-13 | Dow Global Technologies Llc | Process to make long chain branched (LCB), block, or interconnected copolymers of ethylene |
| CN102459357B (zh) | 2009-06-05 | 2013-07-31 | 陶氏环球技术有限责任公司 | 制备乙烯的长链支化的(lcb)嵌段共聚物或互连共聚物的方法 |
| US9243087B2 (en) | 2009-06-11 | 2016-01-26 | Dow Global Technologies Llc | LDPE enabling high output and good optics when blended with other polymers |
| WO2011019563A1 (en) | 2009-08-10 | 2011-02-17 | Dow Global Technologies Inc. | Ldpe for use as a blend component in shrinkage film applications |
| US20110196105A1 (en) | 2010-02-08 | 2011-08-11 | Dow Global Technologies Inc. | Novel high pressure, low density polyethylene resins produced through the use of highly active chain transfer agents |
-
2010
- 2010-09-14 EP EP10757894.0A patent/EP2478025B1/en active Active
- 2010-09-14 BR BR112012005692-1A patent/BR112012005692B1/pt active IP Right Grant
- 2010-09-14 CA CA2773325A patent/CA2773325A1/en not_active Abandoned
- 2010-09-14 SG SG2012016457A patent/SG179053A1/en unknown
- 2010-09-14 ES ES10757894T patent/ES2711958T3/es active Active
- 2010-09-14 US US13/394,675 patent/US8691923B2/en active Active
- 2010-09-14 CN CN201080051438.2A patent/CN102695735B/zh active Active
- 2010-09-14 JP JP2012528998A patent/JP5764561B2/ja active Active
- 2010-09-14 KR KR1020127009442A patent/KR101715435B1/ko active Active
- 2010-09-14 WO PCT/US2010/048818 patent/WO2011032172A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP2478025B1 (en) | 2018-12-05 |
| BR112012005692A2 (pt) | 2020-10-13 |
| KR101715435B1 (ko) | 2017-03-10 |
| EP2478025A1 (en) | 2012-07-25 |
| ES2711958T3 (es) | 2019-05-08 |
| WO2011032172A1 (en) | 2011-03-17 |
| CN102695735B (zh) | 2014-11-05 |
| KR20120083403A (ko) | 2012-07-25 |
| JP5764561B2 (ja) | 2015-08-19 |
| JP2013504665A (ja) | 2013-02-07 |
| US8691923B2 (en) | 2014-04-08 |
| CA2773325A1 (en) | 2011-03-17 |
| CN102695735A (zh) | 2012-09-26 |
| US20120172545A1 (en) | 2012-07-05 |
| SG179053A1 (en) | 2012-04-27 |
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Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 14/09/2010, OBSERVADAS AS CONDICOES LEGAIS. PATENTE CONCEDIDA CONFORME ADI 5.529/DF, QUE DETERMINA A ALTERACAO DO PRAZO DE CONCESSAO. |