BR0317845A - Processos para a transição entre vários catalisadores de polimerização - Google Patents

Processos para a transição entre vários catalisadores de polimerização

Info

Publication number
BR0317845A
BR0317845A BR0317845-5A BR0317845A BR0317845A BR 0317845 A BR0317845 A BR 0317845A BR 0317845 A BR0317845 A BR 0317845A BR 0317845 A BR0317845 A BR 0317845A
Authority
BR
Brazil
Prior art keywords
transition
processes
various polymerization
polymerization catalysts
systems
Prior art date
Application number
BR0317845-5A
Other languages
English (en)
Other versions
BR0317845B1 (pt
Inventor
Mark G Goode
Ian Burdett
Ping P Cai
Ronald E Eisinger
F David Hussein
Michael A Kinnan
Michael E Muhle
James L Swecker
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Publication of BR0317845A publication Critical patent/BR0317845A/pt
Publication of BR0317845B1 publication Critical patent/BR0317845B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1872—Details of the fluidised bed reactor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/05—Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

"PROCESSOS PARA A TRANSIçãO ENTRE VáRIOS CATALISADORES DE POLIMERIZAçãO". A presente invenção refere-se a processos para a transição entre sistemas catalíticos de polimerização, de preferência sistemas catalíticos, que são incompatíveis entre si. Particularmente, a invenção refere-se a processos para a transição entre reações de polimerização de olefinas utilizando sistemas catalíticos de Ziegler-Natta, sistemas catalíticos de metaloceno e sistemas catalíticos à base de cromo.
BRPI0317845-5B1A 2002-12-30 2003-12-03 Processo para a transição de uma primeira reação de polimerização conduzida na presença de um primeiro sistema catalítico para uma segunda reação de polimerização conduzida na presença de um segundo sistema catalítico BR0317845B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US43709102P 2002-12-30 2002-12-30
US10/716,041 US6858684B2 (en) 2002-12-30 2003-11-17 Processes for transitioning between various polymerization catalysts
PCT/US2003/038269 WO2004060921A2 (en) 2002-12-30 2003-12-03 Processes for transitioning between various polymerization catalysts

Publications (2)

Publication Number Publication Date
BR0317845A true BR0317845A (pt) 2005-12-06
BR0317845B1 BR0317845B1 (pt) 2013-11-12

Family

ID=32717878

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0317845-5B1A BR0317845B1 (pt) 2002-12-30 2003-12-03 Processo para a transição de uma primeira reação de polimerização conduzida na presença de um primeiro sistema catalítico para uma segunda reação de polimerização conduzida na presença de um segundo sistema catalítico

Country Status (8)

Country Link
US (1) US6858684B2 (pt)
EP (1) EP1578808B1 (pt)
JP (1) JP4143608B2 (pt)
AU (1) AU2003298813A1 (pt)
BR (1) BR0317845B1 (pt)
CA (1) CA2508761C (pt)
DE (1) DE60324463D1 (pt)
WO (1) WO2004060921A2 (pt)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1328310C (zh) * 2004-11-05 2007-07-25 中国科学院化学研究所 聚烯烃复合材料及其制备方法
US7629422B2 (en) * 2004-12-21 2009-12-08 Univation Technologies, Llc Process for transitioning between Ziegler-Natta-based and chromium-based catalysts
US8513366B2 (en) * 2005-03-17 2013-08-20 University Of Maryland, College Park Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby
EP1767549A1 (en) 2005-09-20 2007-03-28 Ineos Europe Limited Polymerisation catalysts
US20070270558A1 (en) * 2006-05-16 2007-11-22 Paul Keith Scherrer Pulsing olefin polymerization fluidized-bed reactors
CN101965371B (zh) * 2007-12-31 2015-09-23 陶氏环球技术有限责任公司 用于聚合基于烯烃的聚合物的方法
DE102008056694A1 (de) * 2008-11-11 2010-05-12 Mitsubishi Polyester Film Gmbh Biaxial gestreckte Polyesterfolie die einen Kettenverlängerer enthält, sowie Verfahren zu ihrer Herstellung und ihre Verwendung
CN102264773B (zh) * 2008-12-23 2013-12-04 巴塞尔聚烯烃股份有限公司 不相容的烯烃聚合催化剂体系之间转变的方法
PT2387590E (pt) 2009-12-18 2013-04-23 Total Res & Technology Feluy Método para a susbtituição de catalisadores de polimerização de etileno compatíveis
US8598283B2 (en) 2010-02-18 2013-12-03 Univation Technologies, Llc Methods for operating a polymerization reactor
EP2383301A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
EP2383298A1 (en) † 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
US9433914B2 (en) 2013-12-20 2016-09-06 Chevron Phillips Chemical Company, Lp Polyolefin reactor system having a gas phase reactor
US9914794B2 (en) 2014-05-27 2018-03-13 Sabic Global Technologies B.V. Process for transitioning between incompatible catalysts
EA032875B1 (ru) 2014-12-22 2019-07-31 Сабик Глоубл Текнолоджиз Б.В. Способ перехода между несовместимыми катализаторами
KR20170109548A (ko) 2014-12-22 2017-09-29 사빅 글로벌 테크놀러지스 비.브이. 비융화성 촉매 간의 전환 방법
WO2016151098A1 (en) 2015-03-24 2016-09-29 Sabic Global Technologies B.V. Process for transitioning between incompatible catalysts
SG11201708069UA (en) 2015-04-08 2017-10-30 Univation Tech Llc Closed reactor transitions between metallocene catalysts
CN108699168B (zh) 2015-12-22 2021-04-27 Sabic环球技术有限责任公司 用于不相容催化剂之间转换的方法
JP6743463B2 (ja) 2016-04-12 2020-08-19 住友化学株式会社 ポリオレフィンの製造方法
US10023666B2 (en) 2016-12-13 2018-07-17 Chevron Phillips Chemical Company Lp Process for transitioning between low percentage chrome and high percentage chrome catalysts
SG11202103831TA (en) 2018-11-06 2021-05-28 Dow Global Technologies Llc Alkane-soluble non-metallocene precatalysts
SG11202104262XA (en) 2018-11-06 2021-05-28 Dow Global Technologies Llc Method of olefin polymerization using alkane-soluble non-metallocene precatalyst
EP3877391B1 (en) 2018-11-06 2023-11-15 Dow Global Technologies LLC Alkane-soluble non-metallocene precatalysts
CN114426590A (zh) * 2020-09-28 2022-05-03 中国石油化工股份有限公司 一种茂金属催化剂与Ziegler-Natta催化剂的在线切换方法
EP4389783A1 (en) 2022-12-20 2024-06-26 Borealis AG Catalyst transition process
CN117567675B (zh) * 2024-01-16 2024-04-23 新疆独山子石油化工有限公司 一种铬系聚乙烯转产茂金属聚乙烯的生产方法

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2966150D1 (en) * 1978-03-23 1983-10-20 Ici Plc Gas-phase olefin polymerisation system and process for operating it
US4460755A (en) * 1982-09-30 1984-07-17 Union Carbide Corporation Direct conversion of a polymerization reaction catalyzed by a Ziegler-type catalyst into one catalyzed by a chromium-based catalyst
DE3305782A1 (de) 1983-02-19 1984-08-30 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur polymerisation und copolymerisation von ethylen
US4834947A (en) * 1983-09-01 1989-05-30 Mobil Oil Corporation Reactor system for rapid kill gas injection to gas phase polymerization reactors
JPS60245603A (ja) * 1984-05-21 1985-12-05 Idemitsu Petrochem Co Ltd α−オレフインの多段気相重合法
US4701489A (en) * 1986-09-08 1987-10-20 El Paso Products Company Process for the production of stable noncorrosive amorphous polyalphaolefins
US5118757A (en) * 1990-03-26 1992-06-02 Shell Oil Company Polymer production
JP2875361B2 (ja) * 1990-07-13 1999-03-31 日本石油化学株式会社 気相重合流動床の床高さ制御方法
US5204751A (en) 1990-08-17 1993-04-20 Hughes Display Products Target support for projection cathode ray tube
GB9103527D0 (en) 1991-02-20 1991-04-10 Exxon Chemical Patents Inc Hp catalyst killer
US5227438A (en) * 1991-09-24 1993-07-13 Union Carbide Chemicals & Plastics Technology Corporation Process for the slowdown or termination of polymerization
US5270408A (en) * 1992-01-29 1993-12-14 Union Carbide Chemicals & Plastics Technology Corporation Method and apparatus for stopping reaction in a gas phase polymerization reactor system
US5371053A (en) * 1993-05-18 1994-12-06 Exxon Chemical Patents Inc. Process for deactivating Ziegler-Natta and metallocene catalysts
US5442019A (en) * 1994-03-25 1995-08-15 Exxon Chemical Company Process for transitioning between incompatible polymerization catalysts
US5672666A (en) * 1995-06-05 1997-09-30 Exxon Chemical Patents Inc. Process for transitioning between incompatible polymerization catalysts
NO301331B1 (no) * 1996-03-05 1997-10-13 Borealis As Fremgangsmåte for skifting av katalysator ved suspensjonspolymerisasjon av olefiner
CZ170897A3 (en) * 1996-06-06 1997-12-17 Union Carbide Chem Plastic Control of static charge in the course of polymerization process during which metallocene catalyst is used
JP3836219B2 (ja) 1996-09-12 2006-10-25 三井化学株式会社 オレフィン気相重合の停止方法、オレフィン気相重合の開始方法およびオレフィンの気相重合装置
WO1998030599A1 (en) 1997-01-13 1998-07-16 Eastman Chemical Company Temporary idling of a polymerization reaction
WO1999003901A1 (en) * 1997-07-16 1999-01-28 Union Carbide Chemicals & Plastics Technology Corporation Low bed-level transition, start-up, and reactor residence time control using sound waves
EP0959081A1 (en) * 1998-05-19 1999-11-24 Bp Chemicals S.N.C. Gas phase polymerisation process
US6262190B1 (en) * 1999-02-10 2001-07-17 Union Carbide Chemicals & Plastics Technology Corporation Process and apparatus for fluid bed polymerization
SG82693A1 (en) * 1999-09-03 2001-08-21 Sumitomo Chemical Co Fluidized bed reactor for gas phase olefin polymerization, process for polymerizing olefin and process for producing olefin polymer
US6388027B1 (en) * 2000-10-24 2002-05-14 Union Carbide Chemicals & Plastics Technology Corporation Transition strategy for the production of sticky polymers

Also Published As

Publication number Publication date
DE60324463D1 (de) 2008-12-11
CA2508761C (en) 2009-09-29
EP1578808B1 (en) 2008-10-29
WO2004060921A3 (en) 2004-12-23
AU2003298813A1 (en) 2004-07-29
CA2508761A1 (en) 2004-07-22
JP2006512452A (ja) 2006-04-13
JP4143608B2 (ja) 2008-09-03
WO2004060921A2 (en) 2004-07-22
AU2003298813A8 (en) 2004-07-29
US20040138391A1 (en) 2004-07-15
BR0317845B1 (pt) 2013-11-12
EP1578808A4 (en) 2006-02-08
EP1578808A2 (en) 2005-09-28
US6858684B2 (en) 2005-02-22

Similar Documents

Publication Publication Date Title
BR0317845A (pt) Processos para a transição entre vários catalisadores de polimerização
BR0317851A (pt) Processos para realizar a transição entre catalisadores de polimerização baseados em cromo e mistos
BR0317830A (pt) Processos para efetuar transição entre catalisadores de polimerização metalocênicos e ziegler-natta
MX9709501A (es) Proceso para transicionar entre catalizadores de polimerizacion incompatibles.
ATE291030T1 (de) Substituierte metallocenverbindungen für olefinpolymerisationkatalysatorsystemen, deren zwischenverbindungen und verfahren zu ihrer herstellung
DE69737368D1 (de) Katalysatorkomponenten für die olefinpolymerisation, polymerisationskatalysatoren und verfharen zur olefinpolymerisierung unter verwendung derselben
BR9813438B1 (pt) processo para polimerizaÇço de olefinas, pelÍcula e polÍmero de etileno-alfa-olefina.
DE69914278D1 (de) Katalysatorbestandteile für die olefinpolymerisation
SG158099A1 (en) Metallocene catalysts, their synthesis and their use for the polymerization of olefins
DE69935137D1 (de) Polymerträgerkatalysatoren für olefinpolymerisation
ATE509962T1 (de) Vorpolymerisierte katalysatorbestandteile für die olefinpolymerisation
CA2338603A1 (en) Highly active supported catalyst compositions
AU2003257448A8 (en) Catalyst system for the polymerization of olefins
BR9506039A (pt) Componentes e catalisadores para a polímerização de olefinas
DE60021747D1 (de) Reaktor, insbesondere für exotherme reaktionen
DE69600532D1 (de) Komponente und Katalysatore für die Olefinpolymerisation
DE69828543D1 (de) Metallocenkatalysator und Katalysatorsystem für die Herstellung von Polypropylenemischungen aus iso- und syndiotaktischem Polypropylene
ATE232878T1 (de) Imidochromverbindungen in katalysatorsystemen für die olefinpolymerisation
NO20050092L (no) Gruppe 4 metallkomplekser inneholdende 4-aryl-substituerte trisykliske indenyl derivater
DE69823988D1 (de) Gruppe 8-10 übergangsmetallkatalysator für die polymerisation von olefinen
BR0312210A (pt) atividores e sistemas catalìticos heterocìclicos contendo nitrogênio para polimerização de olefina
DE69829644D1 (de) Katalysatorzusammensetzung für die olefinpolymerisation mit erhöhter aktivität
DE69903399D1 (de) Prepolymerisierte katalysatorkomponente für die polymerisierung von olefinen
DE69905011D1 (de) Bis(tetrahydro-indenyl) metallocene, und diesen enthaltende olefinpolymerisationskatalysatoren
DE69904521D1 (de) Verbrückte Zirconocene, deren Herstellung und deren Verwendung als Katalysatorkomponente für die Polymerisation von Olefinen

Legal Events

Date Code Title Description
B07A Technical examination (opinion): publication of technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 03/12/2003, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 15A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2494 DE 23-10-2018 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.