BR0312603A - Copolìmero em bloco estirênico radial ou um derivado hidrogenado do mesmo, método para preparar um copolìmero em bloco estirênico radial, e, betume modificado - Google Patents

Copolìmero em bloco estirênico radial ou um derivado hidrogenado do mesmo, método para preparar um copolìmero em bloco estirênico radial, e, betume modificado

Info

Publication number
BR0312603A
BR0312603A BR0312603-0A BR0312603A BR0312603A BR 0312603 A BR0312603 A BR 0312603A BR 0312603 A BR0312603 A BR 0312603A BR 0312603 A BR0312603 A BR 0312603A
Authority
BR
Brazil
Prior art keywords
block copolymer
styrene block
radial
preparing
radial styrene
Prior art date
Application number
BR0312603-0A
Other languages
English (en)
Other versions
BR0312603B1 (pt
Inventor
Marinus P Van Djik
Adriana M P Ros
Nikolaas J Van Dijk
Harvey E Atwood
Robert Charles Bening
Carl Lesley Willis
Barry C Moore
Original Assignee
Kraton Polymers Res Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kraton Polymers Res Bv filed Critical Kraton Polymers Res Bv
Publication of BR0312603A publication Critical patent/BR0312603A/pt
Publication of BR0312603B1 publication Critical patent/BR0312603B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Civil Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Materials For Medical Uses (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)

Abstract

"COPOLìMERO EM BLOCO ESTIRêNICO RADIAL OU UM DERIVADO HIDROGENADO DO MESMO MéTODO PARA PREPARAR UM COPOLìMERO EM BLOCO ESTIRêNICO RADIAL, E, BETUME MODIFICADO". é exposto um aperfeiçoamento em um processo para preparar copolímeros em bloco acoplados, em que a adição de cerca de 0,01 a cerca de 1,5 equivalentes de um composto alquila metálico por equivalente de terminais de cadeia de polímero vivo ao cimento, durante ou após a polimerização, aperfeiçoa as eficiências de acoplamento. Os copolímeros em bloco estirênicos radiais resultantes possuem quantidades reduzidas de oligómeros de braço 5+, que podem ser muito desejáveis em certas aplicações, tais como na modificação de betume.
BRPI0312603-0A 2002-07-11 2003-07-11 copolìmero em bloco estirênico radial ou um derivado hidrogenado do mesmo, método para preparar um copolìmero em bloco estirênico radial, e, betume modificado. BR0312603B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US39513902P 2002-07-11 2002-07-11
US60/395139 2002-07-11
PCT/US2003/021814 WO2004007581A1 (en) 2002-07-11 2003-07-11 Coupled styrenic block copolymers and process for preparing same

Publications (2)

Publication Number Publication Date
BR0312603A true BR0312603A (pt) 2005-05-31
BR0312603B1 BR0312603B1 (pt) 2012-12-11

Family

ID=30115821

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0312603-0A BR0312603B1 (pt) 2002-07-11 2003-07-11 copolìmero em bloco estirênico radial ou um derivado hidrogenado do mesmo, método para preparar um copolìmero em bloco estirênico radial, e, betume modificado.

Country Status (12)

Country Link
US (1) US7009000B2 (pt)
EP (1) EP1532185B1 (pt)
JP (1) JP4368303B2 (pt)
KR (1) KR100626442B1 (pt)
CN (1) CN1302036C (pt)
AT (1) ATE397632T1 (pt)
AU (1) AU2003249169A1 (pt)
BR (1) BR0312603B1 (pt)
DE (1) DE60321467D1 (pt)
EA (1) EA008191B1 (pt)
ES (1) ES2307979T3 (pt)
WO (1) WO2004007581A1 (pt)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7125940B2 (en) 2002-12-31 2006-10-24 Kraton Polymers U.S. Llc Conjugated diene polymers and copolymer blocks and process for preparing same
US8151281B2 (en) 2004-01-09 2012-04-03 International Business Machines Corporation Method and system of mapping at least one web service to at least one OSGi service
US7465768B2 (en) * 2004-06-18 2008-12-16 Bridgestone Corporation Method to reduce coupling during termination with functional end-groups
US7449518B2 (en) * 2006-03-24 2008-11-11 Kraton Polymers U.S. Llc High temperature block copolymers and process for making same
KR100923535B1 (ko) * 2007-11-21 2009-10-27 금호석유화학 주식회사 테이퍼드된 블록 공중합체를 함유한 개질 아스팔트 조성물
US8883927B2 (en) * 2007-11-28 2014-11-11 Dynasol Elastómeros, S.A. De C.V. Radial multi-block copolymers
CN101903455B (zh) 2007-12-21 2013-01-16 科腾聚合物美国有限责任公司 软质弹性体膜
KR20100009799A (ko) 2008-07-21 2010-01-29 주식회사 엘지화학 아스팔트 개질제 조성물 및 이를 함유하는 아스팔트 조성물
US20100316820A1 (en) * 2009-06-16 2010-12-16 Rainer Kolb Composite Materials Comprising Propylene-Based Polymer Blend Coatings
WO2011053406A1 (en) * 2009-10-29 2011-05-05 Exxonmobil Chemical Patents Inc. Pressure-sensitive hot melt adhesive compositions
US9023950B2 (en) 2010-04-21 2015-05-05 Nippon Soda Co., Ltd. Star polymer and method of producing same
CN103038204B (zh) * 2010-05-31 2015-03-04 株式会社普利司通 含羟基的甲基苯乙烯和引入其的聚合物
KR101411159B1 (ko) * 2010-08-03 2014-06-23 주식회사 엘지화학 아스팔트의 열 안정성 개선을 위한 삼중 가지형 비닐 방향족 탄화수소-공액디엔 블록 공중합체 조성물, 이의 제조방법, 및 이를 포함하는 아스팔트 조성물
WO2015054457A1 (en) * 2013-10-11 2015-04-16 Kraton Polymers U.S. Llc An olefinically unsaturated radial styrenic block copolymer and an improved vulcanizer-free latex
US10472514B2 (en) * 2014-01-23 2019-11-12 Asahi Kasei Kabushiki Kaisha Block copolymer composition and adhesive composition
KR101688504B1 (ko) * 2014-07-15 2016-12-22 금호석유화학 주식회사 개질 아스팔트용 첨가제 조성물, 이를 포함하는 개질 아스팔트 조성물, 및 그 제조 방법
US9428628B2 (en) 2014-08-20 2016-08-30 The Goodyear Tire & Rubber Company Functionalized polymer, rubber composition and pneumatic tire
US10385156B2 (en) 2016-06-30 2019-08-20 Kraton Polymers U.S. Llc Performance high vinyl block copolymer compositions and uses thereof

Family Cites Families (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3631006A (en) 1965-09-01 1971-12-28 Cities Service Co Process for the anionic polymerization of unsaturated hydrocarbon monomers
US4518753A (en) 1982-04-26 1985-05-21 National Research Development Corporation Anionic polymerization of conjugated dienes in the presence of hindered triaryl boron or aluminum derivatives
US4530984A (en) 1982-07-01 1985-07-23 The Firestone Tire & Rubber Company Process for production of polymers having increased 1,2-microstructure
US4476240A (en) 1982-07-01 1984-10-09 The Firestone Tire & Rubber Company Catalyst system containing an anionic initiator based on lithium and phosphine oxide modifier
US4473661A (en) 1982-07-01 1984-09-25 The Firestone Tire & Rubber Company Polymerization catalyst system containing organolithium, dialkyl magnesium and/or trialkyl aluminum, and a phosphine oxide
US4429091A (en) 1983-03-09 1984-01-31 The Firestone Tire & Rubber Company Oligomeric oxolanyl alkanes as modifiers for polymerization of dienes using lithium-based initiators
US4429090A (en) 1983-03-09 1984-01-31 The Firestone Tire & Rubber Company Catalyst containing oligomeric oxolanyl alkane modifiers and process for the production of polymers having increased 1,2-microstructure
US4480075A (en) 1983-06-24 1984-10-30 Shell Oil Company Block copolymers of Ziegler-Natta polymerized and anionically polymerized monomers
US4591624A (en) 1984-07-02 1986-05-27 The Firestone Tire & Rubber Company Catalyst system and process for polymerizing conjugated dienes
US4520123A (en) 1984-07-02 1985-05-28 The Firestone Tire & Rubber Company Catalyst system and process for polymerizing conjugated dienes
US5272214A (en) 1986-12-01 1993-12-21 Enichem Elastomeri S.P.A. Radial and branched block copolymers, compositions which contain them, their preparation and their use in bituminous compositions
US5202499A (en) 1988-05-31 1993-04-13 Gencorp Inc. Liquid telechelic polymers having high 1,4-diene structure
US5063190A (en) 1988-05-31 1991-11-05 Gencorp Inc. Anionic initiator system for polymerizing monomers
US5216181A (en) 1988-05-31 1993-06-01 Gencorp Inc. Liquid telechelic polymers having high 1,4-diene structure
US4889900A (en) 1989-06-12 1989-12-26 Shell Oil Company Preparation of alkyl methacrylate monomers for anionic polymerization
GB9002804D0 (en) 1990-02-08 1990-04-04 Secr Defence Anionic polymerisation
US5397851A (en) 1993-11-09 1995-03-14 Polysar Rubber Corporation Process for cis-1,4-polybutadiene production with reduced gel formation
US5376745A (en) 1993-12-01 1994-12-27 Shell Oil Company Low viscosity terminally functionalized isoprene polymers
FR2714384B1 (fr) * 1993-12-29 1996-02-02 Atochem Elf Sa Copolymère bloc étoile d'un monomère vinylaromatique et d'un diène conjugué, son procédé d'obtention, et les compositions comprenant ledit copolymère et du polystyrène cristal.
US5416168A (en) 1994-03-31 1995-05-16 Shell Oil Company Protected functional initiators for making terminally functionalized polymers
US5420203A (en) * 1994-05-17 1995-05-30 Shell Oil Company Process for producing high diblock content block copolymer compositions
US5412045A (en) 1994-09-16 1995-05-02 Polysar Rubber Corporation Preparation of high cis-1,4-polybutadiene with reduced gel
US5552493A (en) 1995-05-30 1996-09-03 Shell Oil Company Method for producing asymmetric radial polymers
US5610227A (en) 1995-06-07 1997-03-11 Bridgestone/Firestone, Inc. Lithium amino magnesiate polymerization initiators and elastomers having reduced hysteresis
US6429273B1 (en) 1996-03-14 2002-08-06 Asahi Kasei Kabushiki Kaisha Process for the preparation of vinylic polymers, polymerization initiator for vinylic monomers, and styrene resin composition
KR100487452B1 (ko) 1996-08-19 2005-05-09 바스프 악티엔게젤샤프트 음이온 중합 방법
WO1998007766A1 (de) 1996-08-19 1998-02-26 Basf Aktiengesellschaft Verfahren zur herstellung von dienpolymerisatlösungen in vinylaromatischen monomeren
US5665827A (en) 1996-11-07 1997-09-09 Bridgestone Corporation Synthesis of multiblock polymers using group IIA and IIB metal cyclic organometallic initiators
US5700888A (en) 1996-11-07 1997-12-23 Bridgestone Corporation Synthesis of macrocyclic polymers having low hysteresis compounded properties
US5677399A (en) 1996-11-07 1997-10-14 Bridgestone Corporation Synthesis of macrocyclic polymers with group IIA and IIB metal cyclic organometallic initiators
DE19648565A1 (de) 1996-11-23 1998-05-28 Basf Ag Verfahren zur Herstellung von Polyalkyl(meth)acrylaten
US6462143B1 (en) 1998-02-03 2002-10-08 Kraton Polymers Us Llc Gel-free process for making functionalized anionically polymerized polymers
ES2211047T3 (es) * 1998-02-07 2004-07-01 Basf Aktiengesellschaft Procedimiento para la obtencion de masas de moldeo termoplasticas, modificadas a la resiliencia.
US6242537B1 (en) 1998-03-30 2001-06-05 Shell Oil Company Gel-free process for making hydrogenated functionalized anionically polymerized polymers
TW442498B (en) 1998-05-18 2001-06-23 Shell Internattonale Res Mij B Process for making anionic polymeric di-and polyfunctional polymers using protected functional initiators, and functionalised polymer producted thereby
US6242538B1 (en) 1998-06-04 2001-06-05 Shell Oil Company Process for making hydrogenated gel-free functionalized anionically polymerized polymers
US6455651B1 (en) 1999-04-23 2002-09-24 Kraton Polymers U.S. Llc Uniform initiation of anionic polymerization using organo-substituted alkali metal initiators
US6391981B1 (en) 1999-04-23 2002-05-21 Kraton Polymers Us Llc Increased throughput in the manufacture of anionic polymers by reduction in polymer cement viscosity through the addition of metal alkyls
US20030114611A1 (en) 2001-10-24 2003-06-19 Fmc Corporation Functionalized alkyllithium formulations with improved thermal stability and processes for making the same
US20030114592A1 (en) 2001-10-24 2003-06-19 Fmc Corporation Processes for improving stability of living polymer chain ends

Also Published As

Publication number Publication date
BR0312603B1 (pt) 2012-12-11
CN1302036C (zh) 2007-02-28
EA200500161A1 (ru) 2005-08-25
DE60321467D1 (de) 2008-07-17
JP4368303B2 (ja) 2009-11-18
WO2004007581A1 (en) 2004-01-22
JP2005533151A (ja) 2005-11-04
CN1675272A (zh) 2005-09-28
KR20050021458A (ko) 2005-03-07
AU2003249169A1 (en) 2004-02-02
US20040054090A1 (en) 2004-03-18
ES2307979T3 (es) 2008-12-01
ATE397632T1 (de) 2008-06-15
EA008191B1 (ru) 2007-04-27
KR100626442B1 (ko) 2006-09-20
US7009000B2 (en) 2006-03-07
EP1532185A1 (en) 2005-05-25
EP1532185B1 (en) 2008-06-04

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