BR0312603A - Copolìmero em bloco estirênico radial ou um derivado hidrogenado do mesmo, método para preparar um copolìmero em bloco estirênico radial, e, betume modificado - Google Patents
Copolìmero em bloco estirênico radial ou um derivado hidrogenado do mesmo, método para preparar um copolìmero em bloco estirênico radial, e, betume modificadoInfo
- Publication number
- BR0312603A BR0312603A BR0312603-0A BR0312603A BR0312603A BR 0312603 A BR0312603 A BR 0312603A BR 0312603 A BR0312603 A BR 0312603A BR 0312603 A BR0312603 A BR 0312603A
- Authority
- BR
- Brazil
- Prior art keywords
- block copolymer
- styrene block
- radial
- preparing
- radial styrene
- Prior art date
Links
- 229920006132 styrene block copolymer Polymers 0.000 title abstract 3
- 239000010426 asphalt Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229920001400 block copolymer Polymers 0.000 abstract 2
- -1 alkyl compound Chemical class 0.000 abstract 1
- 239000004568 cement Substances 0.000 abstract 1
- 230000008878 coupling Effects 0.000 abstract 1
- 238000010168 coupling process Methods 0.000 abstract 1
- 238000005859 coupling reaction Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Materials For Medical Uses (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Abstract
"COPOLìMERO EM BLOCO ESTIRêNICO RADIAL OU UM DERIVADO HIDROGENADO DO MESMO MéTODO PARA PREPARAR UM COPOLìMERO EM BLOCO ESTIRêNICO RADIAL, E, BETUME MODIFICADO". é exposto um aperfeiçoamento em um processo para preparar copolímeros em bloco acoplados, em que a adição de cerca de 0,01 a cerca de 1,5 equivalentes de um composto alquila metálico por equivalente de terminais de cadeia de polímero vivo ao cimento, durante ou após a polimerização, aperfeiçoa as eficiências de acoplamento. Os copolímeros em bloco estirênicos radiais resultantes possuem quantidades reduzidas de oligómeros de braço 5+, que podem ser muito desejáveis em certas aplicações, tais como na modificação de betume.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US39513902P | 2002-07-11 | 2002-07-11 | |
US60/395139 | 2002-07-11 | ||
PCT/US2003/021814 WO2004007581A1 (en) | 2002-07-11 | 2003-07-11 | Coupled styrenic block copolymers and process for preparing same |
Publications (2)
Publication Number | Publication Date |
---|---|
BR0312603A true BR0312603A (pt) | 2005-05-31 |
BR0312603B1 BR0312603B1 (pt) | 2012-12-11 |
Family
ID=30115821
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0312603-0A BR0312603B1 (pt) | 2002-07-11 | 2003-07-11 | copolìmero em bloco estirênico radial ou um derivado hidrogenado do mesmo, método para preparar um copolìmero em bloco estirênico radial, e, betume modificado. |
Country Status (12)
Country | Link |
---|---|
US (1) | US7009000B2 (pt) |
EP (1) | EP1532185B1 (pt) |
JP (1) | JP4368303B2 (pt) |
KR (1) | KR100626442B1 (pt) |
CN (1) | CN1302036C (pt) |
AT (1) | ATE397632T1 (pt) |
AU (1) | AU2003249169A1 (pt) |
BR (1) | BR0312603B1 (pt) |
DE (1) | DE60321467D1 (pt) |
EA (1) | EA008191B1 (pt) |
ES (1) | ES2307979T3 (pt) |
WO (1) | WO2004007581A1 (pt) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7125940B2 (en) | 2002-12-31 | 2006-10-24 | Kraton Polymers U.S. Llc | Conjugated diene polymers and copolymer blocks and process for preparing same |
US8151281B2 (en) | 2004-01-09 | 2012-04-03 | International Business Machines Corporation | Method and system of mapping at least one web service to at least one OSGi service |
US7465768B2 (en) * | 2004-06-18 | 2008-12-16 | Bridgestone Corporation | Method to reduce coupling during termination with functional end-groups |
US7449518B2 (en) * | 2006-03-24 | 2008-11-11 | Kraton Polymers U.S. Llc | High temperature block copolymers and process for making same |
KR100923535B1 (ko) * | 2007-11-21 | 2009-10-27 | 금호석유화학 주식회사 | 테이퍼드된 블록 공중합체를 함유한 개질 아스팔트 조성물 |
US8883927B2 (en) * | 2007-11-28 | 2014-11-11 | Dynasol Elastómeros, S.A. De C.V. | Radial multi-block copolymers |
KR101193772B1 (ko) | 2007-12-21 | 2012-10-23 | 크레이튼 폴리머즈 유.에스. 엘엘씨 | 연질 탄성중합체 필름 |
KR20100009799A (ko) | 2008-07-21 | 2010-01-29 | 주식회사 엘지화학 | 아스팔트 개질제 조성물 및 이를 함유하는 아스팔트 조성물 |
US20100316820A1 (en) * | 2009-06-16 | 2010-12-16 | Rainer Kolb | Composite Materials Comprising Propylene-Based Polymer Blend Coatings |
WO2011053406A1 (en) * | 2009-10-29 | 2011-05-05 | Exxonmobil Chemical Patents Inc. | Pressure-sensitive hot melt adhesive compositions |
US9023950B2 (en) | 2010-04-21 | 2015-05-05 | Nippon Soda Co., Ltd. | Star polymer and method of producing same |
JP5841134B2 (ja) * | 2010-05-31 | 2016-01-13 | 株式会社ブリヂストン | 水酸基含有メチルスチレン及び該水酸基含有メチルスチレンを組み込んだポリマー |
KR101411159B1 (ko) * | 2010-08-03 | 2014-06-23 | 주식회사 엘지화학 | 아스팔트의 열 안정성 개선을 위한 삼중 가지형 비닐 방향족 탄화수소-공액디엔 블록 공중합체 조성물, 이의 제조방법, 및 이를 포함하는 아스팔트 조성물 |
EP3055355B1 (en) * | 2013-10-11 | 2018-08-15 | Kraton Polymers U.S. LLC | An olefinically unsaturated radial styrenic block copolymer and an improved vulcanizer-free latex |
KR101838832B1 (ko) * | 2014-01-23 | 2018-03-14 | 아사히 가세이 가부시키가이샤 | 블록 공중합체 조성물 및 점접착제 조성물 |
KR101688504B1 (ko) | 2014-07-15 | 2016-12-22 | 금호석유화학 주식회사 | 개질 아스팔트용 첨가제 조성물, 이를 포함하는 개질 아스팔트 조성물, 및 그 제조 방법 |
US9428628B2 (en) | 2014-08-20 | 2016-08-30 | The Goodyear Tire & Rubber Company | Functionalized polymer, rubber composition and pneumatic tire |
CN109415475B (zh) | 2016-06-30 | 2022-04-05 | 科腾聚合物美国有限责任公司 | 性能改进的高乙烯基嵌段共聚物组合物及其用途 |
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US3631006A (en) | 1965-09-01 | 1971-12-28 | Cities Service Co | Process for the anionic polymerization of unsaturated hydrocarbon monomers |
US4518753A (en) | 1982-04-26 | 1985-05-21 | National Research Development Corporation | Anionic polymerization of conjugated dienes in the presence of hindered triaryl boron or aluminum derivatives |
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US4473661A (en) | 1982-07-01 | 1984-09-25 | The Firestone Tire & Rubber Company | Polymerization catalyst system containing organolithium, dialkyl magnesium and/or trialkyl aluminum, and a phosphine oxide |
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US4429091A (en) | 1983-03-09 | 1984-01-31 | The Firestone Tire & Rubber Company | Oligomeric oxolanyl alkanes as modifiers for polymerization of dienes using lithium-based initiators |
US4429090A (en) | 1983-03-09 | 1984-01-31 | The Firestone Tire & Rubber Company | Catalyst containing oligomeric oxolanyl alkane modifiers and process for the production of polymers having increased 1,2-microstructure |
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US5272214A (en) * | 1986-12-01 | 1993-12-21 | Enichem Elastomeri S.P.A. | Radial and branched block copolymers, compositions which contain them, their preparation and their use in bituminous compositions |
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-
2003
- 2003-07-11 ES ES03764565T patent/ES2307979T3/es not_active Expired - Lifetime
- 2003-07-11 DE DE60321467T patent/DE60321467D1/de not_active Expired - Lifetime
- 2003-07-11 CN CNB038197987A patent/CN1302036C/zh not_active Expired - Fee Related
- 2003-07-11 US US10/618,394 patent/US7009000B2/en not_active Expired - Lifetime
- 2003-07-11 JP JP2004521737A patent/JP4368303B2/ja not_active Expired - Fee Related
- 2003-07-11 AT AT03764565T patent/ATE397632T1/de not_active IP Right Cessation
- 2003-07-11 BR BRPI0312603-0A patent/BR0312603B1/pt not_active IP Right Cessation
- 2003-07-11 WO PCT/US2003/021814 patent/WO2004007581A1/en active Application Filing
- 2003-07-11 AU AU2003249169A patent/AU2003249169A1/en not_active Abandoned
- 2003-07-11 KR KR1020057000555A patent/KR100626442B1/ko active IP Right Grant
- 2003-07-11 EP EP03764565A patent/EP1532185B1/en not_active Expired - Lifetime
- 2003-07-11 EA EA200500161A patent/EA008191B1/ru not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
US7009000B2 (en) | 2006-03-07 |
EP1532185B1 (en) | 2008-06-04 |
AU2003249169A1 (en) | 2004-02-02 |
EP1532185A1 (en) | 2005-05-25 |
ES2307979T3 (es) | 2008-12-01 |
CN1675272A (zh) | 2005-09-28 |
KR100626442B1 (ko) | 2006-09-20 |
WO2004007581A1 (en) | 2004-01-22 |
BR0312603B1 (pt) | 2012-12-11 |
EA200500161A1 (ru) | 2005-08-25 |
US20040054090A1 (en) | 2004-03-18 |
EA008191B1 (ru) | 2007-04-27 |
JP2005533151A (ja) | 2005-11-04 |
KR20050021458A (ko) | 2005-03-07 |
ATE397632T1 (de) | 2008-06-15 |
DE60321467D1 (de) | 2008-07-17 |
JP4368303B2 (ja) | 2009-11-18 |
CN1302036C (zh) | 2007-02-28 |
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Legal Events
Date | Code | Title | Description |
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B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 11/07/2003, OBSERVADAS AS DEMAIS CONDICOES LEGAIS. |
|
B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 17A ANUIDADE. |
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B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2594 DE 24-09-2020 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |