BR0312077A - Método de despolimerização de polissacarìdeos, galactomanana, e, agente de fraturamento de poço de óleo - Google Patents

Método de despolimerização de polissacarìdeos, galactomanana, e, agente de fraturamento de poço de óleo

Info

Publication number
BR0312077A
BR0312077A BR0312077-5A BR0312077A BR0312077A BR 0312077 A BR0312077 A BR 0312077A BR 0312077 A BR0312077 A BR 0312077A BR 0312077 A BR0312077 A BR 0312077A
Authority
BR
Brazil
Prior art keywords
oil well
guar
galactomannan
polysaccharides
well fracturing
Prior art date
Application number
BR0312077-5A
Other languages
English (en)
Other versions
BR0312077B8 (pt
Inventor
Leo Zhaoqing Liu
Christian Priou
Original Assignee
Rhodia Inc Companhia Americana
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Inc Companhia Americana filed Critical Rhodia Inc Companhia Americana
Publication of BR0312077A publication Critical patent/BR0312077A/pt
Publication of BR0312077B8 publication Critical patent/BR0312077B8/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B37/00Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
    • C08B37/006Heteroglycans, i.e. polysaccharides having more than one sugar residue in the main chain in either alternating or less regular sequence; Gellans; Succinoglycans; Arabinogalactans; Tragacanth or gum tragacanth or traganth from Astragalus; Gum Karaya from Sterculia urens; Gum Ghatti from Anogeissus latifolia; Derivatives thereof
    • C08B37/0087Glucomannans or galactomannans; Tara or tara gum, i.e. D-mannose and D-galactose units, e.g. from Cesalpinia spinosa; Tamarind gum, i.e. D-galactose, D-glucose and D-xylose units, e.g. from Tamarindus indica; Gum Arabic, i.e. L-arabinose, L-rhamnose, D-galactose and D-glucuronic acid units, e.g. from Acacia Senegal or Acacia Seyal; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B37/00Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B37/00Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
    • C08B37/0006Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
    • C08B37/0024Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid beta-D-Glucans; (beta-1,3)-D-Glucans, e.g. paramylon, coriolan, sclerotan, pachyman, callose, scleroglucan, schizophyllan, laminaran, lentinan or curdlan; (beta-1,6)-D-Glucans, e.g. pustulan; (beta-1,4)-D-Glucans; (beta-1,3)(beta-1,4)-D-Glucans, e.g. lichenan; Derivatives thereof
    • C08B37/0033Xanthan, i.e. D-glucose, D-mannose and D-glucuronic acid units, saubstituted with acetate and pyruvate, with a main chain of (beta-1,4)-D-glucose units; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B37/00Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
    • C08B37/006Heteroglycans, i.e. polysaccharides having more than one sugar residue in the main chain in either alternating or less regular sequence; Gellans; Succinoglycans; Arabinogalactans; Tragacanth or gum tragacanth or traganth from Astragalus; Gum Karaya from Sterculia urens; Gum Ghatti from Anogeissus latifolia; Derivatives thereof
    • C08B37/0087Glucomannans or galactomannans; Tara or tara gum, i.e. D-mannose and D-galactose units, e.g. from Cesalpinia spinosa; Tamarind gum, i.e. D-galactose, D-glucose and D-xylose units, e.g. from Tamarindus indica; Gum Arabic, i.e. L-arabinose, L-rhamnose, D-galactose and D-glucuronic acid units, e.g. from Acacia Senegal or Acacia Seyal; Derivatives thereof
    • C08B37/0096Guar, guar gum, guar flour, guaran, i.e. (beta-1,4) linked D-mannose units in the main chain branched with D-galactose units in (alpha-1,6), e.g. from Cyamopsis Tetragonolobus; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/62Compositions for forming crevices or fractures
    • C09K8/66Compositions based on water or polar solvents
    • C09K8/68Compositions based on water or polar solvents containing organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/84Compositions based on water or polar solvents
    • C09K8/86Compositions based on water or polar solvents containing organic compounds
    • C09K8/88Compositions based on water or polar solvents containing organic compounds macromolecular compounds
    • C09K8/90Compositions based on water or polar solvents containing organic compounds macromolecular compounds of natural origin, e.g. polysaccharides, cellulose

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Emergency Medicine (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

"MéTODO DE DESPOLIMERIZAçãO DE POLISSACARìDEOS, GALACTOMANANA, E, AGENTE DE FRATURAMENTO DE POçO DE óLEO". Um método de despolimerização de polímeros de polissacarídeos do tipo galactomanana e xantana, preferivelmente galactomananas, para um peso molecular inferior pré-selecionado por irradiação com feixes de elétrons de alta energia. As galactomananas preferidas para tratamento de acordo com este método são goma guar, guar nativa (guar splits) e hidropropil guar. Em uma forma de realização preferida, a goma guar é despolimerizada preferivelmente para um peso molecular de cerca de 150.000 Daltons a cerca de 200.000 Daltons. A guar despolimerizada tem uma polidispersão de menos que cerca de 3,0 e é útil no fraturamento de poço de óleo para melhorar a produção de óleo.
BRPI0312077A 2002-06-25 2003-06-24 método de despolimerização de polissacarídeos BR0312077B8 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US39132002P 2002-06-25 2002-06-25
PCT/US2003/020015 WO2004000885A2 (en) 2002-06-25 2003-06-24 Molecular weight reduction of polysaccharides by electron beams

Publications (2)

Publication Number Publication Date
BR0312077A true BR0312077A (pt) 2005-04-05
BR0312077B8 BR0312077B8 (pt) 2017-10-24

Family

ID=30000690

Family Applications (2)

Application Number Title Priority Date Filing Date
BRPI0312077-5A BRPI0312077B1 (pt) 2002-06-25 2003-06-24 Method of depolymerization of polysaccharides
BRPI0312077A BR0312077B8 (pt) 2002-06-25 2003-06-24 método de despolimerização de polissacarídeos

Family Applications Before (1)

Application Number Title Priority Date Filing Date
BRPI0312077-5A BRPI0312077B1 (pt) 2002-06-25 2003-06-24 Method of depolymerization of polysaccharides

Country Status (8)

Country Link
US (1) US7259192B2 (pt)
EP (1) EP1551882B1 (pt)
JP (2) JP4653861B2 (pt)
CN (2) CN1309742C (pt)
AU (1) AU2003263753A1 (pt)
BR (2) BRPI0312077B1 (pt)
RU (1) RU2323943C2 (pt)
WO (1) WO2004000885A2 (pt)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9720061D0 (en) 1997-09-19 1997-11-19 Crosfield Joseph & Sons Metal compounds as phosphate binders
JP4653861B2 (ja) * 2002-06-25 2011-03-16 ローディア インク. 電子ビームによる多糖類の分子量低減
US8895480B2 (en) * 2004-06-04 2014-11-25 Baker Hughes Incorporated Method of fracturing using guar-based well treating fluid
MY157620A (en) 2006-01-31 2016-06-30 Cytochroma Dev Inc A granular material of a solid water-soluble mixed metal compound capable of binding phosphate
CN101547678A (zh) * 2006-11-03 2009-09-30 赫尔克里士公司 用于个人护理或家用护理的经非硼酸金属盐或螯合物处理的可分散的聚半乳甘露聚糖聚合物
WO2008140729A1 (en) 2007-05-08 2008-11-20 Rhodia Inc. Polysaccharide based scale inhibitor
GB0714670D0 (en) * 2007-07-27 2007-09-05 Ineos Healthcare Ltd Use
GB0720220D0 (en) * 2007-10-16 2007-11-28 Ineos Healthcare Ltd Compound
US7795190B2 (en) * 2007-12-14 2010-09-14 E.I. Du Pont De Nemours And Company Process to prepare borozirconate solution and use as a cross-linker in hydraulic fracturing fluids
WO2009132225A2 (en) * 2008-04-24 2009-10-29 Medtronic, Inc. Rehydratable polysaccharide particles and sponge
US7867358B2 (en) * 2008-04-30 2011-01-11 Xyleco, Inc. Paper products and methods and systems for manufacturing such products
UA118089C2 (uk) * 2008-11-17 2018-11-26 Ксілеко, Інк. Переробка біомаси
EA025916B1 (ru) * 2009-02-12 2017-02-28 Родиа Оперейшнс Способы регулирования скорости деполимеризации полимера
GB0913525D0 (en) 2009-08-03 2009-09-16 Ineos Healthcare Ltd Method
FR2953217B1 (fr) 2009-11-27 2012-10-05 Ifremer Procede de depolymerisation de polysaccharides par broyage mecanique
US8371383B2 (en) * 2009-12-18 2013-02-12 Baker Hughes Incorporated Method of fracturing subterranean formations with crosslinked fluid
US9194223B2 (en) 2009-12-18 2015-11-24 Baker Hughes Incorporated Method of fracturing subterranean formations with crosslinked fluid
GB201001779D0 (en) 2010-02-04 2010-03-24 Ineos Healthcare Ltd Composition
NZ717014A (en) * 2010-05-24 2017-07-28 Xyleco Inc Methods for modifying the solubility of a polymer in a solvent
TW201200614A (en) * 2010-06-29 2012-01-01 Hon Hai Prec Ind Co Ltd Coating device
WO2012022046A1 (en) * 2010-08-20 2012-02-23 Rhodia (China) Co., Ltd. Soil additives for prevention of evaporation and methods for use
US20120193092A1 (en) * 2011-01-31 2012-08-02 Baker Hughes Incorporated Apparatus and methods for tracking the location of fracturing fluid in a subterranean formation
ITVA20110028A1 (it) * 2011-10-03 2013-04-04 Lamberti Spa Depolimerizzazione di polisaccaridi e prodotti correlati
CN103113485A (zh) * 2013-02-01 2013-05-22 上海中纺联高能技术有限公司 一种印染糊料的改性方法
CN104449646A (zh) * 2014-11-20 2015-03-25 中国石油大学(北京) 一种新型水基冻胶压裂液增稠剂的配方
US11497210B2 (en) 2018-04-09 2022-11-15 Rhodia Operations Compositions and methods for long lasting disinfection
CN109517085A (zh) * 2018-11-23 2019-03-26 浙江省能源与核技术应用研究院 一种电子束辐射降解黄原胶的方法
WO2020109560A1 (en) 2018-11-29 2020-06-04 Rhodia Operations Use of cationic hydroxyalkyl guars for microorganisms growth
WO2020109591A1 (en) 2018-11-29 2020-06-04 Rhodia Operations Use of guar derivatives in biofungicide compositions
WO2021069956A1 (en) 2019-10-09 2021-04-15 Rhodia Brasil S.A. Agrochemical composition
US20220386603A1 (en) 2019-10-18 2022-12-08 Rhodia Operations Growth enhancement of plant by using low molecular weight guar gum
CN110931793B (zh) * 2019-11-21 2022-06-14 合肥国轩高科动力能源有限公司 一种负极粘结剂及含有该粘结剂的硅基负极片的制备方法

Family Cites Families (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1255723A (en) 1915-01-04 1918-02-05 Larsen Ice Machine Company Inc Refrigerating apparatus.
US2895891A (en) 1957-05-15 1959-07-21 Gen Electric Cellulosic materials
DE1928045A1 (de) * 1968-06-18 1970-01-02 Dow Chemical Co Verfahren zur Herstellung von wasserloeslichen Zelluloseprodukten mit niedriger Viskositaet durch Elektronenbestrahlung
US4021355A (en) * 1970-12-14 1977-05-03 Halliburton Company Compositions for fracturing well formations
NO136113C (no) * 1970-12-14 1977-07-20 Halliburton Co Fremgangsm}te ved oppbrytning av underjordiske formasjoner.
US3766031A (en) 1972-04-10 1973-10-16 Garlock Inc Process for non-destructive radiation degradation of polytetrafluoroethylene
US4105665A (en) 1974-03-20 1978-08-08 Bayer Aktiengesellschaft Monomethine dyestuffs
US3974077A (en) 1974-09-19 1976-08-10 The Dow Chemical Company Fracturing subterranean formation
JPS5192508A (en) * 1975-02-12 1976-08-13 Deisuikohoni okeru itsudeiboshiho
US4057509A (en) * 1976-10-26 1977-11-08 Celanese Corporation Polygalactomannan allyl ether gels
US4143007A (en) 1977-10-31 1979-03-06 Celanese Corporation Thickening agent containing a polygalactomannan gum and a copolymer of an olefinically unsaturated dicarboxylic acid anhydride useful in hydraulic well-treating
US4169945A (en) * 1978-01-05 1979-10-02 Celanese Corporation Process for production of polygalactomannan ethers
US4505826A (en) * 1982-10-25 1985-03-19 Smith International Inc. Prepackaged crosslinked polymer
US4686052A (en) 1985-07-08 1987-08-11 Dowell Schlumberger Incorporated Stabilized fracture fluid and crosslinker therefor
US4657080A (en) 1986-02-19 1987-04-14 Dowell Schlumberger Incorporated Method of fracturing a subterranean formation using delayed crosslinker compositions containing organic titanium complexes
US5352277A (en) 1988-12-12 1994-10-04 E. I. Du Pont De Nemours & Company Final polishing composition
US5366755A (en) 1989-02-10 1994-11-22 Maritta Timonen Foodstuffs containing novel degraded cellulose derivatives
US5569483A (en) * 1989-02-10 1996-10-29 Alko Group Ltd. Degraded polysaccharide derivatives
DE69129608T2 (de) * 1990-07-02 1998-10-15 Aqualon Co Niedrigviskose-Polysaccharidzusammensetzung mit hohem Festkörpergehalt
US5184680A (en) * 1991-09-27 1993-02-09 Halliburton Company High temperature well cement compositions and methods
CA2120230A1 (en) 1991-10-15 1993-04-29 Donald W. Renn .beta.-1,3-glucan polysaccharides, compositions, and their preparation and uses
DE4202248A1 (de) * 1992-01-28 1993-07-29 Belland Ag Verfahren zur wiedergewinnung von in waessrig alkalischem oder saurem milieu geloesten polymeren
US5253711A (en) 1992-03-02 1993-10-19 Texas United Chemical Corp. Process for decomposing polysaccharides in alkaline aqueous systems
US5273767A (en) 1992-09-09 1993-12-28 Merck & Co., Inc. Rapidly hydrating gums
GB9226392D0 (en) * 1992-12-18 1993-02-10 Cpc International Inc Gelling agent
JPH0725772A (ja) * 1993-07-09 1995-01-27 Japan Atom Energy Res Inst 放射線処理による多糖類からの抗菌活性物質及びその製造方法
US5635153A (en) * 1995-03-29 1997-06-03 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Method for production of powders
WO1997001520A1 (en) 1995-06-28 1997-01-16 E.I. Du Pont De Nemours And Company Composition and method for stabilizing radiolabeled organic compounds
US5756720A (en) 1996-10-25 1998-05-26 Rhodia Inc. Derivatized guar gum composition including nonionic and cationic groups which demonstrate excellent solution clarity properties
US5916929A (en) 1997-06-23 1999-06-29 E-Beam Services, Inc. Method for irradiating organic polymers
ES2206965T3 (es) 1997-07-29 2004-05-16 Alcon Laboratories, Inc. Composiciones oftalmicas que contienen polimeros de galactomanana y borato.
US6242035B1 (en) 1998-11-23 2001-06-05 Cp Kelco U.S., Inc. Reduced molecular weight native gellan gum
DE19920688A1 (de) * 1999-05-05 2000-11-23 Manfred Kuhn Radiolytisch modifizierte Heteropolysaccharide
KR100369518B1 (ko) * 2000-02-02 2003-01-30 김공수 저분자 다당류의 제조방법
US6383344B1 (en) * 2000-07-19 2002-05-07 Genzyme Corporation Molecular weight reduction of polymer using irradiation treatment
KR20030020955A (ko) 2000-08-03 2003-03-10 허큘레스 인코포레이티드 화학적으로 또는 효소적으로 개질된 다당류 제조 방법 및이에 의해 제조된 생성물
US6488091B1 (en) 2001-06-11 2002-12-03 Halliburton Energy Services, Inc. Subterranean formation treating fluid concentrates, treating fluids and methods
WO2002100902A1 (en) * 2001-06-11 2002-12-19 Rhodia, Inc Galactomannan compositions and methods for making and using same
JP4653861B2 (ja) * 2002-06-25 2011-03-16 ローディア インク. 電子ビームによる多糖類の分子量低減
EP1539776B1 (en) * 2002-06-25 2011-10-19 Rhodia, Inc. Grafting polymerization of guar by electron beams

Also Published As

Publication number Publication date
RU2323943C2 (ru) 2008-05-10
US20040072699A1 (en) 2004-04-15
US7259192B2 (en) 2007-08-21
WO2004000885A3 (en) 2004-03-18
CN1970680A (zh) 2007-05-30
RU2005101751A (ru) 2005-09-10
AU2003263753A8 (en) 2004-01-06
CN1309742C (zh) 2007-04-11
BRPI0312077B1 (pt) 2017-06-13
JP2010285615A (ja) 2010-12-24
JP2005530897A (ja) 2005-10-13
CN1671749A (zh) 2005-09-21
EP1551882A4 (en) 2005-12-14
AU2003263753A1 (en) 2004-01-06
JP5580110B2 (ja) 2014-08-27
CN1970680B (zh) 2015-08-26
EP1551882A2 (en) 2005-07-13
WO2004000885A2 (en) 2003-12-31
EP1551882B1 (en) 2016-05-11
BR0312077B8 (pt) 2017-10-24
JP4653861B2 (ja) 2011-03-16

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B09W Correction of the decision to grant [chapter 9.1.4 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]
B16C Correction of notification of the grant [chapter 16.3 patent gazette]
B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

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