BR0112705A - Métodos para converter syngas e para otimizar a conversão de syngas em produtos de peso molecular mais alto, e para rapidamente determinar um conjunto apropriado de condições de reação e combinações de catalisador para formar um produto desejado - Google Patents

Métodos para converter syngas e para otimizar a conversão de syngas em produtos de peso molecular mais alto, e para rapidamente determinar um conjunto apropriado de condições de reação e combinações de catalisador para formar um produto desejado

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Publication number
BR0112705A
BR0112705A BR0112705-5A BR0112705A BR0112705A BR 0112705 A BR0112705 A BR 0112705A BR 0112705 A BR0112705 A BR 0112705A BR 0112705 A BR0112705 A BR 0112705A
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BR
Brazil
Prior art keywords
methods
syngas
optimizing
molecular weight
higher molecular
Prior art date
Application number
BR0112705-5A
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English (en)
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Chevron Usa Inc
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Publication of BR0112705A publication Critical patent/BR0112705A/pt

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  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"MéTODOS PARA CONVERTER SYNGAS E PARA OTIMIZAR A CONVERSãO DE SYNGAS EM PRODUTOS DE PESO MOLECULAR MAIS ALTO, E PARA RAPIDAMENTE DETERMINAR UM CONJUNTO APROPRIADO DE CONDIçõES DE REAçãO E COMBINAçõES DE CATALISADOR PARA FORMAR UM PRODUTO DESEJADO". Métodos para conversão de syngas em produtos de peso molecular mais alto usando síntese de Fischer-Tropsch, e métodos para otimizar os sistemas de catalisador na síntese, são divulgados. Em uma modalidade, os métodos usam catalisadores de Fischer-Tropsch de cobalto/rutênio em combinação com um catalisador de isomerização de olefina, que isomeriza ligações duplas em olefinas de C~ 4~+ à medida que elas são formadas. Em outra modalidade, os métodos usam catalisadores de Fischer-Tropsch que podem ou não ser catalisadores de cobalto/rutênio, em combinação com catalisadores de isomerização de olefina que são ácidos o bastante para isomerizar as olefinas de C~ 4~+ mas não muito ácidos para causar coqueificação rápida. Um benefício de usar os zeólitos relativamente menos ácidos é que a razão de iso-parafinas para aromáticos é aumentada relativo quando mais zeólitos ácidos forem usados. Também, os zeólitos relativamente menos ácidos não coqueificam tão facilmente que os zeólitos relativamente mais ácidos. Os métodos podem vantajosamente ser otimizados usando química combinatória, em que um banco de dados de combinações de sistemas de catalisadores e, opcionalmente, condições de reação, que fornecem vários fluxos de produto, são gerados. Uma vez que as condições de mercado variam e/ou os requerimentos de produto alteram, as condições adequadas para formar os produtos desejados podem ser identificadas com pouco ou nenhum tempo ocioso.
BR0112705-5A 2000-07-24 2001-07-13 Métodos para converter syngas e para otimizar a conversão de syngas em produtos de peso molecular mais alto, e para rapidamente determinar um conjunto apropriado de condições de reação e combinações de catalisador para formar um produto desejado BR0112705A (pt)

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US09/624,172 US6472441B1 (en) 2000-07-24 2000-07-24 Methods for optimizing Fischer-Tropsch synthesis of hydrocarbons in the distillate fuel and/or lube base oil ranges
PCT/US2001/022105 WO2002008163A1 (en) 2000-07-24 2001-07-13 Methods for optimizing fischer-tropsch synthesis of hydrocarbons in the distillate fuel and/or lube base oil ranges

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