BE562435A - - Google Patents
Info
- Publication number
- BE562435A BE562435A BE562435DA BE562435A BE 562435 A BE562435 A BE 562435A BE 562435D A BE562435D A BE 562435DA BE 562435 A BE562435 A BE 562435A
- Authority
- BE
- Belgium
- Prior art keywords
- methacrylates
- hydrolysis
- methacrylate
- vinyloxy
- acrylates
- Prior art date
Links
- 150000002734 metacrylic acid derivatives Chemical class 0.000 claims description 10
- 238000006460 hydrolysis reaction Methods 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 7
- -1 hydroxyalkyl acrylates Chemical class 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 5
- 230000002401 inhibitory effect Effects 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 230000000875 corresponding Effects 0.000 claims description 2
- 238000010526 radical polymerization reaction Methods 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 16
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 8
- 238000007127 saponification reaction Methods 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 6
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N benzohydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 5
- 239000010410 layer Substances 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L mgso4 Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 3
- 239000012044 organic layer Substances 0.000 description 3
- 239000001184 potassium carbonate Substances 0.000 description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- YKXAYLPDMSGWEV-UHFFFAOYSA-N 4-hydroxybutyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCO YKXAYLPDMSGWEV-UHFFFAOYSA-N 0.000 description 2
- YGTVWCBFJAVSMS-UHFFFAOYSA-N 5-hydroxypentyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCO YGTVWCBFJAVSMS-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 125000000182 1,4-naphthoquinonyl group Chemical group C1(C(=CC(C2=CC=CC=C12)=O)*)=O 0.000 description 1
- BSNJMDOYCPYHST-UHFFFAOYSA-N 2-ethenoxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOC=C BSNJMDOYCPYHST-UHFFFAOYSA-N 0.000 description 1
- NBTXFNJPFOORGI-UHFFFAOYSA-N 2-ethenoxyethyl prop-2-enoate Chemical compound C=COCCOC(=O)C=C NBTXFNJPFOORGI-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N 2-hydroxyethyl 2-methylacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 229940095095 2-hydroxyethyl acrylate Drugs 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- ZEUGUMVMFBIRJG-UHFFFAOYSA-N 4-ethenoxybutyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCOC=C ZEUGUMVMFBIRJG-UHFFFAOYSA-N 0.000 description 1
- SFXIITYNPFPIDC-UHFFFAOYSA-N 4-ethenoxybutyl prop-2-enoate Chemical compound C=COCCCCOC(=O)C=C SFXIITYNPFPIDC-UHFFFAOYSA-N 0.000 description 1
- SXIFAEWFOJETOA-UHFFFAOYSA-N 4-hydroxy-butyl Chemical group [CH2]CCCO SXIFAEWFOJETOA-UHFFFAOYSA-N 0.000 description 1
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 1
- QLXBYBOGVVAOPY-UHFFFAOYSA-N 5-ethenoxypentyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCOC=C QLXBYBOGVVAOPY-UHFFFAOYSA-N 0.000 description 1
- INRQKLGGIVSJRR-UHFFFAOYSA-N 5-hydroxypentyl prop-2-enoate Chemical compound OCCCCCOC(=O)C=C INRQKLGGIVSJRR-UHFFFAOYSA-N 0.000 description 1
- KIKPXINDSAFKDN-UHFFFAOYSA-N C(C=C)(=O)OCCCCCOC=C Chemical compound C(C=C)(=O)OCCCCCOC=C KIKPXINDSAFKDN-UHFFFAOYSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N O-Phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012259 ether extract Substances 0.000 description 1
- 125000001145 hydrido group Chemical group *[H] 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE562435A true BE562435A (de) |
Family
ID=184028
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE562435D BE562435A (de) |
Country Status (1)
| Country | Link |
|---|---|
| BE (1) | BE562435A (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1238215B (de) * | 1961-10-31 | 1967-04-06 | Ciba Geigy | Verfahren zur Herstellung von Copolymerisaten |
-
0
- BE BE562435D patent/BE562435A/fr unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1238215B (de) * | 1961-10-31 | 1967-04-06 | Ciba Geigy | Verfahren zur Herstellung von Copolymerisaten |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CH462136A (fr) | Procédé de préparation de dérivés de l'acide a-phényl-propionique | |
| CH375017A (fr) | Procédé de préparation de nouveaux dérivés de l'imidazole | |
| CH652385A5 (fr) | 5-(2-facultativement substitue-4-trifluoromethyl-6-facultativement substitue-phenoxy)-2-nitro, -halo ou -cyano-phenylcarbonyle alpha substitues-oximes et derives carbonyles correspondants. | |
| BE562435A (de) | ||
| CH464172A (fr) | Procédé de préparation d'acides carboxyliques -substitués | |
| EP0303545B1 (de) | Verfahren zur Herstellung von Phenyläthanolaminotetralinen | |
| CH615414A5 (de) | ||
| EP0071500B1 (de) | Verfahren zur Herstellung von 4-Amino-buttersäureamide | |
| FR2519630A1 (fr) | Esters ou ethers de methylol tricyclique et composition parfumante ou aromatisante les contenant | |
| EP0059659B1 (de) | Derivate der 4-Methyl-3-formyl-pentansäure, ihr Herstellungsverfahren und Anwendung zur Herstellung von cyclischen Derivaten | |
| EP0043307B1 (de) | Derivate von Cyclopropan-1-carbonsäure, ihre Salze und Verfahren zur Herstellung und Anwendung für die Synthese von intermediairem cis-Pyrethroid | |
| EP0148666B1 (de) | Verfahren zur Herstellung von Hydroxy-3-methyl-3-glutarsäure | |
| BE500594A (de) | ||
| EP0373057A1 (de) | Verfahren zur Herstellung von (2-Propyl)2-Pentensäure und ihren Estern | |
| CH426781A (fr) | Procédé pour la conversion de composés 1,2,3,4-tétrahydro-anthracènes en des composés 1,2,3,4,4a,5,12,12a-octahydronaphtacènes | |
| BE573097A (de) | ||
| EP0040140A1 (de) | Verfahren zur Herstellung von meta-Phenoxybenzoesäuren sowie von ihren Estern | |
| BE648892A (de) | ||
| CH336838A (fr) | Procédé pour la préparation de N,N-dibenzylaminoacides | |
| BE634833A (de) | ||
| BE541651A (de) | ||
| CH285943A (fr) | Procédé de synthèse de la vitamine A. | |
| BE478336A (de) | ||
| BE534468A (de) | ||
| CH406190A (fr) | Procédé de préparation de l'acide hydroxy-10 décène-2 oïque trans |