AU2013357970B2 - Process for preparing Fisher-Tropsch catalyst - Google Patents
Process for preparing Fisher-Tropsch catalyst Download PDFInfo
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- AU2013357970B2 AU2013357970B2 AU2013357970A AU2013357970A AU2013357970B2 AU 2013357970 B2 AU2013357970 B2 AU 2013357970B2 AU 2013357970 A AU2013357970 A AU 2013357970A AU 2013357970 A AU2013357970 A AU 2013357970A AU 2013357970 B2 AU2013357970 B2 AU 2013357970B2
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- fisher
- preparing
- catalyst precursor
- tropsch synthesis
- synthesis according
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Classifications
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- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/088—Decomposition of a metal salt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
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- Chemical Kinetics & Catalysis (AREA)
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- Oil, Petroleum & Natural Gas (AREA)
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Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20120146400 | 2012-12-14 | ||
| KR10-2012-0146400 | 2012-12-14 | ||
| KR10-2013-0068338 | 2013-06-14 | ||
| KR1020130068338A KR101298783B1 (ko) | 2012-12-14 | 2013-06-14 | 피셔-트롭쉬 촉매의 제조방법 |
| PCT/KR2013/006641 WO2014092278A1 (en) | 2012-12-14 | 2013-07-24 | Process for preparing fisher-tropsch catalyst |
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| Publication Number | Publication Date |
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| AU2013357970A1 AU2013357970A1 (en) | 2015-07-02 |
| AU2013357970B2 true AU2013357970B2 (en) | 2016-03-17 |
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| AU2013357970A Active AU2013357970B2 (en) | 2012-12-14 | 2013-07-24 | Process for preparing Fisher-Tropsch catalyst |
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| Country | Link |
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| KR (1) | KR101298783B1 (zh) |
| CN (1) | CN104955571B (zh) |
| AU (1) | AU2013357970B2 (zh) |
| MY (1) | MY171816A (zh) |
| WO (1) | WO2014092278A1 (zh) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101595181B1 (ko) * | 2014-05-30 | 2016-02-18 | 한국가스공사 | 활성 및 수명 특성이 향상된 피셔-트롭쉬 촉매의 제조방법 |
| KR20150137733A (ko) * | 2014-05-30 | 2015-12-09 | 한국가스공사 | 고활성 피셔-트롭쉬 촉매의 제조방법 |
| KR102233983B1 (ko) * | 2015-10-26 | 2021-03-30 | 주식회사 엘지화학 | 유기 아연 촉매, 이의 제조 방법 및 상기 촉매를 이용한 폴리알킬렌 카보네이트 수지의 제조 방법 |
| FR3050660B1 (fr) | 2016-04-29 | 2021-09-03 | Ifp Energies Now | Catalyseur de cobalt a base d'un support contenant une phase d'oxyde mixte contenant du cobalt et/ou du nickel prepare par l'utilisation d'un compose comportant deux fontions acides carboxyliques et au moins trois atomes de carbone |
| FR3050659B1 (fr) | 2016-04-29 | 2021-09-03 | Ifp Energies Now | Catalyseur de cobalt a base d'un support contenant une phase d'oxyde mixte contenant du cobalt et/ou du nickel prepare par l'utilisation d'un compose ester |
| FR3050663A1 (fr) | 2016-04-29 | 2017-11-03 | Ifp Energies Now | Catalyseur de cobalt a base d'un support contenant une phase d'oxyde mixte contenant du cobalt et/ou du nickel prepare par l'utilisation d'acide oxalique ou d'oxalate |
| FR3057472B1 (fr) | 2016-10-17 | 2018-11-16 | IFP Energies Nouvelles | Catalyseur de cobalt a base d'un support contenant une phase d'oxyde mixte contenant du cobalt et/ou du nickel prepare par l'utilisation d'un compose hydrogenocarbone. |
| CN106693962B (zh) * | 2017-01-21 | 2019-10-01 | 明光市天骄科技发展有限公司 | 一种双贵金属纳米催化剂的制备方法 |
| FR3087671B1 (fr) | 2018-10-25 | 2023-09-29 | Ifp Energies Now | Catalyseur de cobalt a base d’un support comprenant une phase d’oxyde mixte contenant du cobalt et/ou du nickel prepare a partir d’un compose ether |
| FR3087673B1 (fr) | 2018-10-25 | 2022-12-02 | Ifp Energies Now | Catalyseur de cobalt a base d’un support comprenant une phase d’oxyde mixte contenant du cobalt et/ou du nickel prepare a partir d’un compose dilactone |
| FR3087786B1 (fr) | 2018-10-25 | 2020-12-18 | Ifp Energies Now | Procede de synthese fischer-tropsch comprenant un catalyseur prepare par addition d’un compose organique en phase gazeuse |
| FR3087672B1 (fr) | 2018-10-25 | 2023-09-29 | Ifp Energies Now | Catalyseur de cobalt a base d’un support comprenant une phase d’oxyde mixte contenant du cobalt et/ou du nickel prepare a partir d’un compose organique de la famille des carboxyanhydrides |
| CN115209990A (zh) * | 2020-03-04 | 2022-10-18 | 国立大学法人东京工业大学 | 促进还原性氨基化的氧化物担载钴催化剂 |
| FR3119556A1 (fr) | 2021-02-11 | 2022-08-12 | IFP Energies Nouvelles | Procédé de préparation d’un catalyseur de Fischer-Tropsch en présence d’un additif et d’une étape de calcination spécifique |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003024786A (ja) * | 2001-07-13 | 2003-01-28 | Nippon Oil Corp | フィッシャー・トロプシュ合成用触媒および炭化水素の製造法 |
| JP2003512925A (ja) * | 1999-10-29 | 2003-04-08 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | 高活性一酸化炭素水素添加触媒の調製方法、これらの触媒組成物、このような反応を実施するためのこれら触媒の使用、およびこのような反応の生成物 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7452844B2 (en) * | 2001-05-08 | 2008-11-18 | Süd-Chemie Inc | High surface area, small crystallite size catalyst for Fischer-Tropsch synthesis |
| GB0512791D0 (en) | 2005-06-23 | 2005-07-27 | Johnson Matthey Plc | Catalysts |
| JP2007307436A (ja) | 2006-05-16 | 2007-11-29 | Ihi Corp | フィッシャー・トロプシュ合成触媒とその製造方法 |
| KR100885310B1 (ko) | 2007-07-26 | 2009-02-24 | 한국화학연구원 | 피셔-트롭쉬 합성용 코발트／인―알루미나 촉매와 이의제조방법 |
| CN101920199B (zh) * | 2009-06-09 | 2012-10-17 | 中国石油化工股份有限公司 | 改性硅胶为载体费托合成钴基催化剂及其制备方法 |
| KR101230625B1 (ko) | 2010-05-06 | 2013-02-06 | 한국과학기술연구원 | 메조포러스 실리카 구조체를 이용한 피셔-트롭시 공정용 촉매 |
| CN101979138B (zh) * | 2010-11-11 | 2012-07-25 | 中国科学院山西煤炭化学研究所 | 一种钴-铜费托合成催化剂及其制备方法 |
| CN102008960B (zh) * | 2010-11-17 | 2013-04-10 | 中南民族大学 | 一种氧化物载体负载钴催化剂及其制备方法和应用 |
| CN102139223B (zh) * | 2011-03-02 | 2013-06-19 | 浙江工业大学 | 一种负载型双金属催化剂及其应用 |
| CN102179255A (zh) * | 2011-03-02 | 2011-09-14 | 浙江工业大学 | 一种负载型钴合金催化剂及其在费托合成中的应用 |
-
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- 2013-06-14 KR KR1020130068338A patent/KR101298783B1/ko active IP Right Grant
- 2013-07-24 WO PCT/KR2013/006641 patent/WO2014092278A1/en active Application Filing
- 2013-07-24 MY MYPI2015001522A patent/MY171816A/en unknown
- 2013-07-24 CN CN201380071805.9A patent/CN104955571B/zh active Active
- 2013-07-24 AU AU2013357970A patent/AU2013357970B2/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003512925A (ja) * | 1999-10-29 | 2003-04-08 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | 高活性一酸化炭素水素添加触媒の調製方法、これらの触媒組成物、このような反応を実施するためのこれら触媒の使用、およびこのような反応の生成物 |
| JP2003024786A (ja) * | 2001-07-13 | 2003-01-28 | Nippon Oil Corp | フィッシャー・トロプシュ合成用触媒および炭化水素の製造法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2013357970A1 (en) | 2015-07-02 |
| CN104955571B (zh) | 2018-01-05 |
| CN104955571A (zh) | 2015-09-30 |
| WO2014092278A1 (en) | 2014-06-19 |
| MY171816A (en) | 2019-10-31 |
| KR101298783B1 (ko) | 2013-08-26 |
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