AU2006214748B2 - Anti-corrosion detergent compositions and use of same in cleaning dental and medical instruments - Google Patents

Anti-corrosion detergent compositions and use of same in cleaning dental and medical instruments Download PDF

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Publication number
AU2006214748B2
AU2006214748B2 AU2006214748A AU2006214748A AU2006214748B2 AU 2006214748 B2 AU2006214748 B2 AU 2006214748B2 AU 2006214748 A AU2006214748 A AU 2006214748A AU 2006214748 A AU2006214748 A AU 2006214748A AU 2006214748 B2 AU2006214748 B2 AU 2006214748B2
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AU
Australia
Prior art keywords
acid
corrosion
detergent composition
sodium
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU2006214748A
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English (en)
Other versions
AU2006214748A1 (en
Inventor
Bhupinder Bharaj
Navid Omidbakhsh
Veso Tijanic
Edgar Joel Acosta Zara
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Sci Can Ltd
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Sci Can Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sci Can Ltd filed Critical Sci Can Ltd
Publication of AU2006214748A1 publication Critical patent/AU2006214748A1/en
Assigned to SCICAN LTD. reassignment SCICAN LTD. Request for Assignment Assignors: SCICAN
Application granted granted Critical
Publication of AU2006214748B2 publication Critical patent/AU2006214748B2/en
Ceased legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/40—Monoamines or polyamines; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/58—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0073—Anticorrosion compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/28—Heterocyclic compounds containing nitrogen in the ring
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/361—Phosphonates, phosphinates or phosphonites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/364—Organic compounds containing phosphorus containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
    • C23G1/19—Iron or steel
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
    • A61L2202/20—Targets to be treated
    • A61L2202/24—Medical instruments, e.g. endoscopes, catheters, sharps
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces
    • C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Emergency Medicine (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Cosmetics (AREA)
AU2006214748A 2005-02-15 2006-02-14 Anti-corrosion detergent compositions and use of same in cleaning dental and medical instruments Ceased AU2006214748B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US65270105P 2005-02-15 2005-02-15
US60/652,701 2005-02-15
PCT/CA2006/000213 WO2006086875A1 (en) 2005-02-15 2006-02-14 Anti-corrosion detergent compositions and use of same in cleaning dental and medical instruments

Publications (2)

Publication Number Publication Date
AU2006214748A1 AU2006214748A1 (en) 2006-08-24
AU2006214748B2 true AU2006214748B2 (en) 2010-11-11

Family

ID=36916135

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2006214748A Ceased AU2006214748B2 (en) 2005-02-15 2006-02-14 Anti-corrosion detergent compositions and use of same in cleaning dental and medical instruments

Country Status (12)

Country Link
US (2) US7462586B2 (enExample)
EP (1) EP1851297B1 (enExample)
JP (1) JP2008530279A (enExample)
KR (1) KR100978822B1 (enExample)
CN (1) CN101146905B (enExample)
AT (1) ATE486923T1 (enExample)
AU (1) AU2006214748B2 (enExample)
CA (2) CA2768903C (enExample)
DE (1) DE602006017971D1 (enExample)
RU (1) RU2388797C2 (enExample)
WO (1) WO2006086875A1 (enExample)
ZA (1) ZA200706561B (enExample)

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WO2009000820A2 (de) * 2007-06-28 2008-12-31 Siemens Aktiengesellschaft Korrosionsschützender zusatz für flüssigkeiten
US20090104097A1 (en) * 2007-10-17 2009-04-23 E. I. Du Pont De Nemours And Company Mercury removal from a gas stream
JP5317466B2 (ja) * 2007-12-14 2013-10-16 花王株式会社 医療器具用洗浄剤組成物
EP2090646A1 (en) * 2008-01-22 2009-08-19 Thermphos Trading GmbH Surface treatment composition containing phosphonic acid compounds
JP5280814B2 (ja) * 2008-11-26 2013-09-04 クリーンケミカル株式会社 洗浄医療器具の乾燥前処理剤と使用済み医療器具の再生方法
WO2011105869A2 (ko) 2010-02-26 2011-09-01 주식회사 나이벡 치아의 접합능을 향상시키기 위한 치과용 클린저 조성물
WO2012090306A1 (ja) 2010-12-28 2012-07-05 花王株式会社 医療器具の洗浄方法
KR101239794B1 (ko) * 2011-02-01 2013-03-06 강원대학교산학협력단 의료기기용 부식방지제 조성물
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CN102294056B (zh) * 2011-09-02 2013-12-04 山东新华医疗器械股份有限公司 手术器械保湿剂及其制备方法
US9259272B2 (en) 2011-10-28 2016-02-16 Restore Medical Solutions, Inc. Adjustable surgical instrument stringer, tray system, and method of sterilization
US9156571B2 (en) 2011-10-28 2015-10-13 Restore Medical Solutions, Inc. Adjustable surgical instrument stringer with pegs, tray system, and method of sterilization
US8815174B2 (en) 2012-08-17 2014-08-26 American Sterilizer Company Steam sterilizer
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CN104818478A (zh) * 2012-12-13 2015-08-05 蒋红娟 可提高耐腐蚀性的水电解极板表面处理液的使用方法
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WO2014124265A1 (en) * 2013-02-07 2014-08-14 Restore Medical Solutions, Inc. Surgical instrument stringer tray system
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CN103602995B (zh) * 2013-10-25 2016-04-06 青岛华仁技术孵化器有限公司 环保型金属去污剂
US9765286B2 (en) * 2014-12-22 2017-09-19 Ecolab Usa Inc. Warewashing composition containing alkanol amine phosphonate and methods of use
DE102015219659A1 (de) * 2015-10-09 2017-04-13 Blue Safety Gmbh Aufbereitungsverfahren für eine Betriebswasserversorgungseinheit
WO2017148524A1 (en) * 2016-03-03 2017-09-08 Ecolab Usa Inc Non-enzymatic cleaner for reprocessing surgical instruments and flexible endoscopes
CN105821428A (zh) * 2016-06-04 2016-08-03 罗浩 一种低腐蚀性的医用器皿清洗剂及其制备方法
FR3070686B1 (fr) 2017-09-01 2019-08-30 Arkema France Acide sulfonique faiblement colore
FR3070687B1 (fr) * 2017-09-01 2019-11-22 Arkema France Procede de preparation d'acide sulfonique
US20190322898A1 (en) 2018-04-20 2019-10-24 Postprocess Technologies, Inc. Finishing Mediums And Finishing Suspensions
KR102117649B1 (ko) 2018-08-17 2020-06-02 주식회사 나이벡 치은치주염 또는 임플란트 주위염 치료 및 예방용 조성물 및 상기 조성물이 코팅되어 있는 치간칫솔
EP3842041B1 (en) 2018-08-17 2025-05-21 Nibec Co., Ltd. Composition for treating and preventing gingivoperiodontitis or peri-implantitis, and interdental brush coated with same
EP3923721A4 (en) * 2019-02-15 2022-10-26 Whiteley Corporation Pty Ltd IMPROVED ENDOSCOPIC DISINFECTANT
CN111088120B (zh) * 2019-12-30 2021-05-07 深圳金泽万长石化有限公司 一种强力去污清洗液及其制备方法
US11584900B2 (en) 2020-05-14 2023-02-21 Corrosion Innovations, Llc Method for removing one or more of: coating, corrosion, salt from a surface
KR102416911B1 (ko) 2022-03-10 2022-07-06 (주)에이치피앤씨 바이오 필름 제거효과가 우수한 의료기기용 세정제 조성물
CN115595034B (zh) * 2022-10-25 2023-08-08 广东润和新材料科技有限公司 一种机舱用抗病毒抗菌纳米涂料及其制备方法与应用
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US5589099A (en) * 1993-04-20 1996-12-31 Ecolab Inc. Low foaming rinse agents comprising ethylene oxide/propylene oxide block copolymer
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US5645755A (en) * 1995-07-20 1997-07-08 Castlebar Industries Corp. Ice-melting composition having anti-corrosion properties
WO1997034711A1 (en) * 1996-03-19 1997-09-25 Church & Dwight Company, Inc. Aqueous alkali cleaning compositions
US5712236A (en) * 1995-08-02 1998-01-27 Church & Dwight Co., Inc. Alkali metal cleaner with zinc phosphate anti-corrosion system
CA2305290A1 (en) * 1997-10-08 1999-04-15 Petra Tiarks Process for cleaning surgical instruments
CA2313870A1 (en) * 1999-07-13 2001-01-13 Societe D'exploitation De Produits Pour Les Industries Chimiques (S.E.P. P.I.C.) Novel method of cleaning and disinfecting a haemodialysis apparatus with an aqueous solution comprising a surfactant and an active oxygen generator and novel composition
CA2398942A1 (en) * 2000-02-07 2001-08-09 Steris Inc. Liquid cleaning and sterilization system and method
US6315835B1 (en) * 2000-04-27 2001-11-13 Basf Corporation Anti-spotting and anti-filming hard surface cleaning formulations and methods
US20020173437A1 (en) * 2001-03-23 2002-11-21 Reid Rabon Methods and compositions for cleaning, rinsing, and antimicrobial treatment of medical equipment
WO2003042762A1 (en) * 2001-11-13 2003-05-22 Samsung Electronics Co., Ltd. Chemical rinse composition

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Publication number Priority date Publication date Assignee Title
US5234832A (en) * 1988-05-17 1993-08-10 Henkel Kommanditgesellschaft Auf Aktien Process for cleaning and disinfecting heat and corrosion sensitive medical instruments
US5589099A (en) * 1993-04-20 1996-12-31 Ecolab Inc. Low foaming rinse agents comprising ethylene oxide/propylene oxide block copolymer
US5645755A (en) * 1995-07-20 1997-07-08 Castlebar Industries Corp. Ice-melting composition having anti-corrosion properties
WO1997005222A1 (en) * 1995-07-25 1997-02-13 Henkel Corporation Composition and method for degreasing metal surfaces
US5712236A (en) * 1995-08-02 1998-01-27 Church & Dwight Co., Inc. Alkali metal cleaner with zinc phosphate anti-corrosion system
WO1997034711A1 (en) * 1996-03-19 1997-09-25 Church & Dwight Company, Inc. Aqueous alkali cleaning compositions
CA2305290A1 (en) * 1997-10-08 1999-04-15 Petra Tiarks Process for cleaning surgical instruments
CA2313870A1 (en) * 1999-07-13 2001-01-13 Societe D'exploitation De Produits Pour Les Industries Chimiques (S.E.P. P.I.C.) Novel method of cleaning and disinfecting a haemodialysis apparatus with an aqueous solution comprising a surfactant and an active oxygen generator and novel composition
CA2398942A1 (en) * 2000-02-07 2001-08-09 Steris Inc. Liquid cleaning and sterilization system and method
US6315835B1 (en) * 2000-04-27 2001-11-13 Basf Corporation Anti-spotting and anti-filming hard surface cleaning formulations and methods
US20020173437A1 (en) * 2001-03-23 2002-11-21 Reid Rabon Methods and compositions for cleaning, rinsing, and antimicrobial treatment of medical equipment
WO2003042762A1 (en) * 2001-11-13 2003-05-22 Samsung Electronics Co., Ltd. Chemical rinse composition

Also Published As

Publication number Publication date
WO2006086875A1 (en) 2006-08-24
ATE486923T1 (de) 2010-11-15
HK1118572A1 (en) 2009-02-13
CA2768903C (en) 2014-03-25
AU2006214748A1 (en) 2006-08-24
US7462586B2 (en) 2008-12-09
CN101146905A (zh) 2008-03-19
CN101146905B (zh) 2011-04-06
RU2007134103A (ru) 2009-03-27
EP1851297B1 (en) 2010-11-03
US20060194706A1 (en) 2006-08-31
KR20070103761A (ko) 2007-10-24
EP1851297A4 (en) 2008-05-28
CA2768903A1 (en) 2006-08-24
KR100978822B1 (ko) 2010-08-30
ZA200706561B (en) 2008-07-30
JP2008530279A (ja) 2008-08-07
DE602006017971D1 (de) 2010-12-16
CA2597230A1 (en) 2006-08-24
US20090093389A1 (en) 2009-04-09
CA2597230C (en) 2012-03-06
EP1851297A1 (en) 2007-11-07
RU2388797C2 (ru) 2010-05-10

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