AU2002366733B9 - Process for the polymerization of olefins - Google Patents
Process for the polymerization of olefins Download PDFInfo
- Publication number
- AU2002366733B9 AU2002366733B9 AU2002366733A AU2002366733A AU2002366733B9 AU 2002366733 B9 AU2002366733 B9 AU 2002366733B9 AU 2002366733 A AU2002366733 A AU 2002366733A AU 2002366733 A AU2002366733 A AU 2002366733A AU 2002366733 B9 AU2002366733 B9 AU 2002366733B9
- Authority
- AU
- Australia
- Prior art keywords
- catalyst component
- diameter
- catalyst
- value
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000034 method Methods 0.000 title claims description 57
- 238000006116 polymerization reaction Methods 0.000 title claims description 41
- 150000001336 alkenes Chemical class 0.000 title claims description 18
- 239000003054 catalyst Substances 0.000 claims description 136
- 229920000642 polymer Polymers 0.000 claims description 44
- 239000010936 titanium Substances 0.000 claims description 35
- 239000002245 particle Substances 0.000 claims description 33
- 229910052719 titanium Inorganic materials 0.000 claims description 21
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 229910052736 halogen Inorganic materials 0.000 claims description 16
- 229910052749 magnesium Inorganic materials 0.000 claims description 16
- 150000002367 halogens Chemical class 0.000 claims description 15
- 239000011949 solid catalyst Substances 0.000 claims description 14
- 230000000694 effects Effects 0.000 claims description 13
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 13
- 229910052753 mercury Inorganic materials 0.000 claims description 13
- 239000004215 Carbon black (E152) Substances 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 210000002196 fr. b Anatomy 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- 239000011148 porous material Substances 0.000 claims description 8
- 150000003609 titanium compounds Chemical class 0.000 claims description 8
- 229910010066 TiC14 Inorganic materials 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 7
- 210000003918 fraction a Anatomy 0.000 claims description 7
- 125000005842 heteroatom Chemical group 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 150000007513 acids Chemical class 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- 150000004820 halides Chemical class 0.000 claims description 4
- 150000002576 ketones Chemical class 0.000 claims description 4
- 150000002902 organometallic compounds Chemical class 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 150000002430 hydrocarbons Chemical group 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 description 18
- 239000011777 magnesium Substances 0.000 description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 14
- 239000005977 Ethylene Substances 0.000 description 14
- -1 hydrocarbyl radical Chemical group 0.000 description 14
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 14
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 13
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 12
- 238000003756 stirring Methods 0.000 description 11
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- 229910001629 magnesium chloride Inorganic materials 0.000 description 6
- 150000003377 silicon compounds Chemical class 0.000 description 6
- 239000012265 solid product Substances 0.000 description 6
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 125000000753 cycloalkyl group Chemical group 0.000 description 3
- 238000012685 gas phase polymerization Methods 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
- 102000020897 Formins Human genes 0.000 description 2
- 108091022623 Formins Proteins 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 238000002083 X-ray spectrum Methods 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 230000003292 diminished effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920005606 polypropylene copolymer Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 2
- 229920001866 very low density polyethylene Polymers 0.000 description 2
- UVGKQRAGAYVWQV-UHFFFAOYSA-N 2,3-dimethylbutan-2-yl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C(C)C UVGKQRAGAYVWQV-UHFFFAOYSA-N 0.000 description 1
- HRAQMGWTPNOILP-UHFFFAOYSA-N 4-Ethoxy ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(OCC)C=C1 HRAQMGWTPNOILP-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910010061 TiC13 Inorganic materials 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- 238000006653 Ziegler-Natta catalysis Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- MEWFSXFFGFDHGV-UHFFFAOYSA-N cyclohexyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C1CCCCC1 MEWFSXFFGFDHGV-UHFFFAOYSA-N 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 229920013728 elastomeric terpolymer Polymers 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical class OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 150000003022 phthalic acids Chemical class 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 229920000576 tactic polymer Polymers 0.000 description 1
- HXLWJGIPGJFBEZ-UHFFFAOYSA-N tert-butyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C HXLWJGIPGJFBEZ-UHFFFAOYSA-N 0.000 description 1
- NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01204842 | 2001-12-12 | ||
| EP01204842.7 | 2001-12-12 | ||
| PCT/EP2002/014111 WO2003054035A1 (en) | 2001-12-12 | 2002-12-10 | Process for the polymerization of olefins |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| AU2002366733A1 AU2002366733A1 (en) | 2003-07-09 |
| AU2002366733B2 AU2002366733B2 (en) | 2008-10-16 |
| AU2002366733B9 true AU2002366733B9 (en) | 2009-03-19 |
Family
ID=8181409
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2002366733A Ceased AU2002366733B9 (en) | 2001-12-12 | 2002-12-10 | Process for the polymerization of olefins |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US7138469B2 (https=) |
| EP (1) | EP1453867B1 (https=) |
| JP (1) | JP4511185B2 (https=) |
| KR (1) | KR101080666B1 (https=) |
| CN (1) | CN100422221C (https=) |
| AR (1) | AR037790A1 (https=) |
| AU (1) | AU2002366733B9 (https=) |
| BR (1) | BR0207072B1 (https=) |
| CA (1) | CA2452573C (https=) |
| ES (1) | ES2527049T3 (https=) |
| HU (1) | HUP0303960A3 (https=) |
| MX (1) | MXPA03008573A (https=) |
| MY (1) | MY136330A (https=) |
| PL (1) | PL204746B1 (https=) |
| RU (1) | RU2308461C2 (https=) |
| SA (1) | SA03230560B1 (https=) |
| TW (1) | TWI268939B (https=) |
| WO (1) | WO2003054035A1 (https=) |
| ZA (1) | ZA200305940B (https=) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100249330A1 (en) * | 2007-10-15 | 2010-09-30 | Basell Poliolefine Italia S.R.L. | Process for the preparation of high fluidity propylene polymers |
| EP2222730B2 (en) * | 2007-12-18 | 2019-12-25 | Basell Poliolefine Italia S.r.l. | Copolymers of propylene with hexene-1 and blown films obtained from them |
| US8796385B2 (en) * | 2007-12-19 | 2014-08-05 | Basell Poliolefine Italia S.R.L. | Soft and flexible polyolefin compositions |
| CN102803310A (zh) | 2009-06-19 | 2012-11-28 | 巴塞尔聚烯烃意大利有限责任公司 | 制备抗冲击性丙烯聚合物组合物的方法 |
| BR112012010897B1 (pt) | 2009-11-17 | 2019-09-10 | Basell Poliolefine Italia Srl | "filmes termorretráteis" |
| RU2425059C1 (ru) * | 2010-01-28 | 2011-07-27 | Учреждение Российской Академии Наук Ордена Трудового Красного Знамени Институт Нефтехимического Синтеза Им. А.В. Топчиева Ран (Инхс Ран) | Способ получения титан-магниевого нанокатализатора (со)полимеризации альфа-олефинов и сопряженных диенов |
| US20130165591A1 (en) | 2010-09-06 | 2013-06-27 | Basell Poliolefine Italia S.R.L. | Polyolefin compositions having improved sealability |
| CN103298614B (zh) | 2010-12-09 | 2016-02-24 | 巴塞尔聚烯烃意大利有限责任公司 | 可渗透聚合物膜 |
| EP2594593A1 (en) | 2011-11-17 | 2013-05-22 | Basell Poliolefine Italia S.r.l. | Process for the preparation of heterophasic propylene polymer compositions |
| EP2607389A1 (en) | 2011-12-20 | 2013-06-26 | Basell Polyolefine GmbH | Process for preparing olefin polymer by slurry loop polymerization having high powder density |
| EP2743278A1 (en) | 2012-12-11 | 2014-06-18 | Basell Polyolefine GmbH | Process for degassing and buffering polyolefin particles obtained by olefin polymerization |
| EP2743073A1 (en) * | 2012-12-12 | 2014-06-18 | Basell Poliolefine Italia S.r.l. | Propylene-based terpolymers |
| EP2757114A1 (en) * | 2013-01-18 | 2014-07-23 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| KR101787231B1 (ko) * | 2013-06-03 | 2017-10-18 | 루머스 노보렌 테크놀로지 게엠베하 | 고성능 지글러-나타 촉매 시스템, 그 촉매 시스템의 제조 방법 및 용도 |
| ES2651456T3 (es) | 2013-08-14 | 2018-01-26 | Borealis Ag | Composición de propileno con mejor resistencia al impacto a baja temperatura |
| MX2016001930A (es) | 2013-08-21 | 2016-05-26 | Borealis Ag | Composicion de poliolefina de alto flujo con alta rigidez y tenacidad. |
| MX2016001705A (es) | 2013-08-21 | 2016-05-18 | Borealis Ag | Composicion de poliolefina de alto flujo con alta rigidez y tenacidad. |
| PT2853563T (pt) | 2013-09-27 | 2016-07-14 | Borealis Ag | Filmes adequados para processamento de bopp a partir de polímeros com xs elevada e tm elevado |
| ES2568615T3 (es) | 2013-10-11 | 2016-05-03 | Borealis Ag | Película para etiquetas orientada en la dirección de la máquina |
| US9683062B2 (en) * | 2013-10-24 | 2017-06-20 | Basell Poliolefin Italia S.R.L. | Process for the preparation of porous propylene polymers |
| ES2661108T3 (es) | 2013-10-24 | 2018-03-27 | Borealis Ag | Homopolímero de polipropileno de bajo punto de fusión con alto contenido de regioerrores y alto peso molecular |
| MX368147B (es) | 2013-11-22 | 2019-09-20 | Borealis Ag | Homopolímero de propileno de baja emisión con alto flujo de masa fundida. |
| WO2015082379A1 (en) | 2013-12-04 | 2015-06-11 | Borealis Ag | Phthalate-free pp homopolymers for meltblown fibers |
| CN105980457B (zh) | 2013-12-18 | 2019-03-22 | 博里利斯股份公司 | 具有改善的刚性/韧性平衡的bopp膜 |
| EP3094660B1 (en) * | 2014-01-17 | 2018-12-19 | Borealis AG | Process for preparing propylene/1-butene copolymers |
| WO2015117958A1 (en) | 2014-02-06 | 2015-08-13 | Borealis Ag | Soft copolymers with high impact strength |
| US10100186B2 (en) | 2014-02-06 | 2018-10-16 | Borealis Ag | Soft and transparent impact copolymers |
| EP2907841A1 (en) | 2014-02-14 | 2015-08-19 | Borealis AG | Polypropylene composite |
| ES2659731T3 (es) | 2014-05-20 | 2018-03-19 | Borealis Ag | Composición de polipropileno para aplicaciones en interiores de automóviles |
| JP6578069B2 (ja) | 2015-12-11 | 2019-09-18 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | プロピレン系重合体組成物 |
| EP3387027B1 (en) | 2015-12-11 | 2024-02-14 | Basell Poliolefine Italia S.r.l. | Propylene hexene copolymers |
| JP7106241B2 (ja) * | 2019-01-09 | 2022-07-26 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィンの重合用触媒成分 |
| JPWO2023171433A1 (https=) * | 2022-03-11 | 2023-09-14 | ||
| WO2026041323A1 (en) | 2024-08-19 | 2026-02-26 | Basell Poliolefine Italia S.R.L. | Polypropylene composition having good thermal and optical properties |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0361494A2 (en) * | 1988-09-30 | 1990-04-04 | Montell North America Inc. | Components and catalysts for the polymerization of olefins |
| EP0395083A2 (en) * | 1989-04-28 | 1990-10-31 | Montell North America Inc. | Components and catalysts for the polymerization of olefins |
| EP0553805A1 (en) * | 1992-01-31 | 1993-08-04 | Montell Technology Company bv | Components and catalysts for the polymerization of olefins |
| EP0601525A1 (en) * | 1992-12-11 | 1994-06-15 | Montell Technology Company bv | Components and catalysts for the polymerization of olefins |
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2002
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- 2002-12-04 MY MYPI20024550A patent/MY136330A/en unknown
- 2002-12-10 PL PL374056A patent/PL204746B1/pl not_active IP Right Cessation
- 2002-12-10 ES ES02805313.0T patent/ES2527049T3/es not_active Expired - Lifetime
- 2002-12-10 US US10/473,313 patent/US7138469B2/en not_active Expired - Lifetime
- 2002-12-10 MX MXPA03008573A patent/MXPA03008573A/es active IP Right Grant
- 2002-12-10 KR KR1020037012812A patent/KR101080666B1/ko not_active Expired - Lifetime
- 2002-12-10 EP EP02805313.0A patent/EP1453867B1/en not_active Expired - Lifetime
- 2002-12-10 WO PCT/EP2002/014111 patent/WO2003054035A1/en not_active Ceased
- 2002-12-10 RU RU2003128027/04A patent/RU2308461C2/ru active
- 2002-12-10 AU AU2002366733A patent/AU2002366733B9/en not_active Ceased
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- 2002-12-10 JP JP2003554748A patent/JP4511185B2/ja not_active Expired - Lifetime
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- 2002-12-10 BR BRPI0207072-3A patent/BR0207072B1/pt active IP Right Grant
- 2002-12-11 AR ARP020104798A patent/AR037790A1/es active IP Right Grant
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2003
- 2003-03-01 SA SA3230560A patent/SA03230560B1/ar unknown
- 2003-07-31 ZA ZA2003/05940A patent/ZA200305940B/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0361494A2 (en) * | 1988-09-30 | 1990-04-04 | Montell North America Inc. | Components and catalysts for the polymerization of olefins |
| EP0395083A2 (en) * | 1989-04-28 | 1990-10-31 | Montell North America Inc. | Components and catalysts for the polymerization of olefins |
| EP0553805A1 (en) * | 1992-01-31 | 1993-08-04 | Montell Technology Company bv | Components and catalysts for the polymerization of olefins |
| EP0601525A1 (en) * | 1992-12-11 | 1994-06-15 | Montell Technology Company bv | Components and catalysts for the polymerization of olefins |
Also Published As
| Publication number | Publication date |
|---|---|
| BR0207072B1 (pt) | 2012-08-21 |
| WO2003054035A1 (en) | 2003-07-03 |
| RU2003128027A (ru) | 2005-02-27 |
| TW200409780A (en) | 2004-06-16 |
| ZA200305940B (en) | 2005-01-26 |
| MY136330A (en) | 2008-09-30 |
| US20040077490A1 (en) | 2004-04-22 |
| CA2452573C (en) | 2011-03-22 |
| AR037790A1 (es) | 2004-12-01 |
| TWI268939B (en) | 2006-12-21 |
| KR101080666B1 (ko) | 2011-11-08 |
| HUP0303960A3 (en) | 2007-11-28 |
| PL204746B1 (pl) | 2010-02-26 |
| US7138469B2 (en) | 2006-11-21 |
| AU2002366733B2 (en) | 2008-10-16 |
| JP2005513213A (ja) | 2005-05-12 |
| SA03230560B1 (ar) | 2008-07-19 |
| KR20040064613A (ko) | 2004-07-19 |
| CN1518562A (zh) | 2004-08-04 |
| CN100422221C (zh) | 2008-10-01 |
| PL374056A1 (en) | 2005-09-19 |
| BR0207072A (pt) | 2004-01-27 |
| EP1453867A1 (en) | 2004-09-08 |
| EP1453867B1 (en) | 2014-11-12 |
| AU2002366733A1 (en) | 2003-07-09 |
| RU2308461C2 (ru) | 2007-10-20 |
| CA2452573A1 (en) | 2003-07-03 |
| HUP0303960A2 (hu) | 2004-03-01 |
| JP4511185B2 (ja) | 2010-07-28 |
| MXPA03008573A (es) | 2003-12-08 |
| ES2527049T3 (es) | 2015-01-20 |
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