ATE293133T1 - Verfahren zur herstellung von polymeren durch eine kontrollierte radikalischpolymerisation mit halogenierten xanthaten - Google Patents

Verfahren zur herstellung von polymeren durch eine kontrollierte radikalischpolymerisation mit halogenierten xanthaten

Info

Publication number
ATE293133T1
ATE293133T1 AT00938854T AT00938854T ATE293133T1 AT E293133 T1 ATE293133 T1 AT E293133T1 AT 00938854 T AT00938854 T AT 00938854T AT 00938854 T AT00938854 T AT 00938854T AT E293133 T1 ATE293133 T1 AT E293133T1
Authority
AT
Austria
Prior art keywords
radical polymerization
controlled radical
producing polymers
halogenated
xanthates
Prior art date
Application number
AT00938854T
Other languages
English (en)
Inventor
Mathias Destarac
Dominique Charmot
Samir Z Zard
Xavier Franck
Original Assignee
Rhodia Chimie Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Chimie Sa filed Critical Rhodia Chimie Sa
Application granted granted Critical
Publication of ATE293133T1 publication Critical patent/ATE293133T1/de

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/14Methyl esters, e.g. methyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/03Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
AT00938854T 1999-06-04 2000-05-26 Verfahren zur herstellung von polymeren durch eine kontrollierte radikalischpolymerisation mit halogenierten xanthaten ATE293133T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9907096A FR2794463B1 (fr) 1999-06-04 1999-06-04 Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates halogenes
PCT/FR2000/001438 WO2000075207A1 (fr) 1999-06-04 2000-05-26 Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates halogenes

Publications (1)

Publication Number Publication Date
ATE293133T1 true ATE293133T1 (de) 2005-04-15

Family

ID=9546404

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00938854T ATE293133T1 (de) 1999-06-04 2000-05-26 Verfahren zur herstellung von polymeren durch eine kontrollierte radikalischpolymerisation mit halogenierten xanthaten

Country Status (13)

Country Link
US (1) US6777513B1 (de)
EP (1) EP1185570B1 (de)
JP (1) JP3542580B2 (de)
AT (1) ATE293133T1 (de)
AU (1) AU5409900A (de)
CA (1) CA2375849A1 (de)
CZ (1) CZ20014337A3 (de)
DE (1) DE60019419T2 (de)
FR (1) FR2794463B1 (de)
IL (1) IL146696A0 (de)
MX (1) MXPA01012511A (de)
WO (1) WO2000075207A1 (de)
ZA (1) ZA200109549B (de)

Families Citing this family (87)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6716948B1 (en) 1999-07-31 2004-04-06 Symyx Technologies, Inc. Controlled-architecture polymers and use thereof as separation media
FR2802208B1 (fr) 1999-12-09 2003-02-14 Rhodia Chimie Sa Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates
KR20030081462A (ko) * 2001-02-26 2003-10-17 로디아 쉬미 저에너지 표면의 친수성을 증가시키기 위한 양쪽성 블록코폴리머의 용도
FR2829140B1 (fr) * 2001-09-05 2003-12-19 Rhodia Chimie Sa Procede de synthese de polymeres a fonctions thiols
FR2821620B1 (fr) * 2001-03-02 2003-06-27 Coatex Sas Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres de faible polydispersite obtenus, et leurs applications
DE60225550T2 (de) * 2001-05-04 2009-04-02 Rhodia Chimie Blockcopolymer-tenside durch eine kontrollierte radikalpolymerisation hergestellt
FR2826658B1 (fr) * 2001-06-29 2003-09-05 Rhodia Chimie Sa Synthese de polymeres par voie radicalaire controlee en miniemulsion
FR2829494B1 (fr) * 2001-07-13 2005-10-28 Rhodia Chimie Sa Compositions aqueuses comprenant un microgel chimique associe a un polymere pontant, preparation et utilisation
US20030158078A1 (en) * 2002-02-11 2003-08-21 Jeanne Chang Detergent composition comprising a block copolymer
US6855840B2 (en) 2002-02-11 2005-02-15 University Of Southern Mississippi Chain transfer agents for raft polymerization in aqueous media
FR2835826A1 (fr) 2002-02-14 2003-08-15 Rhodianyl Materiaux composites obtenus a partir de liant hydraulique et de fibres organiques presentant un comportement mecanique ameliore
US6667376B2 (en) 2002-03-22 2003-12-23 Symyx Technologies, Inc. Control agents for living-type free radical polymerization and methods of polymerizing
FR2842190A1 (fr) 2002-07-10 2004-01-16 Rhodia Performance Fibres Materiaux composites renforces comprenant un liant hydraulique ou chimique,des fibres de polyamide ainsi qu'un ou plusieurs additifs pour comportement mecanique ameliore
FR2842814B1 (fr) * 2002-07-26 2004-10-22 Coatex Sas Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres obtenus, et leurs applications.
FR2846973B1 (fr) 2002-11-07 2004-12-17 Rhodia Chimie Sa Composition d'antifroissage comprenant un copolymere a architecture controlee, pour articles en fibres textiles
FR2848556B1 (fr) 2002-12-13 2006-06-16 Bio Merieux Procede de polymerisation radicalaire controlee
US6919409B2 (en) 2003-06-26 2005-07-19 Symyx Technologies, Inc. Removal of the thiocarbonylthio or thiophosphorylthio end group of polymers and further functionalization thereof
WO2005003192A1 (en) 2003-06-26 2005-01-13 Symyx Technologies, Inc. Synthesis of photoresist polymers
WO2005000924A1 (en) 2003-06-26 2005-01-06 Symyx Technologies, Inc. Photoresist polymers
DE602004008468T2 (de) 2003-06-26 2008-05-21 Jsr Corp. Photoresistzusammensetzungen
WO2005021612A1 (en) * 2003-09-03 2005-03-10 Rhodia Inc New copolymer having a controlled structure, and use thereof
FR2872038A1 (fr) * 2004-06-23 2005-12-30 Rhodia Chimie Sa Composition cosmetique comprenant un polyorganosiloxane et ses utilisations
FR2872039B1 (fr) * 2004-06-23 2006-08-04 Rhodia Chimie Sa Composition cosmetique comprenant un polyorganosiloxane et ses utilisations
JP2008504411A (ja) 2004-07-01 2008-02-14 ウニベルズィタイト・ヘント (アルキル)アクリル酸部分を含有する単分散性ポリマー、前駆体およびその作製方法ならびにその適用
US7279446B2 (en) 2004-11-15 2007-10-09 Rhodia Inc. Viscoelastic surfactant fluids having enhanced shear recovery, rheology and stability performance
RU2401281C2 (ru) 2005-01-11 2010-10-10 Циба Спешиалти Кемикэлз Холдинг Инк. Способ постмодификации гомо- и сополимеров, полученных регулируемыми процессами свободнорадикальной полимеризации
FR2883291B1 (fr) * 2005-03-17 2010-03-05 Rhodia Chimie Sa Copolymere a blocs pouvant etre utile comme tenseur
FR2885367B1 (fr) * 2005-05-03 2007-07-27 Rhodia Chimie Sa Organosol stabilise par des polymeres sequences amphiphiles
EP1926761A1 (de) * 2005-05-23 2008-06-04 Rhodia Opérations Von vinylphosphonatmonomeren abgeleitetes copolymer mit kontrollierter architektur, herstellungsverfahren dafür und verwendungen davon
JP5000904B2 (ja) * 2006-03-15 2012-08-15 株式会社クラレ 末端にメルカプト基を有するポリビニルアルコール系重合体の製造方法
DE602006006825D1 (de) * 2006-08-17 2009-06-25 Rhodia Operations Blockcopolymere, Verfahren zu deren Herstellung und ihre Verwendung in Emulsionen
FR2911609B1 (fr) * 2007-01-19 2009-03-06 Rhodia Recherches & Tech Copolymere dibloc comprenant des unites derivant du styrene et des unites derivant d'acide acrylique
FR2923487B1 (fr) * 2007-11-09 2009-12-04 Rhodia Operations Copolymere ampholyte a architecture controlee
FI122734B (fi) 2007-05-21 2012-06-15 Kemira Oyj Prosessikemikaali käytettäväksi paperin tai kartongin valmistuksessa
FR2917415B1 (fr) * 2007-06-14 2012-10-12 Rhodia Recherches Et Tech Microgel polymerique comprenant des unites cationiques
FR2921663A1 (fr) 2007-10-02 2009-04-03 Bluestar Silicones France Soc Polyorganosiloxanes a fonction piperidine depourvus de toxicite par contact cutane et utilisation de ces derniers dans des compositions cosmetiques
FR2934154B1 (fr) * 2008-07-23 2010-08-13 Rhodia Operations Emulsions thermosensibles
EP2160946A1 (de) 2008-09-09 2010-03-10 Polymers CRC Limited Verfahren zur Herstellung eines antimikrobiellen Artikels
EP2160945A1 (de) 2008-09-09 2010-03-10 Polymers CRC Limited Antimikrobieller Artikel
FR2937336B1 (fr) 2008-10-22 2011-06-10 Rhodia Operations Composition pour les soins menagers comprenant un nanogel cationique
FR2965264B1 (fr) 2010-09-27 2013-11-29 Rhodia Operations Polymerisation radicalaire controlee de n-vinyl lactames en milieu aqueux
FR2965564B1 (fr) 2010-09-30 2012-10-26 Rhodia Operations Preparation de polymeres hydrophiles de haute masse par polymerisation radicalaire controlee
CN102020744B (zh) * 2010-11-17 2012-07-11 江苏苏博特新材料股份有限公司 醋酸乙烯酯类无皂乳液、可再分散性胶粉及其制备方法
EP2551338A1 (de) 2011-07-27 2013-01-30 Henkel AG & Co. KGaA Waschmittel mit Fleckenentfernungseigenschaften
BR112014009835B1 (pt) 2011-10-24 2021-03-02 Rhodia Operations processo de preparação de polímeros em bloco anfifílicos por polimerização radicalar micelar controlada, polímero em bloco e utilização do polímero
EP2809698B1 (de) 2012-01-31 2016-01-27 Rhodia Operations Polymerisation von halogenierten vinylmonomeren in der dispergierten phase in anwesenheit von lebenden reaktiven stabilisatoren
US9487598B2 (en) 2012-01-31 2016-11-08 Rhodia Operations Live poly(n-vinyl lactam) reactive stabilizers for dispersed phase polymerization
FR2987837B1 (fr) 2012-03-09 2014-03-14 Rhodia Operations Polymerisation radicalaire controlee en dispersion eau-dans-l'eau
FR3004458A1 (fr) 2013-04-11 2014-10-17 Rhodia Operations Fluides de fracturation a base de polymeres associatifs et de tensioactifs labiles
FR3011555A1 (fr) 2013-10-04 2015-04-10 Rhodia Operations Polymeres sequences pour le controle du filtrat
EP2896637A1 (de) 2014-01-21 2015-07-22 Rhodia Operations Copolymer mit Einheiten des Typs A, abgeleitet von Carbonsäuremonomeren und Einheiten von Typ B, abgeleitet von Sulfonsäuremonomeren
WO2015173193A1 (en) 2014-05-12 2015-11-19 Solvay Specialty Polymers Italy S.P.A. Method for the controlled polymerization of fluoromonomers
FR3027309B1 (fr) 2014-10-17 2018-08-10 Rhodia Operations Polymeres polyfonctionnels a base d'unites phosphonates et d'unites amines
FR3034768B1 (fr) 2015-04-07 2017-05-05 Rhodia Operations Polymeres sequences pour le controle du filtrat
FR3034776A1 (fr) 2015-04-07 2016-10-14 Rhodia Operations Polymeres sequences pour le controle du filtrat
FR3034777A1 (fr) 2015-04-07 2016-10-14 Rhodia Operations Polymeres sequences pour le controle du filtrat et de la rheologie
EP3292189A2 (de) 2015-05-04 2018-03-14 Rhodia Operations Copolymere zur schmierung von metallen
FR3037074B1 (fr) 2015-06-03 2017-07-14 Rhodia Operations Agents de suspension obtenus par polymerisation micellaire
FR3043083B1 (fr) 2015-10-30 2019-04-19 Rhodia Operations Polymeres sequences amphiphiles solubles en milieu fortement salin
CN108697074A (zh) 2015-12-10 2018-10-23 阿达玛马克西姆股份有限公司 聚电解质层形成嵌段共聚物及其组合物和用途
WO2017103635A1 (en) 2015-12-16 2017-06-22 Rhodia Poliamida E Especialidades Ltda Emulsifier system for explosive emulsions
EA201991006A1 (ru) 2016-11-29 2020-02-03 Родиа Оперейшнс Полимерные системы для дисперсии частиц
FR3064641A1 (fr) 2017-04-03 2018-10-05 Rhodia Operations Association pour le controle du filtrat et la migration de gaz
FR3070043B1 (fr) 2017-08-09 2019-08-16 Rhodia Operations Formulation contenant un polymere associatif
ES2906198T3 (es) 2017-09-14 2022-04-13 Chemetall Gmbh Método para pretratar materiales de aluminio, en particular ruedas de aluminio
EP3728512B1 (de) 2017-12-19 2024-07-03 Energy Solutions (US) LLC Wässrige formulierungen von tensiden und assoziativen polymeren zur unterstützten gewinnung von erdöl
WO2019126255A1 (en) 2017-12-20 2019-06-27 Rhodia Operations Polymeric systems for particle dispersion
AR114185A1 (es) 2018-01-23 2020-07-29 Adama Makhteshim Ltd Síntesis de 5-cloro-2-[(3,4,4-trifluoro-3-buten-1-il)tio]-tiazol
FR3079833B1 (fr) 2018-04-10 2020-10-09 Rhodia Operations Composition aqueuse gelifiee pour l'extraction petroliere
FR3083238A1 (fr) 2018-07-02 2020-01-03 Rhodia Operations Relargage progressif de chaines polymeres en milieu liquide
US12049571B2 (en) 2018-07-05 2024-07-30 Specialty Operations France Method for treating metallic surfaces with an acidic aqueous composition and a post rinsing composition to improve corrosion resistance
JP2022501519A (ja) 2018-07-05 2022-01-06 ケメタル ゲゼルシャフト ミット ベシュレンクテル ハフツング 金属表面を酸性水性組成物で処理して腐食抵抗性を改善する方法
WO2020049132A1 (en) 2018-09-07 2020-03-12 Chemetall Gmbh Method for treating surfaces of aluminum containing substrates
MX2021002641A (es) 2018-09-07 2021-05-12 Chemetall Gmbh Metodo para tratar superficies de sustratos que contienen aluminio.
CN112888809A (zh) 2018-10-08 2021-06-01 凯密特尔有限责任公司 金属表面的无镍磷化方法和用于这种方法的组合物
CN112930420A (zh) 2018-10-08 2021-06-08 凯密特尔有限责任公司 金属表面的无镍磷化方法和用于这种方法的组合物
KR20210134679A (ko) 2019-02-28 2021-11-10 로디아 오퍼레이션스 에멀젼의 높은 안정화를 위한 조성물
FR3093514A1 (fr) 2019-03-05 2020-09-11 Rhodia Operations Suspension de polymères associatifs pour le traitement de formations souterraines
CN113557284A (zh) 2019-03-12 2021-10-26 罗地亚经营管理公司 稳定化的减摩剂乳液
CN113631595B (zh) 2019-03-15 2023-04-11 罗地亚经营管理公司 聚合物组合物及其应用
KR102714209B1 (ko) * 2019-12-18 2024-10-04 주식회사 엘지화학 고흡수성 수지의 제조 방법
EP4077507B1 (de) 2019-12-20 2026-04-22 Specialty Operations France Verfahren zum fragmentieren eines polymers
JP6989792B2 (ja) 2019-12-25 2022-01-12 ダイキン工業株式会社 フルオロポリマーの製造方法
MX2023004398A (es) 2020-10-23 2023-07-11 Energy Solutions Us Llc Sistemas polimericos que tienen viscosidad mejorada y propiedades de transporte de apuntalantes.
FR3125296A1 (fr) 2021-07-13 2023-01-20 Rhodia Operations Préparation de polymères séquencés amphiphiles par polymérisation radicalaire micellaire inverse
CN115785576B (zh) * 2022-12-06 2024-04-05 合肥工业大学 一种耐γ-射线辐照可陶瓷化阻燃耐火电缆护套材料及其制备方法
WO2025204124A1 (ja) * 2024-03-29 2025-10-02 Agc株式会社 ポリマーの製造方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3862975A (en) * 1973-07-31 1975-01-28 Goodrich Co B F Process for preparing liquid xanthate-terminated polymers
DE69225591T2 (de) * 1991-02-06 1999-01-07 The Commonwealth Scientific And Industrial Research Organization, Campbell Polymerisationsregelung
EP0910587B1 (de) * 1996-07-10 2001-12-12 E.I. Du Pont De Nemours And Company Polymerisation mit "living" kennzeichen
FR2764892B1 (fr) * 1997-06-23 2000-03-03 Rhodia Chimie Sa Procede de synthese de polymeres a blocs
ES2277678T3 (es) * 1997-12-18 2007-07-16 E.I. Du Pont De Nemours And Company Proceso de polimerizacion con caracteristicas vivientes y polimeros obtenidos mediante este proceso.
FR2773161B1 (fr) * 1997-12-31 2000-01-21 Rhodia Chimie Sa Procede de synthese de polymeres a blocs
FR2814168B1 (fr) 2000-09-18 2006-11-17 Rhodia Chimie Sa Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee en presence d'un compose disulfure

Also Published As

Publication number Publication date
IL146696A0 (en) 2002-07-25
FR2794463A1 (fr) 2000-12-08
JP2003501528A (ja) 2003-01-14
CZ20014337A3 (cs) 2002-05-15
DE60019419T2 (de) 2006-03-09
AU5409900A (en) 2000-12-28
ZA200109549B (en) 2002-08-26
EP1185570A1 (de) 2002-03-13
FR2794463B1 (fr) 2005-02-25
MXPA01012511A (es) 2002-07-02
US6777513B1 (en) 2004-08-17
CA2375849A1 (fr) 2000-12-14
EP1185570B1 (de) 2005-04-13
JP3542580B2 (ja) 2004-07-14
WO2000075207A1 (fr) 2000-12-14
DE60019419D1 (de) 2005-05-19

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