ATE293133T1 - Verfahren zur herstellung von polymeren durch eine kontrollierte radikalischpolymerisation mit halogenierten xanthaten - Google Patents

Verfahren zur herstellung von polymeren durch eine kontrollierte radikalischpolymerisation mit halogenierten xanthaten

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Publication number
ATE293133T1
ATE293133T1 AT00938854T AT00938854T ATE293133T1 AT E293133 T1 ATE293133 T1 AT E293133T1 AT 00938854 T AT00938854 T AT 00938854T AT 00938854 T AT00938854 T AT 00938854T AT E293133 T1 ATE293133 T1 AT E293133T1
Authority
AT
Austria
Prior art keywords
radical polymerization
controlled radical
producing polymers
halogenated
xanthates
Prior art date
Application number
AT00938854T
Other languages
English (en)
Inventor
Mathias Destarac
Dominique Charmot
Samir Z Zard
Xavier Franck
Original Assignee
Rhodia Chimie Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Chimie Sa filed Critical Rhodia Chimie Sa
Application granted granted Critical
Publication of ATE293133T1 publication Critical patent/ATE293133T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
AT00938854T 1999-06-04 2000-05-26 Verfahren zur herstellung von polymeren durch eine kontrollierte radikalischpolymerisation mit halogenierten xanthaten ATE293133T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9907096A FR2794463B1 (fr) 1999-06-04 1999-06-04 Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates halogenes
PCT/FR2000/001438 WO2000075207A1 (fr) 1999-06-04 2000-05-26 Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates halogenes

Publications (1)

Publication Number Publication Date
ATE293133T1 true ATE293133T1 (de) 2005-04-15

Family

ID=9546404

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00938854T ATE293133T1 (de) 1999-06-04 2000-05-26 Verfahren zur herstellung von polymeren durch eine kontrollierte radikalischpolymerisation mit halogenierten xanthaten

Country Status (13)

Country Link
US (1) US6777513B1 (de)
EP (1) EP1185570B1 (de)
JP (1) JP3542580B2 (de)
AT (1) ATE293133T1 (de)
AU (1) AU5409900A (de)
CA (1) CA2375849A1 (de)
CZ (1) CZ20014337A3 (de)
DE (1) DE60019419T2 (de)
FR (1) FR2794463B1 (de)
IL (1) IL146696A0 (de)
MX (1) MXPA01012511A (de)
WO (1) WO2000075207A1 (de)
ZA (1) ZA200109549B (de)

Families Citing this family (86)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6716948B1 (en) 1999-07-31 2004-04-06 Symyx Technologies, Inc. Controlled-architecture polymers and use thereof as separation media
FR2802208B1 (fr) * 1999-12-09 2003-02-14 Rhodia Chimie Sa Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates
FR2829140B1 (fr) * 2001-09-05 2003-12-19 Rhodia Chimie Sa Procede de synthese de polymeres a fonctions thiols
KR20030081462A (ko) * 2001-02-26 2003-10-17 로디아 쉬미 저에너지 표면의 친수성을 증가시키기 위한 양쪽성 블록코폴리머의 용도
FR2821620B1 (fr) 2001-03-02 2003-06-27 Coatex Sas Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres de faible polydispersite obtenus, et leurs applications
ATE388970T1 (de) * 2001-05-04 2008-03-15 Rhodia Chimie Sa Blockcopolymer-tenside durch eine kontrollierte radikalpolymerisation hergestellt
FR2826658B1 (fr) * 2001-06-29 2003-09-05 Rhodia Chimie Sa Synthese de polymeres par voie radicalaire controlee en miniemulsion
FR2829494B1 (fr) * 2001-07-13 2005-10-28 Rhodia Chimie Sa Compositions aqueuses comprenant un microgel chimique associe a un polymere pontant, preparation et utilisation
US6855840B2 (en) 2002-02-11 2005-02-15 University Of Southern Mississippi Chain transfer agents for raft polymerization in aqueous media
US20030158078A1 (en) * 2002-02-11 2003-08-21 Jeanne Chang Detergent composition comprising a block copolymer
FR2835826A1 (fr) 2002-02-14 2003-08-15 Rhodianyl Materiaux composites obtenus a partir de liant hydraulique et de fibres organiques presentant un comportement mecanique ameliore
US6667376B2 (en) * 2002-03-22 2003-12-23 Symyx Technologies, Inc. Control agents for living-type free radical polymerization and methods of polymerizing
FR2842190A1 (fr) 2002-07-10 2004-01-16 Rhodia Performance Fibres Materiaux composites renforces comprenant un liant hydraulique ou chimique,des fibres de polyamide ainsi qu'un ou plusieurs additifs pour comportement mecanique ameliore
FR2842814B1 (fr) * 2002-07-26 2004-10-22 Coatex Sas Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres obtenus, et leurs applications.
FR2846973B1 (fr) 2002-11-07 2004-12-17 Rhodia Chimie Sa Composition d'antifroissage comprenant un copolymere a architecture controlee, pour articles en fibres textiles
FR2848556B1 (fr) 2002-12-13 2006-06-16 Bio Merieux Procede de polymerisation radicalaire controlee
US6919409B2 (en) 2003-06-26 2005-07-19 Symyx Technologies, Inc. Removal of the thiocarbonylthio or thiophosphorylthio end group of polymers and further functionalization thereof
WO2005000924A1 (en) 2003-06-26 2005-01-06 Symyx Technologies, Inc. Photoresist polymers
US7250475B2 (en) 2003-06-26 2007-07-31 Symyx Technologies, Inc. Synthesis of photoresist polymers
CN100549051C (zh) 2003-06-26 2009-10-14 捷时雅株式会社 光刻胶聚合物组合物
ATE406395T1 (de) * 2003-09-03 2008-09-15 Rhodia Neues copolymer mit kontrolliertem aufbau und verwendung davon
FR2872039B1 (fr) * 2004-06-23 2006-08-04 Rhodia Chimie Sa Composition cosmetique comprenant un polyorganosiloxane et ses utilisations
FR2872038A1 (fr) * 2004-06-23 2005-12-30 Rhodia Chimie Sa Composition cosmetique comprenant un polyorganosiloxane et ses utilisations
JP2008504411A (ja) 2004-07-01 2008-02-14 ウニベルズィタイト・ヘント （アルキル）アクリル酸部分を含有する単分散性ポリマー、前駆体およびその作製方法ならびにその適用
US7279446B2 (en) 2004-11-15 2007-10-09 Rhodia Inc. Viscoelastic surfactant fluids having enhanced shear recovery, rheology and stability performance
BRPI0606305A2 (pt) 2005-01-11 2009-06-16 Ciba Sc Holding Inc processo para preparação de um polìmero ou copolìmero modificado, bem como uso concentrado de pigmento e composição compreendendo o polìmero ou copolìmero assim obtido
FR2883291B1 (fr) * 2005-03-17 2010-03-05 Rhodia Chimie Sa Copolymere a blocs pouvant etre utile comme tenseur
FR2885367B1 (fr) * 2005-05-03 2007-07-27 Rhodia Chimie Sa Organosol stabilise par des polymeres sequences amphiphiles
US20100029853A1 (en) * 2005-05-23 2010-02-04 Rhodia Receherches et Technologies Controlled architecture copolymers prepared from vinyl phosphonate monomers
JP5000904B2 (ja) * 2006-03-15 2012-08-15 株式会社クラレ 末端にメルカプト基を有するポリビニルアルコール系重合体の製造方法
EP1889858B1 (de) * 2006-08-17 2009-05-13 Rhodia Opérations Blockcopolymere, Verfahren zu deren Herstellung und ihre Verwendung in Emulsionen
FR2911609B1 (fr) * 2007-01-19 2009-03-06 Rhodia Recherches & Tech Copolymere dibloc comprenant des unites derivant du styrene et des unites derivant d'acide acrylique
FR2923487B1 (fr) * 2007-11-09 2009-12-04 Rhodia Operations Copolymere ampholyte a architecture controlee
FI122734B (fi) 2007-05-21 2012-06-15 Kemira Oyj Prosessikemikaali käytettäväksi paperin tai kartongin valmistuksessa
FR2917415B1 (fr) * 2007-06-14 2012-10-12 Rhodia Recherches Et Tech Microgel polymerique comprenant des unites cationiques
FR2921663A1 (fr) 2007-10-02 2009-04-03 Bluestar Silicones France Soc Polyorganosiloxanes a fonction piperidine depourvus de toxicite par contact cutane et utilisation de ces derniers dans des compositions cosmetiques
FR2934154B1 (fr) * 2008-07-23 2010-08-13 Rhodia Operations Emulsions thermosensibles
EP2160946A1 (de) 2008-09-09 2010-03-10 Polymers CRC Limited Verfahren zur Herstellung eines antimikrobiellen Artikels
EP2160945A1 (de) 2008-09-09 2010-03-10 Polymers CRC Limited Antimikrobieller Artikel
FR2937336B1 (fr) 2008-10-22 2011-06-10 Rhodia Operations Composition pour les soins menagers comprenant un nanogel cationique
FR2965264B1 (fr) 2010-09-27 2013-11-29 Rhodia Operations Polymerisation radicalaire controlee de n-vinyl lactames en milieu aqueux
FR2965564B1 (fr) 2010-09-30 2012-10-26 Rhodia Operations Preparation de polymeres hydrophiles de haute masse par polymerisation radicalaire controlee
CN102020744B (zh) * 2010-11-17 2012-07-11 江苏苏博特新材料股份有限公司 醋酸乙烯酯类无皂乳液、可再分散性胶粉及其制备方法
EP2551338A1 (de) 2011-07-27 2013-01-30 Henkel AG & Co. KGaA Waschmittel mit Fleckenentfernungseigenschaften
CN104011101B (zh) 2011-10-24 2018-01-05 罗地亚运作公司 通过受控自由基胶束聚合来制备两亲嵌段聚合物
US9487598B2 (en) 2012-01-31 2016-11-08 Rhodia Operations Live poly(n-vinyl lactam) reactive stabilizers for dispersed phase polymerization
CN104144956B (zh) 2012-01-31 2017-04-12 罗地亚运作公司 活性反应性稳定剂存在下卤化的乙烯基单体的分散相聚合反应
FR2987837B1 (fr) 2012-03-09 2014-03-14 Rhodia Operations Polymerisation radicalaire controlee en dispersion eau-dans-l'eau
FR3004458A1 (fr) 2013-04-11 2014-10-17 Rhodia Operations Fluides de fracturation a base de polymeres associatifs et de tensioactifs labiles
FR3011555A1 (fr) 2013-10-04 2015-04-10 Rhodia Operations Polymeres sequences pour le controle du filtrat
EP2896637A1 (de) 2014-01-21 2015-07-22 Rhodia Operations Copolymer mit Einheiten des Typs A, abgeleitet von Carbonsäuremonomeren und Einheiten von Typ B, abgeleitet von Sulfonsäuremonomeren
US10377843B2 (en) 2014-05-12 2019-08-13 Solvay Specialty Polymers Italy S.P.A. Method for the controlled polymerization of fluoromonomers
FR3027309B1 (fr) 2014-10-17 2018-08-10 Rhodia Operations Polymeres polyfonctionnels a base d'unites phosphonates et d'unites amines
FR3034768B1 (fr) 2015-04-07 2017-05-05 Rhodia Operations Polymeres sequences pour le controle du filtrat
FR3034777A1 (fr) 2015-04-07 2016-10-14 Rhodia Operations Polymeres sequences pour le controle du filtrat et de la rheologie
FR3034776A1 (fr) 2015-04-07 2016-10-14 Rhodia Operations Polymeres sequences pour le controle du filtrat
WO2016177839A2 (fr) 2015-05-04 2016-11-10 Rhodia Operations Copolymères pour la lubrification des métaux
FR3037074B1 (fr) 2015-06-03 2017-07-14 Rhodia Operations Agents de suspension obtenus par polymerisation micellaire
FR3043083B1 (fr) 2015-10-30 2019-04-19 Rhodia Operations Polymeres sequences amphiphiles solubles en milieu fortement salin
JP7139246B2 (ja) 2015-12-10 2022-09-20 アダマ・マクテシム・リミテッド 高分子電解質層形成ブロックコポリマーならびにその組成物および使用
WO2017103635A1 (en) 2015-12-16 2017-06-22 Rhodia Poliamida E Especialidades Ltda Emulsifier system for explosive emulsions
WO2018102270A1 (en) 2016-11-29 2018-06-07 Rhodia Operations Polymeric systems for particle dispersion
FR3064641A1 (fr) 2017-04-03 2018-10-05 Rhodia Operations Association pour le controle du filtrat et la migration de gaz
FR3070043B1 (fr) 2017-08-09 2019-08-16 Rhodia Operations Formulation contenant un polymere associatif
PL3682042T3 (pl) 2017-09-14 2022-04-04 Chemetall Gmbh Sposób wstępnej obróbki materiałów aluminiowych, w szczególności kół aluminiowych
US11421147B2 (en) 2017-12-19 2022-08-23 Rhodia Operations Aqueous formulations of surfactants and associative polymers for the assisted recovery of petroleum
CN111492035B (zh) 2017-12-20 2023-05-02 罗地亚经营管理公司 用于颗粒分散的聚合物体系
AR114185A1 (es) 2018-01-23 2020-07-29 Adama Makhteshim Ltd Síntesis de 5-cloro-2-[(3,4,4-trifluoro-3-buten-1-il)tio]-tiazol
FR3079833B1 (fr) 2018-04-10 2020-10-09 Rhodia Operations Composition aqueuse gelifiee pour l'extraction petroliere
FR3083238A1 (fr) 2018-07-02 2020-01-03 Rhodia Operations Relargage progressif de chaines polymeres en milieu liquide
MX2021000135A (es) 2018-07-05 2021-03-25 Chemetall Gmbh Metodo para el tratamiento de superficies metalicas con una composicion acuosa acida y una composicion post-enjuague para mejorar la resistencia a la corrosion.
EP3818190A1 (de) 2018-07-05 2021-05-12 Chemetall GmbH Verfahren zur behandlung von metallischen oberflächen mit einer sauren wässrigen zusammensetzung zur verbesserung der korrosionsbeständigkeit
JP7476173B2 (ja) 2018-09-07 2024-04-30 ケメタル ゲゼルシャフト ミット ベシュレンクテル ハフツング アルミニウム含有基材の表面を処理する方法
CN113166947B (zh) 2018-09-07 2023-05-26 凯密特尔有限责任公司 处理含铝基底的表面的方法
CN112930420A (zh) 2018-10-08 2021-06-08 凯密特尔有限责任公司 金属表面的无镍磷化方法和用于这种方法的组合物
KR20210070351A (ko) 2018-10-08 2021-06-14 케메탈 게엠베하 금속 표면의 ni-무함유 인산염처리 방법 및 이러한 방법에 사용하기 위한 조성물
CN113490699B (zh) 2019-02-28 2024-11-22 罗地亚经营管理公司 用于高度稳定乳液的组合物
FR3093514A1 (fr) 2019-03-05 2020-09-11 Rhodia Operations Suspension de polymères associatifs pour le traitement de formations souterraines
WO2020182919A1 (en) 2019-03-12 2020-09-17 Rhodia Operations Stabilized friction reducer emulsions
CN113631595B (zh) 2019-03-15 2023-04-11 罗地亚经营管理公司 聚合物组合物及其应用
KR102714209B1 (ko) * 2019-12-18 2024-10-04 주식회사 엘지화학 고흡수성 수지의 제조 방법
US12479968B2 (en) 2019-12-20 2025-11-25 Specialty Operations France Process for fragmenting a polymer
JP6989792B2 (ja) 2019-12-25 2022-01-12 ダイキン工業株式会社 フルオロポリマーの製造方法
MX2023004398A (es) 2020-10-23 2023-07-11 Energy Solutions Us Llc Sistemas polimericos que tienen viscosidad mejorada y propiedades de transporte de apuntalantes.
FR3125296A1 (fr) 2021-07-13 2023-01-20 Rhodia Operations Préparation de polymères séquencés amphiphiles par polymérisation radicalaire micellaire inverse
CN115785576B (zh) * 2022-12-06 2024-04-05 合肥工业大学 一种耐γ-射线辐照可陶瓷化阻燃耐火电缆护套材料及其制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3862975A (en) * 1973-07-31 1975-01-28 Goodrich Co B F Process for preparing liquid xanthate-terminated polymers
EP0586379B1 (de) * 1991-02-06 1998-05-20 Commonwealth Scientific And Industrial Research Organisation Polymerisationsregelung
CA2259559C (en) * 1996-07-10 2004-11-09 E.I. Du Pont De Nemours And Company Polymerization with living characteristics
FR2764892B1 (fr) * 1997-06-23 2000-03-03 Rhodia Chimie Sa Procede de synthese de polymeres a blocs
NZ505654A (en) * 1997-12-18 2002-03-28 John Chiefair Living polymerisation process whereby photo-initiators of polymerisation utilises a thermal process resulting in polymers of controlled molecular weight and low polydispersity
FR2773161B1 (fr) * 1997-12-31 2000-01-21 Rhodia Chimie Sa Procede de synthese de polymeres a blocs
FR2814168B1 (fr) 2000-09-18 2006-11-17 Rhodia Chimie Sa Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee en presence d'un compose disulfure

Also Published As

Publication number Publication date
MXPA01012511A (es) 2002-07-02
DE60019419D1 (de) 2005-05-19
DE60019419T2 (de) 2006-03-09
CZ20014337A3 (cs) 2002-05-15
ZA200109549B (en) 2002-08-26
EP1185570A1 (de) 2002-03-13
JP2003501528A (ja) 2003-01-14
WO2000075207A1 (fr) 2000-12-14
IL146696A0 (en) 2002-07-25
FR2794463A1 (fr) 2000-12-08
US6777513B1 (en) 2004-08-17
JP3542580B2 (ja) 2004-07-14
AU5409900A (en) 2000-12-28
CA2375849A1 (fr) 2000-12-14
EP1185570B1 (de) 2005-04-13
FR2794463B1 (fr) 2005-02-25

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