ATE239685T1 - Reduktion von carbonylverbindungen durch ein silanderivat in gegenwart eines zink-katalysator - Google Patents

Reduktion von carbonylverbindungen durch ein silanderivat in gegenwart eines zink-katalysator

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Publication number
ATE239685T1
ATE239685T1 AT99902787T AT99902787T ATE239685T1 AT E239685 T1 ATE239685 T1 AT E239685T1 AT 99902787 T AT99902787 T AT 99902787T AT 99902787 T AT99902787 T AT 99902787T AT E239685 T1 ATE239685 T1 AT E239685T1
Authority
AT
Austria
Prior art keywords
reduction
silande
derivative
carbonyl compounds
zinc catalyst
Prior art date
Application number
AT99902787T
Other languages
English (en)
Inventor
Hubert Mimoun
Original Assignee
Firmenich & Cie
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Filing date
Publication date
Application filed by Firmenich & Cie filed Critical Firmenich & Cie
Application granted granted Critical
Publication of ATE239685T1 publication Critical patent/ATE239685T1/de

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/02—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains containing only carbon and hydrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/06—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms
    • C07C403/08—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms by hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/14—All rings being cycloaliphatic
    • C07C2602/26—All rings being cycloaliphatic the ring system containing ten carbon atoms
    • C07C2602/28—Hydrogenated naphthalenes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyridine Compounds (AREA)
AT99902787T 1998-04-01 1999-02-25 Reduktion von carbonylverbindungen durch ein silanderivat in gegenwart eines zink-katalysator ATE239685T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH77898 1998-04-01
PCT/IB1999/000329 WO1999050211A1 (en) 1998-04-01 1999-02-25 Reduction of carbonyl compounds by a silane in the presence of a zinc catalyst

Publications (1)

Publication Number Publication Date
ATE239685T1 true ATE239685T1 (de) 2003-05-15

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Application Number Title Priority Date Filing Date
AT99902787T ATE239685T1 (de) 1998-04-01 1999-02-25 Reduktion von carbonylverbindungen durch ein silanderivat in gegenwart eines zink-katalysator

Country Status (10)

Country Link
US (3) US6245952B1 (de)
EP (1) EP0986527B1 (de)
JP (1) JP4169801B2 (de)
CN (1) CN1208295C (de)
AT (1) ATE239685T1 (de)
CA (1) CA2291486A1 (de)
DE (1) DE69907589T2 (de)
ES (1) ES2198886T3 (de)
IL (1) IL133270A (de)
WO (1) WO1999050211A1 (de)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69812385T2 (de) * 1997-09-09 2004-02-05 Firmenich S.A. Enatioselektive reduktion von ketonen mit einem system aus silanmittel / metallischer verbindung / chiralem ligand
WO1999050211A1 (en) * 1998-04-01 1999-10-07 Firmenich S.A. Reduction of carbonyl compounds by a silane in the presence of a zinc catalyst
CN1303279A (zh) * 1998-06-01 2001-07-11 A·J·沃比斯卡 局部透皮疗法
US7955611B2 (en) 2000-01-03 2011-06-07 International Flora Technologies Ltd. Binding and rinse-off of quaternary ammonium compounds for cosmetic and personal care applications
DE10238114A1 (de) * 2002-08-21 2004-03-04 Bayer Ag Optisch aktive Diamine und deren Anwendung in katalytischen Prozessen
JP4962924B2 (ja) * 2005-03-04 2012-06-27 学校法人東京理科大学 光学活性アルコールの製造方法
JP5179430B2 (ja) * 2009-02-27 2013-04-10 国立大学法人名古屋大学 光学活性アルコールの製造方法
CN101844957B (zh) * 2010-03-30 2012-10-24 杭州师范大学 一种α, β-不饱和酮羰基还原成亚甲基的方法
CN104981524B (zh) * 2012-12-20 2020-03-13 埃肯有机硅法国简易股份公司 在环境温度下可硫化成弹性体的有机聚硅氧烷组合物以及新的有机聚硅氧烷缩聚催化剂
CN104981523B (zh) * 2012-12-20 2018-10-09 埃肯有机硅法国简易股份公司 在环境温度下可硫化成弹性体的有机聚硅氧烷组合物以及有机聚硅氧烷缩聚催化剂
FR2999980A1 (fr) * 2012-12-20 2014-06-27 Bluestar Silicones France Article presentant des proprietes antisalissures et destine a etre utilise dans des applications aquatiques en particulier marines
JP6134006B2 (ja) * 2012-12-20 2017-05-24 ブルースター・シリコーンズ・フランス・エスアエス 水中用途、特に海洋用途を目的とする防汚特性を有する物品
US20170073898A1 (en) * 2014-05-21 2017-03-16 Dow Corning Corporation Zinc Containing Catalysts, Methods For Preparing The Catalysts, And Compositions Containing The Catalysts
JP6514568B2 (ja) * 2015-05-19 2019-05-15 東ソー・ファインケム株式会社 ジアルキル亜鉛部分加水分解物含有溶液及びこの溶液を用いる酸化亜鉛薄膜の製造方法
IL259459B (en) 2015-11-18 2022-07-01 Provivi Inc Production of fatty olefin derivatives via olefin metathesis
EP3583088B1 (de) 2017-02-17 2025-09-10 Provivi, Inc. Synthese von pheromonen und verwandten materialien durch olefinmetathese
EP3438158B1 (de) 2017-08-01 2020-11-25 Evonik Operations GmbH Herstellung von sioc-verknüpften polyethersiloxanen
BR112022023772A2 (pt) 2020-06-01 2022-12-20 Provivi Inc Síntese de derivados de feromônio por meio de metátese de olefina z-seletiva
WO2022112118A1 (en) * 2020-11-27 2022-06-02 Firmenich Sa Reduction by a silane in the presence of zinc catalyst
CN116874350A (zh) * 2023-07-10 2023-10-13 福建桦智工程技术有限公司 一种使用不饱和酯连续还原制备叶醇的工艺
CN118221704A (zh) * 2024-03-29 2024-06-21 福州大学 一种用于催化不饱和酰胺选择性还原的锌催化剂及其应用

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Publication number Priority date Publication date Assignee Title
US3061424A (en) 1957-02-06 1962-10-30 Wacker Chemie Gmbh Method of reducing organometallic compounds
GB8902228D0 (en) * 1989-02-01 1989-03-22 Ici Plc Carbodiimide-isocyanurate rigid foams
US5227538A (en) * 1990-11-21 1993-07-13 Massachusetts Institute Of Technology Catalytic asymmetric reduction of ketones using metal catalysts
US5220020A (en) 1990-11-21 1993-06-15 Massachusetts Institute Of Technology Catalytic reduction of organic carbonyls using metal catalysts
US5449736A (en) * 1993-07-16 1995-09-12 Research Foundation Of The State Of New York Water soluble phosphorylated polysiloxanes
EP0734370B1 (de) * 1994-10-19 1999-10-20 Firmenich Sa Verfahren zur herstellung von alkoholen
DE69812385T2 (de) * 1997-09-09 2004-02-05 Firmenich S.A. Enatioselektive reduktion von ketonen mit einem system aus silanmittel / metallischer verbindung / chiralem ligand
WO1999050211A1 (en) * 1998-04-01 1999-10-07 Firmenich S.A. Reduction of carbonyl compounds by a silane in the presence of a zinc catalyst

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Publication number Publication date
EP0986527A1 (de) 2000-03-22
US6770588B2 (en) 2004-08-03
US20010034464A1 (en) 2001-10-25
CA2291486A1 (en) 1999-10-07
WO1999050211A1 (en) 1999-10-07
IL133270A0 (en) 2001-04-30
EP0986527B1 (de) 2003-05-07
IL133270A (en) 2006-06-11
US20030171210A1 (en) 2003-09-11
DE69907589D1 (de) 2003-06-12
ES2198886T3 (es) 2004-02-01
DE69907589T2 (de) 2004-03-25
US6533960B2 (en) 2003-03-18
US6245952B1 (en) 2001-06-12
JP2002503259A (ja) 2002-01-29
CN1208295C (zh) 2005-06-29
JP4169801B2 (ja) 2008-10-22
CN1262667A (zh) 2000-08-09

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