ATE178333T1 - Komplexe eines übergangsmetalls mit 2,2-bipyridin-liganden, die mit mindestens einer ammoniumalkylgruppe substituiert sind, verfahren zu ihrer herstellung und ihre anwendung als redoxvermittler - Google Patents

Komplexe eines übergangsmetalls mit 2,2-bipyridin-liganden, die mit mindestens einer ammoniumalkylgruppe substituiert sind, verfahren zu ihrer herstellung und ihre anwendung als redoxvermittler

Info

Publication number
ATE178333T1
ATE178333T1 AT93119597T AT93119597T ATE178333T1 AT E178333 T1 ATE178333 T1 AT E178333T1 AT 93119597 T AT93119597 T AT 93119597T AT 93119597 T AT93119597 T AT 93119597T AT E178333 T1 ATE178333 T1 AT E178333T1
Authority
AT
Austria
Prior art keywords
transition metal
complexes
production
alkyl group
application
Prior art date
Application number
AT93119597T
Other languages
English (en)
Inventor
David Fraser
Shaik Mohammed Zakeeruddin
Michael Graetzel
Original Assignee
Asulab Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asulab Sa filed Critical Asulab Sa
Application granted granted Critical
Publication of ATE178333T1 publication Critical patent/ATE178333T1/de

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/002—Osmium compounds
    • C07F15/0026—Osmium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • C07D213/22—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom containing two or more pyridine rings directly linked together, e.g. bipyridyl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C07F15/0053—Ruthenium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12Q—MEASURING OR TESTING PROCESSES INVOLVING ENZYMES, NUCLEIC ACIDS OR MICROORGANISMS; COMPOSITIONS OR TEST PAPERS THEREFOR; PROCESSES OF PREPARING SUCH COMPOSITIONS; CONDITION-RESPONSIVE CONTROL IN MICROBIOLOGICAL OR ENZYMOLOGICAL PROCESSES
    • C12Q1/00—Measuring or testing processes involving enzymes, nucleic acids or microorganisms; Compositions therefor; Processes of preparing such compositions
    • C12Q1/001—Enzyme electrodes
    • C12Q1/004—Enzyme electrodes mediator-assisted
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/30—Coordination compounds
    • H10K85/341—Transition metal complexes, e.g. Ru(II)polypyridine complexes
    • H10K85/344—Transition metal complexes, e.g. Ru(II)polypyridine complexes comprising ruthenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Health & Medical Sciences (AREA)
  • Immunology (AREA)
  • Biochemistry (AREA)
  • Biophysics (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Analytical Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Biotechnology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Pyridine Compounds (AREA)
  • Catalysts (AREA)
  • Measuring Or Testing Involving Enzymes Or Micro-Organisms (AREA)
AT93119597T 1992-12-15 1993-12-06 Komplexe eines übergangsmetalls mit 2,2-bipyridin-liganden, die mit mindestens einer ammoniumalkylgruppe substituiert sind, verfahren zu ihrer herstellung und ihre anwendung als redoxvermittler ATE178333T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9215214A FR2699170B1 (fr) 1992-12-15 1992-12-15 Complexes d'un métal de transition à ligands 2,2'-bipyridine substitués par au moins un radical ammonium alkyle, leur procédé de fabrication et leur application comme médiateur redox.

Publications (1)

Publication Number Publication Date
ATE178333T1 true ATE178333T1 (de) 1999-04-15

Family

ID=9436701

Family Applications (1)

Application Number Title Priority Date Filing Date
AT93119597T ATE178333T1 (de) 1992-12-15 1993-12-06 Komplexe eines übergangsmetalls mit 2,2-bipyridin-liganden, die mit mindestens einer ammoniumalkylgruppe substituiert sind, verfahren zu ihrer herstellung und ihre anwendung als redoxvermittler

Country Status (9)

Country Link
US (1) US5410059A (de)
EP (1) EP0602488B1 (de)
JP (1) JP3751032B2 (de)
KR (1) KR940014424A (de)
AT (1) ATE178333T1 (de)
AU (1) AU665327B2 (de)
CA (1) CA2110828C (de)
DE (1) DE69324217T2 (de)
FR (1) FR2699170B1 (de)

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Also Published As

Publication number Publication date
CA2110828A1 (en) 1994-06-16
EP0602488B1 (de) 1999-03-31
FR2699170B1 (fr) 1995-07-28
KR940014424A (ko) 1994-07-18
FR2699170A1 (fr) 1994-06-17
AU665327B2 (en) 1995-12-21
EP0602488A1 (de) 1994-06-22
JPH06263781A (ja) 1994-09-20
US5410059A (en) 1995-04-25
JP3751032B2 (ja) 2006-03-01
DE69324217D1 (de) 1999-05-06
AU5240493A (en) 1994-08-04
CA2110828C (en) 2005-02-15
DE69324217T2 (de) 1999-11-04

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