ATE174364T1 - Absorptionsverfahren zur verwerfung von reaktornebenprodukten und gewinnung von monomeren aus abgasströmen von olefinpolymerisationsverfahren - Google Patents

Absorptionsverfahren zur verwerfung von reaktornebenprodukten und gewinnung von monomeren aus abgasströmen von olefinpolymerisationsverfahren

Info

Publication number
ATE174364T1
ATE174364T1 AT96909528T AT96909528T ATE174364T1 AT E174364 T1 ATE174364 T1 AT E174364T1 AT 96909528 T AT96909528 T AT 96909528T AT 96909528 T AT96909528 T AT 96909528T AT E174364 T1 ATE174364 T1 AT E174364T1
Authority
AT
Austria
Prior art keywords
reactor
absorption
monomers
stream
byproduct
Prior art date
Application number
AT96909528T
Other languages
English (en)
Inventor
Yuv R Mehra
Robert H Stodghill
Original Assignee
Advanced Extraction Technol
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/398,349 external-priority patent/US5521264A/en
Application filed by Advanced Extraction Technol filed Critical Advanced Extraction Technol
Application granted granted Critical
Publication of ATE174364T1 publication Critical patent/ATE174364T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/02Recovery or working-up of waste materials of solvents, plasticisers or unreacted monomers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14Fractional distillation or use of a fractionation or rectification column
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B01J8/0035Periodical feeding or evacuation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00Post-polymerisation treatments
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00Post-polymerisation treatments
    • C08F6/001Removal of residual monomers by physical means
    • C08F6/005Removal of residual monomers by physical means from solid polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00256Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00265Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2208/00274Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00265Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2208/00292Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743Feeding or discharging of solids
    • B01J2208/00761Discharging

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Combustion & Propulsion (AREA)
  • Engineering & Computer Science (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Gas Separation By Absorption (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AT96909528T 1995-03-03 1996-02-26 Absorptionsverfahren zur verwerfung von reaktornebenprodukten und gewinnung von monomeren aus abgasströmen von olefinpolymerisationsverfahren ATE174364T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/398,349 US5521264A (en) 1995-03-03 1995-03-03 Gas phase olefin polymerization process with recovery of monomers from reactor vent gas by absorption
US08/591,314 US5681908A (en) 1995-03-03 1996-01-25 Absorption process for rejection of reactor byproducts and recovery of monomers from waste gas streams in olefin polymerization processes

Publications (1)

Publication Number Publication Date
ATE174364T1 true ATE174364T1 (de) 1998-12-15

Family

ID=27016217

Family Applications (1)

Application Number Title Priority Date Filing Date
AT96909528T ATE174364T1 (de) 1995-03-03 1996-02-26 Absorptionsverfahren zur verwerfung von reaktornebenprodukten und gewinnung von monomeren aus abgasströmen von olefinpolymerisationsverfahren

Country Status (10)

Country Link
US (1) US5681908A (de)
EP (1) EP0813567B1 (de)
JP (1) JPH11501317A (de)
KR (1) KR19980702777A (de)
CN (1) CN1066167C (de)
AT (1) ATE174364T1 (de)
AU (1) AU690445B2 (de)
CA (1) CA2214073C (de)
DE (1) DE69601126T2 (de)
WO (1) WO1996027634A1 (de)

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5837037A (en) * 1996-07-17 1998-11-17 Texaco Inc Gas handling for plastics liquefaction
ES2241278T3 (es) * 1998-04-07 2005-10-16 Exxonmobil Chemical Patents Inc. Procedimiento de polimerizacion.
JP2000044669A (ja) * 1998-08-04 2000-02-15 Teijin Ltd 芳香族ポリカーボネートの製造方法および真空捕集系
DE19915106A1 (de) * 1999-04-01 2000-10-05 Elenac Gmbh Verfahren zur Isolierung von Olefinen aus Polyolefinanlagen
BR9906019B1 (pt) * 1999-12-30 2012-02-22 processo para a polimerização e copolimerização de monÈmeros olefìnicos em reatores fase gás.
US6593506B1 (en) 2000-10-12 2003-07-15 Exxonmobil Chemical Patents Inc. Olefin recovery in a polyolefin production process
US6495609B1 (en) 2000-11-03 2002-12-17 Exxonmobil Chemical Patents Inc. Carbon dioxide recovery in an ethylene to ethylene oxide production process
US7053157B2 (en) * 2001-07-20 2006-05-30 University Of Maryland, College Park Method for production of multimodal polyolefins of tunable composition, molecular weight, and polydispersity
FR2827868A1 (fr) 2001-07-30 2003-01-31 Bp Chem Int Ltd Procede et dispositif de fabrication en continu d'un polymere d'alcoylene aromatique
EP1491559B1 (de) * 2002-03-29 2007-09-05 Mitsui Chemicals, Inc. Verfahren zur rückführung von abgas in einer polymerproduktionsanlage
US7041759B2 (en) * 2002-11-20 2006-05-09 The University Of Maryland, College Park Method for the preparation of well-defined metal acetamidinate-based catalysts on solid supports
US7183364B2 (en) * 2002-12-20 2007-02-27 University Of Maryland, College Park Process for preparation of polyolefins via degenerative transfer polymerization
US7541412B2 (en) * 2002-12-20 2009-06-02 University Of Maryland, College Park Process for preparation of polyolefins via degenerative transfer polymerization
DE102004006817A1 (de) 2004-02-11 2005-09-01 Basell Polyolefine Gmbh Verfahren zum Herstellen von Polyolefinen in Suspension
WO2006102106A1 (en) * 2005-03-17 2006-09-28 University Of Maryland, College Park Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby
US7868088B2 (en) * 2005-03-17 2011-01-11 University Of Maryland, College Park Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby
FR2884247B1 (fr) * 2005-04-11 2007-05-18 Inst Francais Du Petrole Procede et installation pour l'oligomerisation d'olefines mettant en oeuvre une separation membranaire
DE102005061576A1 (de) * 2005-12-22 2007-06-28 Wacker Chemie Ag Rückgewinnung von Ethylen und Vinylacetat aus dem Restgasstrom der Vinylester-Ethylen-Mischpolymerisatherstellung
EP2016985A1 (de) * 2007-07-16 2009-01-21 Total Petrochemicals Research Feluy Verfahren zur Optimierung der Trennung eines kohlenwasserstoffhaltigen Zufuhrstroms
EP2018899A1 (de) * 2007-07-23 2009-01-28 Total Petrochemicals Research Feluy Verfahren zur Kühlung für Destillation und Polymerisation durch Absorptionskühlung
EP2083020A1 (de) * 2008-01-18 2009-07-29 Total Petrochemicals Research Feluy Verfahren zur Monomerrückgewinnung bei einem Polymerisationsverfahren
US8524048B2 (en) * 2010-10-05 2013-09-03 Memc Electronic Materials, Inc. Processes for recovering silane from heavy-ends separation operations
US8524045B2 (en) * 2010-10-05 2013-09-03 Memc Electronic Materials, Inc. Systems for purifying silane
US8524044B2 (en) * 2010-10-05 2013-09-03 Memc Electronic Materials, Inc. Systems for recovering silane from heavy-ends separation operations
US9180405B2 (en) 2010-10-15 2015-11-10 Chevron Phillips Chemical Company Lp Ethylene recovery by absorption
US8410329B2 (en) * 2010-10-15 2013-04-02 Chevron Phillips Chemical Company Lp Ethylene separation
US9108147B2 (en) 2010-10-15 2015-08-18 Chevron Phillips Chemical Company Lp Component separations in polymerization
CA2828434C (en) * 2011-03-08 2019-04-09 Stacey HYDE Process for recycling solvent used in an ethylene-based polymerization reaction and system therefor
KR102012535B1 (ko) 2011-12-30 2019-08-20 코너 스타 리미티드 실란의 정제를 위한 방법 및 시스템
EP2743278A1 (de) * 2012-12-11 2014-06-18 Basell Polyolefine GmbH Verfahren zur Entgasung und zur Zwischenlagerung von Polyolefinpartikeln, die aus der Olefinpolymerisation erhalten wurden
CN103520946B (zh) 2013-09-25 2015-11-25 杭州双安科技有限公司 用于在烯烃聚合物生产中回收排放气的系统和方法
US10808999B2 (en) * 2014-09-30 2020-10-20 Dow Global Technologies Llc Process for increasing ethylene and propylene yield from a propylene plant
WO2017102303A1 (en) * 2015-12-15 2017-06-22 Sabic Global Technologies B.V. Olefin polymerization process
SG11201901027WA (en) * 2016-08-11 2019-03-28 Versalis Spa Process for the purification of the solvent deriving from the production of elastomeric blends
CN108883343A (zh) * 2017-07-26 2018-11-23 深圳市宏事达能源科技有限公司 一种气体分馏装置
CN111356703B (zh) * 2017-11-17 2022-05-03 埃克森美孚化学专利公司 气相烯烃聚合方法
CA3079922C (en) * 2017-12-04 2022-12-06 Borealis Ag A method of recovering olefins in a solution polymerisation process
WO2019110315A1 (en) * 2017-12-04 2019-06-13 Borealis Ag A method of recovering olefins in a solution polymerisation process
KR102383417B1 (ko) 2018-12-10 2022-04-07 주식회사 엘지화학 에틸렌 올리고머화 반응 생성물의 분리방법
WO2020260021A1 (en) * 2019-06-24 2020-12-30 Borealis Ag Process for preparing polypropylene with improved recovery
CN111659149B (zh) * 2020-06-16 2021-10-08 上海化工研究院有限公司 精馏塔、精馏系统及其用途
CN111912170A (zh) * 2020-07-24 2020-11-10 北方华锦化学工业股份有限公司 一种高密度聚乙烯装置驰放气回收综合利用的方法
WO2022050788A1 (ko) * 2020-09-07 2022-03-10 주식회사 엘지화학 올리고머 제조방법
EP4000723A1 (de) * 2020-11-20 2022-05-25 Borealis AG Vorrichtung und verfahren zur herstellung eines zulaufstroms zur lösungspolymerisierung
WO2023117754A1 (de) 2021-12-23 2023-06-29 Röhm Gmbh Verfahren zur herstellung von alkylmethacrylaten mit verbesserter ausbeute und verminderten emissionen flüchtiger organischer verbindungen
CN114917608A (zh) * 2022-06-30 2022-08-19 中国天辰工程有限公司 一种低能耗的丙烯寡聚体分离系统及分离方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB857259A (en) * 1958-09-05 1960-12-29 Phillips Petroleum Co Recovery of hydrocarbon diluent from process off-gas containing same
US4009097A (en) * 1974-03-21 1977-02-22 Uop Inc. Separation process
US3969470A (en) * 1975-04-21 1976-07-13 E. I. Du Pont De Nemours And Company Process for recycling hydrogen when making blends of olefin copolymers
US4035167A (en) * 1976-02-13 1977-07-12 Continental Oil Company Recovery of ethane and ethylene from gaseous mixtures
EP0006288B1 (de) * 1978-06-13 1985-07-17 Imperial Chemical Industries Plc Verfahren und Vorrichtung zur Abtrennung von Olefinmonomeren aus Olefinpolymerisaten
US4482687A (en) * 1979-10-26 1984-11-13 Union Carbide Corporation Preparation of low-density ethylene copolymers in fluid bed reactor
US4405495A (en) * 1980-06-30 1983-09-20 Union Carbide Corporation Catalyst impregnated on fine silica, process for preparing, and use for ethylene polymerization
US4372758A (en) * 1980-09-02 1983-02-08 Union Carbide Corporation Degassing process for removing unpolymerized monomers from olefin polymers
CA1196482A (en) * 1981-07-28 1985-11-12 Robert G. Aronson Fluidized bed discharge process
US4588790A (en) * 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4832718A (en) * 1982-05-03 1989-05-23 Advanced Extraction Technologies, Inc. Processing nitrogen-rich, hydrogen-rich, and olefin-rich gases with physical solvents
US4740222A (en) * 1982-05-03 1988-04-26 Advanced Extraction Technologies, Inc. Recovery and purification of hydrogen from refinery and petrochemical off-gas streams
US4666998A (en) * 1984-12-31 1987-05-19 Mobil Oil Corporation Closed loop recycle of vent gas in polymerization process
FR2598350B1 (fr) * 1986-05-06 1989-11-17 Bp Chimie Sa Procede et dispositif pour degazer et pour transformer en granules des particules de polyolefines obtenues par polymerisation en phase gazeuse
US5019143A (en) * 1987-09-23 1991-05-28 Mehrta Yuv R Low pressure noncryogenic processing for ethylene recovery
US5266276A (en) * 1988-07-15 1993-11-30 Bp Chemicals Limited Apparatus for the gas-phase polymerization of olefins in a fluidized-bed reactor
FR2659338B1 (fr) * 1990-03-09 1993-05-07 Bp Chemicals Snc Procedes et dispositifs de polymerisation catalytique d'alpha-olefines en phase gazeuse.
US5326929A (en) * 1992-02-19 1994-07-05 Advanced Extraction Technologies, Inc. Absorption process for hydrogen and ethylene recovery
US5220097A (en) * 1992-02-19 1993-06-15 Advanced Extraction Technologies, Inc. Front-end hydrogenation and absorption process for ethylene recovery
DE4217611A1 (de) * 1992-05-27 1993-12-02 Linde Ag Verfahren zur Gewinnung leichter C¶2¶¶+¶-Kohlenwasserstoffe aus einem Spaltgas
US5376742A (en) * 1993-09-23 1994-12-27 Quantum Chemical Corporation Monomer recovery in gas phase fluid bed olefin polymerization

Also Published As

Publication number Publication date
KR19980702777A (ko) 1998-08-05
US5681908A (en) 1997-10-28
JPH11501317A (ja) 1999-02-02
CN1066167C (zh) 2001-05-23
EP0813567B1 (de) 1998-12-09
MX9706673A (es) 1998-06-30
EP0813567A1 (de) 1997-12-29
CN1182443A (zh) 1998-05-20
AU5298996A (en) 1996-09-23
CA2214073A1 (en) 1996-09-12
CA2214073C (en) 2001-12-18
AU690445B2 (en) 1998-04-23
WO1996027634A1 (en) 1996-09-12
DE69601126D1 (de) 1999-01-21
DE69601126T2 (de) 1999-07-22

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